The continuing story of dinitrogen activation
Identifieur interne : 001929 ( Main/Exploration ); précédent : 001928; suivant : 001930The continuing story of dinitrogen activation
Auteurs : Michael D. Fryzuk [Canada] ; Samuel A. Johnson [Canada]Source :
- Coordination Chemistry Reviews [ 0010-8545 ] ; 2000.
Descripteurs français
- Wicri :
- topic : Azote.
English descriptors
- KwdEn :
- Teeft :
- Active site, Ammonia, Ancillary ligands, Bond cleavage, Bond distance, Bond formation, Bond length, Bond lengths, Catalytic, Catalytic cycle, Catalytic processes, Chem, Cleavage, Commun, Dalton trans, Dihydrogen, Dihydrogen complexes, Dinitrogen, Dinitrogen complexes, Dinitrogen compound, Dinitrogen compounds, Dinitrogen moiety, Dinitrogen unit, Dinuclear, Dinuclear complexes, Dinuclear mode, Early metals, Early transition metals, Electrophiles, Electrophilic attack, Fryzuk, Functionalization, Harsh conditions, Hidai, Hydride, Inorg, Johnson coordination chemistry re6iews, Late transition metals, Ligand, Many cases, Metal center, Metal centers, Mild conditions, Moiety, Mononuclear, Multiple bonds, Nitride, Nitrogenase, Nitrogenase enzyme, Organometallics, Protonation, Re6iews, Steric bulk, Trans, Transition metal, Transition metals.
Abstract
Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.
Url:
DOI: 10.1016/S0010-8545(00)00264-2
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 001792
- to stream Istex, to step Curation: 001792
- to stream Istex, to step Checkpoint: 000744
- to stream Main, to step Merge: 001972
- to stream Main, to step Curation: 001929
Le document en format XML
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<term>Metal complexes</term>
<term>Nitrogen</term>
<term>Nitrogen fixation</term>
<term>Nitrogenase</term>
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<term>Ammonia</term>
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<term>Bond cleavage</term>
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<term>Bond formation</term>
<term>Bond length</term>
<term>Bond lengths</term>
<term>Catalytic</term>
<term>Catalytic cycle</term>
<term>Catalytic processes</term>
<term>Chem</term>
<term>Cleavage</term>
<term>Commun</term>
<term>Dalton trans</term>
<term>Dihydrogen</term>
<term>Dihydrogen complexes</term>
<term>Dinitrogen</term>
<term>Dinitrogen complexes</term>
<term>Dinitrogen compound</term>
<term>Dinitrogen compounds</term>
<term>Dinitrogen moiety</term>
<term>Dinitrogen unit</term>
<term>Dinuclear</term>
<term>Dinuclear complexes</term>
<term>Dinuclear mode</term>
<term>Early metals</term>
<term>Early transition metals</term>
<term>Electrophiles</term>
<term>Electrophilic attack</term>
<term>Fryzuk</term>
<term>Functionalization</term>
<term>Harsh conditions</term>
<term>Hidai</term>
<term>Hydride</term>
<term>Inorg</term>
<term>Johnson coordination chemistry re6iews</term>
<term>Late transition metals</term>
<term>Ligand</term>
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<term>Metal centers</term>
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<term>Mononuclear</term>
<term>Multiple bonds</term>
<term>Nitride</term>
<term>Nitrogenase</term>
<term>Nitrogenase enzyme</term>
<term>Organometallics</term>
<term>Protonation</term>
<term>Re6iews</term>
<term>Steric bulk</term>
<term>Trans</term>
<term>Transition metal</term>
<term>Transition metals</term>
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<front><div type="abstract" xml:lang="en">Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.</div>
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