Inclusion complexes of coumarin in cucurbiturils
Identifieur interne : 000C02 ( Istex/Checkpoint ); précédent : 000C01; suivant : 000C03Inclusion complexes of coumarin in cucurbiturils
Auteurs : Ruibing Wang [Canada] ; David Bardelang [Canada] ; Mlanie Waite [Canada] ; Konstantin A. Udachin [Canada] ; Donald M. Leek [Canada] ; Kui Yu [Canada] ; Christopher I. Ratcliffe [Canada] ; John A. Ripmeester [Canada]Source :
- Organic & Biomolecular Chemistry [ 1477-0520 ] ; 2009.
Abstract
Coumarin was found to form stable inclusion complexes with cucurbiturils. In the presence of cucurbit[7]uril (CB[7]), 1 : 1 inclusion complexes were observed in aqueous solution, as monitored by 1H NMR and UV-visible absorption spectroscopies, and further supported by ab initio calculations, whereas with cucurbit[8]uril (CB[8]) a solid phase 1 : 2 host : guest complex was found in a single crystal X-ray diffraction structure determination.
Url:
DOI: 10.1039/b903057c
Affiliations:
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<front><div type="abstract">Coumarin was found to form stable inclusion complexes with cucurbiturils. In the presence of cucurbit[7]uril (CB[7]), 1 : 1 inclusion complexes were observed in aqueous solution, as monitored by 1H NMR and UV-visible absorption spectroscopies, and further supported by ab initio calculations, whereas with cucurbit[8]uril (CB[8]) a solid phase 1 : 2 host : guest complex was found in a single crystal X-ray diffraction structure determination.</div>
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