System-forming functions of bound water in the mechanism of topochemical reactions of formation of ultrathin layers on water surface
Identifieur interne : 002295 ( Istex/Curation ); précédent : 002294; suivant : 002296System-forming functions of bound water in the mechanism of topochemical reactions of formation of ultrathin layers on water surface
Auteurs : N. A. Bulienkov [Russie] ; E. A. Zheligovskaya [Russie]Source :
- Biophysics [ 0006-3509 ] ; 2013-01-01.
English descriptors
Abstract
Abstract: The system-forming role of the surface layer of water in the process of formation of ultrathin layers from the epoxide oligomer and triethylenetetramine or phosphotungstic acid on the surface of the aqueous phase is shown. Previously, this process was studied experimentally. The surface layer of the aqueous phase plays the role of a matrix, on which an epoxide oligomer monolayer and triethylenetetramine or phosphotungstic acid molecules are immobilized by hydrogen-bonding with water molecules from above or from below this matrix, respectively. Thus, topochemical reactions between the epoxide oligomer and triethylenetetramine or between the epoxide oligomer molecules in the presence of phosphotungstic acid become possible, so that ultrathin network epoxide-triethylenetetramine or epoxide layers are formed on the surface of water.
Url:
DOI: 10.1134/S0006350913010041
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Zheligovskaya</name><affiliation wicri:level="1"><mods:affiliation>Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia</mods:affiliation><country xml:lang="fr">Russie</country><wicri:regionArea>Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow</wicri:regionArea></affiliation></author></analytic><monogr></monogr><series><title level="j">Biophysics</title><title level="j" type="abbrev">BIOPHYSICS</title><idno type="ISSN">0006-3509</idno><idno type="eISSN">1555-6654</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2013-01-01">2013-01-01</date><biblScope unit="volume">58</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="1">1</biblScope><biblScope unit="page" to="18">18</biblScope></imprint><idno type="ISSN">0006-3509</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0006-3509</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>bound water</term><term>self-organization</term><term>structural mechanism</term><term>surface layer</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The system-forming role of the surface layer of water in the process of formation of ultrathin layers from the epoxide oligomer and triethylenetetramine or phosphotungstic acid on the surface of the aqueous phase is shown. Previously, this process was studied experimentally. The surface layer of the aqueous phase plays the role of a matrix, on which an epoxide oligomer monolayer and triethylenetetramine or phosphotungstic acid molecules are immobilized by hydrogen-bonding with water molecules from above or from below this matrix, respectively. Thus, topochemical reactions between the epoxide oligomer and triethylenetetramine or between the epoxide oligomer molecules in the presence of phosphotungstic acid become possible, so that ultrathin network epoxide-triethylenetetramine or epoxide layers are formed on the surface of water.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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