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Inclusion complexes of coumarin in cucurbiturils

Identifieur interne : 006462 ( Main/Exploration ); précédent : 006461; suivant : 006463

Inclusion complexes of coumarin in cucurbiturils

Auteurs : Ruibing Wang [Canada] ; David Bardelang [Canada] ; Mlanie Waite [Canada] ; Konstantin A. Udachin [Canada] ; Donald M. Leek [Canada] ; Kui Yu [Canada] ; Christopher I. Ratcliffe [Canada] ; John A. Ripmeester [Canada]

Source :

RBID : ISTEX:B23C1F82AAEDD5F02F8D42FD46E721D04DAE7F22

Abstract

Coumarin was found to form stable inclusion complexes with cucurbiturils. In the presence of cucurbit[7]uril (CB[7]), 1 : 1 inclusion complexes were observed in aqueous solution, as monitored by 1H NMR and UV-visible absorption spectroscopies, and further supported by ab initio calculations, whereas with cucurbit[8]uril (CB[8]) a solid phase 1 : 2 host : guest complex was found in a single crystal X-ray diffraction structure determination.

Url:
DOI: 10.1039/b903057c


Affiliations:


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<div type="abstract">Coumarin was found to form stable inclusion complexes with cucurbiturils. In the presence of cucurbit[7]uril (CB[7]), 1 : 1 inclusion complexes were observed in aqueous solution, as monitored by 1H NMR and UV-visible absorption spectroscopies, and further supported by ab initio calculations, whereas with cucurbit[8]uril (CB[8]) a solid phase 1 : 2 host : guest complex was found in a single crystal X-ray diffraction structure determination.</div>
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