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The continuing story of dinitrogen activation

Identifieur interne : 001929 ( Main/Exploration ); précédent : 001928; suivant : 001930

The continuing story of dinitrogen activation

Auteurs : Michael D. Fryzuk [Canada] ; Samuel A. Johnson [Canada]

Source :

RBID : ISTEX:FA3EBFB349EBB636343C7125EC7C76B414E2C451

Descripteurs français

English descriptors

Abstract

Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.

Url:
DOI: 10.1016/S0010-8545(00)00264-2


Affiliations:


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Le document en format XML

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<term>Dinitrogen</term>
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<term>Nitrogen</term>
<term>Nitrogen fixation</term>
<term>Nitrogenase</term>
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<term>Active site</term>
<term>Ammonia</term>
<term>Ancillary ligands</term>
<term>Bond cleavage</term>
<term>Bond distance</term>
<term>Bond formation</term>
<term>Bond length</term>
<term>Bond lengths</term>
<term>Catalytic</term>
<term>Catalytic cycle</term>
<term>Catalytic processes</term>
<term>Chem</term>
<term>Cleavage</term>
<term>Commun</term>
<term>Dalton trans</term>
<term>Dihydrogen</term>
<term>Dihydrogen complexes</term>
<term>Dinitrogen</term>
<term>Dinitrogen complexes</term>
<term>Dinitrogen compound</term>
<term>Dinitrogen compounds</term>
<term>Dinitrogen moiety</term>
<term>Dinitrogen unit</term>
<term>Dinuclear</term>
<term>Dinuclear complexes</term>
<term>Dinuclear mode</term>
<term>Early metals</term>
<term>Early transition metals</term>
<term>Electrophiles</term>
<term>Electrophilic attack</term>
<term>Fryzuk</term>
<term>Functionalization</term>
<term>Harsh conditions</term>
<term>Hidai</term>
<term>Hydride</term>
<term>Inorg</term>
<term>Johnson coordination chemistry re6iews</term>
<term>Late transition metals</term>
<term>Ligand</term>
<term>Many cases</term>
<term>Metal center</term>
<term>Metal centers</term>
<term>Mild conditions</term>
<term>Moiety</term>
<term>Mononuclear</term>
<term>Multiple bonds</term>
<term>Nitride</term>
<term>Nitrogenase</term>
<term>Nitrogenase enzyme</term>
<term>Organometallics</term>
<term>Protonation</term>
<term>Re6iews</term>
<term>Steric bulk</term>
<term>Trans</term>
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<term>Transition metals</term>
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