The continuing story of dinitrogen activation
Identifieur interne : 001792 ( Istex/Corpus ); précédent : 001791; suivant : 001793The continuing story of dinitrogen activation
Auteurs : Michael D. Fryzuk ; Samuel A. JohnsonSource :
- Coordination Chemistry Reviews [ 0010-8545 ] ; 2000.
English descriptors
- KwdEn :
- Teeft :
- Active site, Ammonia, Ancillary ligands, Bond cleavage, Bond distance, Bond formation, Bond length, Bond lengths, Catalytic, Catalytic cycle, Catalytic processes, Chem, Cleavage, Commun, Dalton trans, Dihydrogen, Dihydrogen complexes, Dinitrogen, Dinitrogen complexes, Dinitrogen compound, Dinitrogen compounds, Dinitrogen moiety, Dinitrogen unit, Dinuclear, Dinuclear complexes, Dinuclear mode, Early metals, Early transition metals, Electrophiles, Electrophilic attack, Fryzuk, Functionalization, Harsh conditions, Hidai, Hydride, Inorg, Johnson coordination chemistry re6iews, Late transition metals, Ligand, Many cases, Metal center, Metal centers, Mild conditions, Moiety, Mononuclear, Multiple bonds, Nitride, Nitrogenase, Nitrogenase enzyme, Organometallics, Protonation, Re6iews, Steric bulk, Trans, Transition metal, Transition metals.
Abstract
Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.
Url:
DOI: 10.1016/S0010-8545(00)00264-2
Links to Exploration step
ISTEX:FA3EBFB349EBB636343C7125EC7C76B414E2C451Le document en format XML
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Fryzuk</name><affiliation><mods:affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: fryzuk@chem.ubc.ca</mods:affiliation></affiliation></author><author><name sortKey="Johnson, Samuel A" sort="Johnson, Samuel A" uniqKey="Johnson S" first="Samuel A" last="Johnson">Samuel A. Johnson</name><affiliation><mods:affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Coordination Chemistry Reviews</title><title level="j" type="abbrev">CCR</title><idno type="ISSN">0010-8545</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000">2000</date><biblScope unit="volume">200–202</biblScope><biblScope unit="supplement">C</biblScope><biblScope unit="page" from="379">379</biblScope><biblScope unit="page" to="409">409</biblScope></imprint><idno type="ISSN">0010-8545</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0010-8545</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Dinitrogen</term><term>Metal complexes</term><term>Nitrogen</term><term>Nitrogen fixation</term><term>Nitrogenase</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Active site</term><term>Ammonia</term><term>Ancillary ligands</term><term>Bond cleavage</term><term>Bond distance</term><term>Bond formation</term><term>Bond length</term><term>Bond lengths</term><term>Catalytic</term><term>Catalytic cycle</term><term>Catalytic processes</term><term>Chem</term><term>Cleavage</term><term>Commun</term><term>Dalton trans</term><term>Dihydrogen</term><term>Dihydrogen complexes</term><term>Dinitrogen</term><term>Dinitrogen complexes</term><term>Dinitrogen compound</term><term>Dinitrogen compounds</term><term>Dinitrogen moiety</term><term>Dinitrogen unit</term><term>Dinuclear</term><term>Dinuclear complexes</term><term>Dinuclear mode</term><term>Early metals</term><term>Early transition metals</term><term>Electrophiles</term><term>Electrophilic attack</term><term>Fryzuk</term><term>Functionalization</term><term>Harsh conditions</term><term>Hidai</term><term>Hydride</term><term>Inorg</term><term>Johnson coordination chemistry re6iews</term><term>Late transition metals</term><term>Ligand</term><term>Many cases</term><term>Metal center</term><term>Metal centers</term><term>Mild conditions</term><term>Moiety</term><term>Mononuclear</term><term>Multiple bonds</term><term>Nitride</term><term>Nitrogenase</term><term>Nitrogenase enzyme</term><term>Organometallics</term><term>Protonation</term><term>Re6iews</term><term>Steric bulk</term><term>Trans</term><term>Transition metal</term><term>Transition metals</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. 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In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.</abstract><qualityIndicators><score>7.888</score><pdfWordCount>9374</pdfWordCount><pdfCharCount>55764</pdfCharCount><pdfVersion>1.2</pdfVersion><pdfPageCount>31</pdfPageCount><pdfPageSize>542 x 685 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>74</abstractWordCount><abstractCharCount>502</abstractCharCount><keywordCount>5</keywordCount></qualityIndicators><title>The continuing story of dinitrogen activation</title><pii><json:string>S0010-8545(00)00264-2</json:string></pii><genre><json:string>review-article</json:string></genre><host><title>Coordination Chemistry Reviews</title><language><json:string>unknown</json:string></language><publicationDate>2000</publicationDate><issn><json:string>0010-8545</json:string></issn><pii><json:string>S0010-8545(00)X0043-4</json:string></pii><volume>200–202</volume><pages><first>379</first><last>409</last></pages><genre><json:string>journal</json:string></genre></host><namedEntities><unitex><date><json:string>2000</json:string></date><geogName></geogName><orgName></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName></persName><placeName><json:string>Canada</json:string></placeName><ref_url></ref_url><ref_bibl></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/6H6-KFZX1C5Q-3</json:string></ark><categories><wos><json:string>1 - science</json:string><json:string>2 - chemistry, inorganic & nuclear</json:string></wos><scienceMetrix><json:string>1 - natural sciences</json:string><json:string>2 - chemistry</json:string><json:string>3 - general chemistry</json:string></scienceMetrix><scopus><json:string>1 - Physical Sciences</json:string><json:string>2 - Chemistry</json:string><json:string>3 - General Chemistry</json:string></scopus><inist><json:string>1 - sciences appliquees, technologies et medecines</json:string><json:string>2 - sciences biologiques et medicales</json:string><json:string>3 - sciences biologiques fondamentales et appliquees. psychologie</json:string></inist></categories><publicationDate>2000</publicationDate><copyrightDate>2000</copyrightDate><doi><json:string>10.1016/S0010-8545(00)00264-2</json:string></doi><id>FA3EBFB349EBB636343C7125EC7C76B414E2C451</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/6H6-KFZX1C5Q-3/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/6H6-KFZX1C5Q-3/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/6H6-KFZX1C5Q-3/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">The continuing story of dinitrogen activation</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher scheme="https://scientific-publisher.data.istex.fr">ELSEVIER</publisher><availability><licence><p>©2000 Elsevier Science S.A.</p></licence><p scheme="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</p></availability><date>2000</date></publicationStmt><notesStmt><note type="review-article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-L5L7X3NF-P">review-article</note><note type="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note><note type="content">Fig. 1: Schematic of the FeMo cofactor of FeMo nitrogenase.</note><note type="content">Scheme 1:</note><note type="content">Fig. 2: Synergistic bonding in end-on dinitrogen complexes involves σ-donation from the N2 unit to the metal and π-back-bonding from two orthogonal metal orbitals to the π*-orbitals of the N2 moiety. This back-bonding can also be described by the contribution of resonance structure B to the σ-bonded structure A.</note><note type="content">Scheme 2:</note><note type="content">Scheme 3:</note><note type="content">Scheme 4:</note><note type="content">Scheme 5:</note><note type="content">Fig. 3: The dinitrogen complex shown in (a) co-crystallized with Cp2Ti(diglyme). The charge on the individual fragments is unknown; the dinitrogen complex may be uninegative. Removal of a fragment known to form a THF adduct produces the hypothetical fragment shown in (b), which resembles the bonding mode shown in Eq. (7).</note><note type="content">Scheme 6:</note><note type="content">Scheme 7:</note><note type="content">Scheme 8:</note><note type="content">Scheme 9:</note><note type="content">Scheme 10:</note><note type="content">Scheme 11:</note><note type="content">Scheme 12:</note><note type="content">Scheme 13:</note><note type="content">Scheme 14:</note><note type="content">Table 1: NN bond lengths and stretching frequencies for NN triple, double, and single bonds, as well as a selection of dinitrogen compounds</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">The continuing story of dinitrogen activation</title><author xml:id="author-0000"><persName><forename type="first">Michael D</forename><surname>Fryzuk</surname></persName><email>fryzuk@chem.ubc.ca</email><note type="correspondence"><p>Corresponding author. Tel.: +1-604-8222897; fax: +1-604-8222847</p></note><affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</affiliation></author><author xml:id="author-0001"><persName><forename type="first">Samuel A</forename><surname>Johnson</surname></persName><affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</affiliation></author><idno type="istex">FA3EBFB349EBB636343C7125EC7C76B414E2C451</idno><idno type="ark">ark:/67375/6H6-KFZX1C5Q-3</idno><idno type="DOI">10.1016/S0010-8545(00)00264-2</idno><idno type="PII">S0010-8545(00)00264-2</idno></analytic><monogr><title level="j">Coordination Chemistry Reviews</title><title level="j" type="abbrev">CCR</title><idno type="pISSN">0010-8545</idno><idno type="PII">S0010-8545(00)X0043-4</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000"></date><biblScope unit="volume">200–202</biblScope><biblScope unit="supplement">C</biblScope><biblScope unit="page" from="379">379</biblScope><biblScope unit="page" to="409">409</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2000</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.</p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>Keywords</head><item><term>Dinitrogen</term></item><item><term>Nitrogen</term></item><item><term>Nitrogen fixation</term></item><item><term>Nitrogenase</term></item><item><term>Metal complexes</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2000">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/6H6-KFZX1C5Q-3/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: ce:floats; body; tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"><istex:entity SYSTEM="gr1" NDATA="IMAGE" name="gr1"></istex:entity><istex:entity SYSTEM="sc1" NDATA="IMAGE" name="sc1"></istex:entity><istex:entity SYSTEM="gr2" NDATA="IMAGE" name="gr2"></istex:entity><istex:entity SYSTEM="fx1" NDATA="IMAGE" name="fx1"></istex:entity><istex:entity SYSTEM="sc2" NDATA="IMAGE" name="sc2"></istex:entity><istex:entity SYSTEM="sc3" NDATA="IMAGE" name="sc3"></istex:entity><istex:entity SYSTEM="fx2" NDATA="IMAGE" name="fx2"></istex:entity><istex:entity SYSTEM="sc4" NDATA="IMAGE" name="sc4"></istex:entity><istex:entity SYSTEM="fx3" NDATA="IMAGE" name="fx3"></istex:entity><istex:entity SYSTEM="sc5" NDATA="IMAGE" name="sc5"></istex:entity><istex:entity SYSTEM="fx4" NDATA="IMAGE" name="fx4"></istex:entity><istex:entity SYSTEM="fx5" NDATA="IMAGE" name="fx5"></istex:entity><istex:entity SYSTEM="fx6" NDATA="IMAGE" name="fx6"></istex:entity><istex:entity SYSTEM="fx7" NDATA="IMAGE" name="fx7"></istex:entity><istex:entity SYSTEM="fx8" NDATA="IMAGE" name="fx8"></istex:entity><istex:entity SYSTEM="fx9" NDATA="IMAGE" name="fx9"></istex:entity><istex:entity SYSTEM="gr3" NDATA="IMAGE" name="gr3"></istex:entity><istex:entity SYSTEM="fx10" NDATA="IMAGE" name="fx10"></istex:entity><istex:entity SYSTEM="fx11" NDATA="IMAGE" name="fx11"></istex:entity><istex:entity SYSTEM="fx12" NDATA="IMAGE" name="fx12"></istex:entity><istex:entity SYSTEM="fx13" NDATA="IMAGE" name="fx13"></istex:entity><istex:entity SYSTEM="sc6" NDATA="IMAGE" name="sc6"></istex:entity><istex:entity SYSTEM="fx14" NDATA="IMAGE" name="fx14"></istex:entity><istex:entity SYSTEM="fx15" NDATA="IMAGE" name="fx15"></istex:entity><istex:entity SYSTEM="fx16" NDATA="IMAGE" name="fx16"></istex:entity><istex:entity SYSTEM="sc7" NDATA="IMAGE" name="sc7"></istex:entity><istex:entity SYSTEM="sc8" NDATA="IMAGE" name="sc8"></istex:entity><istex:entity SYSTEM="fx17" NDATA="IMAGE" name="fx17"></istex:entity><istex:entity SYSTEM="sc9" NDATA="IMAGE" name="sc9"></istex:entity><istex:entity SYSTEM="fx18" NDATA="IMAGE" name="fx18"></istex:entity><istex:entity SYSTEM="sc10" NDATA="IMAGE" name="sc10"></istex:entity><istex:entity SYSTEM="sc11" NDATA="IMAGE" name="sc11"></istex:entity><istex:entity SYSTEM="sc12" NDATA="IMAGE" name="sc12"></istex:entity><istex:entity SYSTEM="sc13" NDATA="IMAGE" name="sc13"></istex:entity><istex:entity SYSTEM="sc14" NDATA="IMAGE" name="sc14"></istex:entity></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="rev" xml:lang="en"><item-info><jid>CCR</jid><aid>9715</aid><ce:pii>S0010-8545(00)00264-2</ce:pii><ce:doi>10.1016/S0010-8545(00)00264-2</ce:doi><ce:copyright type="full-transfer" year="2000">Elsevier Science S.A.</ce:copyright></item-info><head><ce:title>The continuing story of dinitrogen activation</ce:title><ce:author-group><ce:author><ce:given-name>Michael D</ce:given-name><ce:surname>Fryzuk</ce:surname><ce:cross-ref refid="CORR1">*</ce:cross-ref><ce:e-address>fryzuk@chem.ubc.ca</ce:e-address></ce:author><ce:author><ce:given-name>Samuel A</ce:given-name><ce:surname>Johnson</ce:surname></ce:author><ce:affiliation><ce:textfn>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</ce:textfn></ce:affiliation><ce:correspondence id="CORR1"><ce:label>*</ce:label><ce:text>Corresponding author. Tel.: +1-604-8222897; fax: +1-604-8222847</ce:text></ce:correspondence></ce:author-group><ce:date-received day="21" month="9" year="1999"></ce:date-received><ce:date-accepted day="7" month="1" year="2000"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Dinitrogen</ce:text></ce:keyword><ce:keyword><ce:text>Nitrogen</ce:text></ce:keyword><ce:keyword><ce:text>Nitrogen fixation</ce:text></ce:keyword><ce:keyword><ce:text>Nitrogenase</ce:text></ce:keyword><ce:keyword><ce:text>Metal complexes</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>The continuing story of dinitrogen activation</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>The continuing story of dinitrogen activation</title></titleInfo><name type="personal"><namePart type="given">Michael D</namePart><namePart type="family">Fryzuk</namePart><affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</affiliation><affiliation>E-mail: fryzuk@chem.ubc.ca</affiliation><description>Corresponding author. Tel.: +1-604-8222897; fax: +1-604-8222847</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Samuel A</namePart><namePart type="family">Johnson</namePart><affiliation>Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="review-article" displayLabel="Review article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-L5L7X3NF-P">review-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">2000</dateIssued><copyrightDate encoding="w3cdtf">2000</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal–dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area.</abstract><note type="content">Fig. 1: Schematic of the FeMo cofactor of FeMo nitrogenase.</note><note type="content">Scheme 1: </note><note type="content">Fig. 2: Synergistic bonding in end-on dinitrogen complexes involves σ-donation from the N2 unit to the metal and π-back-bonding from two orthogonal metal orbitals to the π*-orbitals of the N2 moiety. This back-bonding can also be described by the contribution of resonance structure B to the σ-bonded structure A.</note><note type="content">Scheme 2: </note><note type="content">Scheme 3: </note><note type="content">Scheme 4: </note><note type="content">Scheme 5: </note><note type="content">Fig. 3: The dinitrogen complex shown in (a) co-crystallized with Cp2Ti(diglyme). The charge on the individual fragments is unknown; the dinitrogen complex may be uninegative. Removal of a fragment known to form a THF adduct produces the hypothetical fragment shown in (b), which resembles the bonding mode shown in Eq. (7).</note><note type="content">Scheme 6: </note><note type="content">Scheme 7: </note><note type="content">Scheme 8: </note><note type="content">Scheme 9: </note><note type="content">Scheme 10: </note><note type="content">Scheme 11: </note><note type="content">Scheme 12: </note><note type="content">Scheme 13: </note><note type="content">Scheme 14: </note><note type="content">Table 1: NN bond lengths and stretching frequencies for NN triple, double, and single bonds, as well as a selection of dinitrogen compounds</note><subject lang="en"><genre>Keywords</genre><topic>Dinitrogen</topic><topic>Nitrogen</topic><topic>Nitrogen fixation</topic><topic>Nitrogenase</topic><topic>Metal complexes</topic></subject><relatedItem type="host"><titleInfo><title>Coordination Chemistry Reviews</title></titleInfo><titleInfo type="abbreviated"><title>CCR</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">2000</dateIssued></originInfo><identifier type="ISSN">0010-8545</identifier><identifier type="PII">S0010-8545(00)X0043-4</identifier><part><date>2000</date><detail type="volume"><number>200–202</number><caption>vol.</caption></detail><detail type="supplement"><number>C</number><caption>Suppl.</caption></detail><extent unit="issue-pages"><start>1</start><end>1040</end></extent><extent unit="pages"><start>379</start><end>409</end></extent></part></relatedItem><identifier type="istex">FA3EBFB349EBB636343C7125EC7C76B414E2C451</identifier><identifier type="ark">ark:/67375/6H6-KFZX1C5Q-3</identifier><identifier type="DOI">10.1016/S0010-8545(00)00264-2</identifier><identifier type="PII">S0010-8545(00)00264-2</identifier><accessCondition type="use and reproduction" contentType="copyright">©2000 Elsevier Science S.A.</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource><recordOrigin>Elsevier Science S.A., ©2000</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/ark:/67375/6H6-KFZX1C5Q-3/record.json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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