Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O
Identifieur interne : 000840 ( Istex/Corpus ); précédent : 000839; suivant : 000841Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O
Auteurs : Michael Schaefer ; Lars Engelke ; Wolfgang BenschSource :
- ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2003-10.
English descriptors
- Teeft :
- Acta crystallogr, Allg, Amine, Amine molecules, Angles range, Anion, Anorg, Atomic coordinates, Bensch, Bensch table, Bond lengths, Cation, Chem, Chxn, Chxn ligands, Crystal structure, Crystal structures, Different steps, Disordered atoms, Experimental value, Final occupancies, General positions, Gmbh, Heating rate, Hydrogen atoms, Hydrogen bonds, Inner volume, Isotropic displacement, Kgaa, Ligand, Monodentate, Monodentate ligand, Octahedral environment, Powder pattern, Raman, Raman spectra, Room temperature, Sbs4 tetrahedra, Solvothermal synthesis, Split positions, Standard deviations, Steel autoclave, Sterical demand, Thermal decomposition, Thermal stability, Tren, Verlag, Verlag gmbh, Water molecules, Weight loss, Weinheim.
Abstract
The two novel thioantimonate(V) compounds [Mn(C6H18N4)(C6H19N4)]SbS4 (I) and [Mn(C6H14N2)3] 2—[Mn(C6H14N2)2(SbS4)2]·6H2O (II) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (trans‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound I crystallises in the triclinic space group P1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å3, Z = 2, and II in the monoclinic space group C2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å3, Z = 4. In I the Mn2+ cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS4]3— anion yielding a distorted octahedral environment. In II one unique Mn2+ ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn2+ ion is coordinated by two chxn ligands and two monodentate [SbS4]3— units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.
Solvothermale Synthese und Kristallstrukturen zweier Thioantimonat(V)‐Verbindungen mit dem einzähnig wirkenden [SbS4]3—‐Anion: [Mn(C6H18N4)(C6H19N4)]SbS4 und [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O Die beiden neuen Thioantimonate(V) [Mn(C6H18N4)(C6H19N4)]SbS4 (I) und [Mn(C6H14N2)3] 2 —[Mn(C6H14N2)2(SbS4)2]·6H2O (II) werden unter solvothermalen Bedingungen bei der Reaktion von Mangan, Antimon und Schwefel im stöchiometrischen Verhältnis in 5 ml Tris(2‐Aminoethyl)amin (tren) bei 140 °C oder chxn (trans‐1, 2‐Diaminocyclohexan, 50 %‐ige Lösung) bei 130 °C gebildet. Verbindung I kristallisiert in der triklinen Raumgruppe P1¯, a = 9, 578(2)Å, b = 11, 541(2)Å, c = 12, 297(2)Å, α = 62, 55(1)°, β = 85, 75(1)°, γ = 89, 44(1)°, V = 1202, 6(4)Å3, Z = 2, und II in der monoklinen Raumgruppe C2/c, a = 32, 611(2)Å, b = 13, 680(1)Å, c = 19, 997(1)Å, β = 117, 237(5)°, V = 7931, 7(8)Å3, Z = 4. In I ist das Mn2+‐Kation von einem vierzähnigen tren‐Liganden, einem einfach protonierten, einzähnigen tren‐Liganden sowie einem einzähnig wirkenden [SbS4]3—‐Anion verzerrt oktaedrisch umgeben. In II befindet sich ein unabhängiges Mn2+‐Ion in einer oktaedrischen Umgebung aus drei zweizähnigen chxn‐Liganden, das zweite unabhängige Mn2+‐Ion ist verzerrt oktaedrisch von zwei chxn‐Liganden sowie zwei einzähnigen [SbS4]3—‐Einheiten koordiniert. Die Verbindungen wurden mit thermischen und spektroskopischen Methoden untersucht und charakterisiert.
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DOI: 10.1002/zaac.200300158
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title><author><name sortKey="Schaefer, Michael" sort="Schaefer, Michael" uniqKey="Schaefer M" first="Michael" last="Schaefer">Michael Schaefer</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation></author><author><name sortKey="Engelke, Lars" sort="Engelke, Lars" uniqKey="Engelke L" first="Lars" last="Engelke">Lars Engelke</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation></author><author><name sortKey="Bensch, Wolfgang" sort="Bensch, Wolfgang" uniqKey="Bensch W" first="Wolfgang" last="Bensch">Wolfgang Bensch</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: wbensch@ac.uni‐kiel.de</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Institut für Anorganische Chemie der Universität Kiel, Olshausenstr. 40, D‐24098 Kiel, Fax: +49 (0)431/880 — 1520</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:637949FA0E71F965F680DAB35125392C426BED64</idno><date when="2003" year="2003">2003</date><idno type="doi">10.1002/zaac.200300158</idno><idno type="url">https://api.istex.fr/ark:/67375/WNG-H98WL9R5-X/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">000840</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000840</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main">Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title><author><name sortKey="Schaefer, Michael" sort="Schaefer, Michael" uniqKey="Schaefer M" first="Michael" last="Schaefer">Michael Schaefer</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation></author><author><name sortKey="Engelke, Lars" sort="Engelke, Lars" uniqKey="Engelke L" first="Lars" last="Engelke">Lars Engelke</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation></author><author><name sortKey="Bensch, Wolfgang" sort="Bensch, Wolfgang" uniqKey="Bensch W" first="Wolfgang" last="Bensch">Wolfgang Bensch</name><affiliation><mods:affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: wbensch@ac.uni‐kiel.de</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Institut für Anorganische Chemie der Universität Kiel, Olshausenstr. 40, D‐24098 Kiel, Fax: +49 (0)431/880 — 1520</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="ISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><imprint><biblScope unit="vol">629</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="1912">1912</biblScope><biblScope unit="page" to="1918">1918</biblScope><biblScope unit="page-count">7</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2003-10">2003-10</date></imprint><idno type="ISSN">0044-2313</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-2313</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Acta crystallogr</term><term>Allg</term><term>Amine</term><term>Amine molecules</term><term>Angles range</term><term>Anion</term><term>Anorg</term><term>Atomic coordinates</term><term>Bensch</term><term>Bensch table</term><term>Bond lengths</term><term>Cation</term><term>Chem</term><term>Chxn</term><term>Chxn ligands</term><term>Crystal structure</term><term>Crystal structures</term><term>Different steps</term><term>Disordered atoms</term><term>Experimental value</term><term>Final occupancies</term><term>General positions</term><term>Gmbh</term><term>Heating rate</term><term>Hydrogen atoms</term><term>Hydrogen bonds</term><term>Inner volume</term><term>Isotropic displacement</term><term>Kgaa</term><term>Ligand</term><term>Monodentate</term><term>Monodentate ligand</term><term>Octahedral environment</term><term>Powder pattern</term><term>Raman</term><term>Raman spectra</term><term>Room temperature</term><term>Sbs4 tetrahedra</term><term>Solvothermal synthesis</term><term>Split positions</term><term>Standard deviations</term><term>Steel autoclave</term><term>Sterical demand</term><term>Thermal decomposition</term><term>Thermal stability</term><term>Tren</term><term>Verlag</term><term>Verlag gmbh</term><term>Water molecules</term><term>Weight loss</term><term>Weinheim</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The two novel thioantimonate(V) compounds [Mn(C6H18N4)(C6H19N4)]SbS4 (I) and [Mn(C6H14N2)3] 2—[Mn(C6H14N2)2(SbS4)2]·6H2O (II) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (trans‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound I crystallises in the triclinic space group P1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å3, Z = 2, and II in the monoclinic space group C2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å3, Z = 4. In I the Mn2+ cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS4]3— anion yielding a distorted octahedral environment. In II one unique Mn2+ ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn2+ ion is coordinated by two chxn ligands and two monodentate [SbS4]3— units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.</div><div type="abstract" xml:lang="de">Solvothermale Synthese und Kristallstrukturen zweier Thioantimonat(V)‐Verbindungen mit dem einzähnig wirkenden [SbS4]3—‐Anion: [Mn(C6H18N4)(C6H19N4)]SbS4 und [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O Die beiden neuen Thioantimonate(V) [Mn(C6H18N4)(C6H19N4)]SbS4 (I) und [Mn(C6H14N2)3] 2 —[Mn(C6H14N2)2(SbS4)2]·6H2O (II) werden unter solvothermalen Bedingungen bei der Reaktion von Mangan, Antimon und Schwefel im stöchiometrischen Verhältnis in 5 ml Tris(2‐Aminoethyl)amin (tren) bei 140 °C oder chxn (trans‐1, 2‐Diaminocyclohexan, 50 %‐ige Lösung) bei 130 °C gebildet. Verbindung I kristallisiert in der triklinen Raumgruppe P1¯, a = 9, 578(2)Å, b = 11, 541(2)Å, c = 12, 297(2)Å, α = 62, 55(1)°, β = 85, 75(1)°, γ = 89, 44(1)°, V = 1202, 6(4)Å3, Z = 2, und II in der monoklinen Raumgruppe C2/c, a = 32, 611(2)Å, b = 13, 680(1)Å, c = 19, 997(1)Å, β = 117, 237(5)°, V = 7931, 7(8)Å3, Z = 4. In I ist das Mn2+‐Kation von einem vierzähnigen tren‐Liganden, einem einfach protonierten, einzähnigen tren‐Liganden sowie einem einzähnig wirkenden [SbS4]3—‐Anion verzerrt oktaedrisch umgeben. In II befindet sich ein unabhängiges Mn2+‐Ion in einer oktaedrischen Umgebung aus drei zweizähnigen chxn‐Liganden, das zweite unabhängige Mn2+‐Ion ist verzerrt oktaedrisch von zwei chxn‐Liganden sowie zwei einzähnigen [SbS4]3—‐Einheiten koordiniert. Die Verbindungen wurden mit thermischen und spektroskopischen Methoden untersucht und charakterisiert.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>bensch</json:string><json:string>tren</json:string><json:string>anorg</json:string><json:string>allg</json:string><json:string>cation</json:string><json:string>monodentate</json:string><json:string>anion</json:string><json:string>amine</json:string><json:string>chxn</json:string><json:string>gmbh</json:string><json:string>verlag gmbh</json:string><json:string>kgaa</json:string><json:string>weinheim</json:string><json:string>verlag</json:string><json:string>raman</json:string><json:string>crystal structures</json:string><json:string>ligand</json:string><json:string>solvothermal synthesis</json:string><json:string>disordered atoms</json:string><json:string>water molecules</json:string><json:string>chxn ligands</json:string><json:string>raman spectra</json:string><json:string>acta crystallogr</json:string><json:string>monodentate ligand</json:string><json:string>standard deviations</json:string><json:string>crystal structure</json:string><json:string>general positions</json:string><json:string>bensch table</json:string><json:string>angles range</json:string><json:string>bond lengths</json:string><json:string>sbs4 tetrahedra</json:string><json:string>sterical demand</json:string><json:string>hydrogen bonds</json:string><json:string>octahedral environment</json:string><json:string>experimental value</json:string><json:string>heating rate</json:string><json:string>thermal decomposition</json:string><json:string>thermal stability</json:string><json:string>weight loss</json:string><json:string>amine molecules</json:string><json:string>powder pattern</json:string><json:string>atomic coordinates</json:string><json:string>isotropic displacement</json:string><json:string>steel autoclave</json:string><json:string>inner volume</json:string><json:string>room temperature</json:string><json:string>final occupancies</json:string><json:string>split positions</json:string><json:string>hydrogen atoms</json:string><json:string>different steps</json:string></teeft></keywords><author><json:item><name>Michael Schaefer</name><affiliations><json:string>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</json:string></affiliations></json:item><json:item><name>Lars Engelke</name><affiliations><json:string>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</json:string></affiliations></json:item><json:item><name>Wolfgang Bensch Prof. Dr.</name><affiliations><json:string>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</json:string><json:string>E-mail: wbensch@ac.uni‐kiel.de</json:string><json:string>Correspondence address: Institut für Anorganische Chemie der Universität Kiel, Olshausenstr. 40, D‐24098 Kiel, Fax: +49 (0)431/880 — 1520</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Thioantimonate</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Solvothermal synthesis</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Thermal stability</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Raman spectroscopy</value></json:item></subject><articleId><json:string>ZAAC200300158</json:string></articleId><arkIstex>ark:/67375/WNG-H98WL9R5-X</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>The two novel thioantimonate(V) compounds [Mn(C6H18N4)(C6H19N4)]SbS4 (I) and [Mn(C6H14N2)3] 2—[Mn(C6H14N2)2(SbS4)2]·6H2O (II) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (trans‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound I crystallises in the triclinic space group P1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å3, Z = 2, and II in the monoclinic space group C2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å3, Z = 4. In I the Mn2+ cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS4]3— anion yielding a distorted octahedral environment. In II one unique Mn2+ ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn2+ ion is coordinated by two chxn ligands and two monodentate [SbS4]3— units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.</abstract><qualityIndicators><score>7.643</score><pdfWordCount>3435</pdfWordCount><pdfCharCount>24253</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>7</pdfPageCount><pdfPageSize>601 x 788 pts</pdfPageSize><pdfWordsPerPage>491</pdfWordsPerPage><pdfText>true</pdfText><refBibsNative>true</refBibsNative><abstractWordCount>184</abstractWordCount><abstractCharCount>1193</abstractCharCount><keywordCount>4</keywordCount></qualityIndicators><title>Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title><genre><json:string>article</json:string></genre><host><title>ZAAC ‐ Journal of Inorganic and General Chemistry</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-3749</json:string></doi><issn><json:string>0044-2313</json:string></issn><eissn><json:string>1521-3749</json:string></eissn><publisherId><json:string>ZAAC</json:string></publisherId><volume>629</volume><issue>11</issue><pages><first>1912</first><last>1918</last><total>7</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Article</value></json:item></subject></host><namedEntities><unitex><date><json:string>2003</json:string></date><geogName></geogName><orgName><json:string>Universität Kiel Olshausenstr</json:string></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName><json:string>Co</json:string><json:string>Solvothermal Synthesis</json:string><json:string>Z. Anorg</json:string><json:string>L. Engelke</json:string><json:string>U. Cornelissen</json:string><json:string>Wolfgang Bensch</json:string><json:string>Michael Schaefer</json:string><json:string>W. Bensch</json:string><json:string>Crystal Structures</json:string><json:string>Ni</json:string><json:string>Lars Engelke</json:string></persName><placeName><json:string>Kiel</json:string></placeName><ref_url></ref_url><ref_bibl><json:string>[12]</json:string><json:string>[22]</json:string><json:string>[19, 20]</json:string><json:string>[1]</json:string><json:string>[21]</json:string><json:string>[010]</json:string><json:string>[3]</json:string><json:string>[4, 5, 7, 12]</json:string><json:string>[13, 14]</json:string><json:string>[7]</json:string><json:string>[2]</json:string></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/WNG-H98WL9R5-X</json:string></ark><categories><wos><json:string>1 - science</json:string><json:string>2 - chemistry, inorganic & nuclear</json:string></wos><scienceMetrix><json:string>1 - natural sciences</json:string><json:string>2 - chemistry</json:string><json:string>3 - inorganic & nuclear chemistry</json:string></scienceMetrix><scopus><json:string>1 - Physical Sciences</json:string><json:string>2 - Chemistry</json:string><json:string>3 - Inorganic Chemistry</json:string></scopus><inist><json:string>1 - sciences appliquees, technologies et medecines</json:string><json:string>2 - sciences biologiques et medicales</json:string><json:string>3 - sciences biologiques fondamentales et appliquees. psychologie</json:string></inist></categories><publicationDate>2003</publicationDate><copyrightDate>2003</copyrightDate><doi><json:string>10.1002/zaac.200300158</json:string></doi><id>637949FA0E71F965F680DAB35125392C426BED64</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-H98WL9R5-X/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-H98WL9R5-X/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/WNG-H98WL9R5-X/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main">Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><licence>Copyright © 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</licence></availability><date type="published" when="2003-10"></date></publicationStmt><notesStmt><note type="content-type" subtype="article" source="article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="article"><analytic><title level="a" type="main">Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title><author xml:id="author-0000"><persName><forename type="first">Michael</forename><surname>Schaefer</surname></persName><affiliation><address><addrLine>Kiel</addrLine><addrLine>Institut für Anorganische Chemie der Christian‐Albrechts Universität</addrLine><country key="DE" xml:lang="en">GERMANY</country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Lars</forename><surname>Engelke</surname></persName><affiliation><address><addrLine>Kiel</addrLine><addrLine>Institut für Anorganische Chemie der Christian‐Albrechts Universität</addrLine><country key="DE" xml:lang="en">GERMANY</country></address></affiliation></author><author xml:id="author-0002" role="corresp"><persName><forename type="first">Wolfgang</forename><surname>Bensch</surname><roleName type="degree">Prof. Dr.</roleName></persName><email>wbensch@ac.uni‐kiel.de</email><affiliation><address><addrLine>Kiel</addrLine><addrLine>Institut für Anorganische Chemie der Christian‐Albrechts Universität</addrLine><country key="DE" xml:lang="en">GERMANY</country></address></affiliation></author><idno type="istex">637949FA0E71F965F680DAB35125392C426BED64</idno><idno type="ark">ark:/67375/WNG-H98WL9R5-X</idno><idno type="DOI">10.1002/zaac.200300158</idno><idno type="unit">ZAAC200300158</idno><idno type="toTypesetVersion">file:ZAAC.ZAAC200300158.pdf</idno></analytic><monogr><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="pISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><idno type="book-DOI">10.1002/(ISSN)1521-3749</idno><idno type="book-part-DOI">10.1002/zaac.v629:11</idno><idno type="product">ZAAC</idno><imprint><biblScope unit="vol">629</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="1912">1912</biblScope><biblScope unit="page" to="1918">1918</biblScope><biblScope unit="page-count">7</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2003-10"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><encodingDesc><schemaRef type="ODD" url="https://xml-schema.delivery.istex.fr/tei-istex.odd"></schemaRef><appInfo><application ident="pub2tei" version="1.0.10" when="2019-12-20"><label>pub2TEI-ISTEX</label><desc>A set of style sheets for converting XML documents encoded in various scientific publisher formats into a common TEI format.
<ref target="http://www.tei-c.org/">We use TEI</ref></desc></application></appInfo></encodingDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>The two novel thioantimonate(V) compounds [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">18</hi>N<hi rend="subscript">4</hi>)(C<hi rend="subscript">6</hi>H<hi rend="subscript">19</hi>N<hi rend="subscript">4</hi>)]SbS<hi rend="subscript">4</hi> (<hi rend="bold">I</hi>) and [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">3</hi>]<formula><math><msub><mtext> </mtext><mrow><msup><mtext> </mtext><mrow><mtext>2—</mtext></mrow></msup></mrow></msub></math></formula>[Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">2</hi>(SbS<hi rend="subscript">4</hi>)<hi rend="subscript">2</hi>]·6H<hi rend="subscript">2</hi>O (<hi rend="bold">II</hi>) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (<hi rend="italic">trans</hi>‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound <hi rend="bold">I</hi> crystallises in the triclinic space group <hi rend="italic">P</hi>1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å<hi rend="superscript">3</hi>, Z = 2, and <hi rend="bold">II</hi> in the monoclinic space group <hi rend="italic">C</hi>2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å<hi rend="superscript">3</hi>, Z = 4. In <hi rend="bold">I</hi> the Mn<hi rend="superscript">2+</hi> cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS<hi rend="subscript">4</hi>]<hi rend="superscript">3—</hi> anion yielding a distorted octahedral environment. In <hi rend="bold">II</hi> one unique Mn<hi rend="superscript">2+</hi> ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn<hi rend="superscript">2+</hi> ion is coordinated by two chxn ligands and two monodentate [SbS<hi rend="subscript">4</hi>]<hi rend="superscript">3—</hi> units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.</p></abstract><abstract xml:lang="de" style="main"><p><hi rend="bold">Solvothermale Synthese und Kristallstrukturen zweier Thioantimonat(V)‐Verbindungen mit dem einzähnig wirkenden [SbS<hi rend="subscript">4</hi>]<hi rend="superscript">3—</hi>‐Anion: [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">18</hi>N<hi rend="subscript">4</hi>)(C<hi rend="subscript">6</hi>H<hi rend="subscript">19</hi>N<hi rend="subscript">4</hi>)]SbS<hi rend="subscript">4</hi> und [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">3</hi>]<hi rend="subscript">2</hi>[Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">2</hi>(SbS<hi rend="subscript">4</hi>)<hi rend="subscript">2</hi>]·6H<hi rend="subscript">2</hi>O</hi></p><p>Die beiden neuen Thioantimonate(V) [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">18</hi>N<hi rend="subscript">4</hi>)(C<hi rend="subscript">6</hi>H<hi rend="subscript">19</hi>N<hi rend="subscript">4</hi>)]SbS<hi rend="subscript">4</hi> (<hi rend="bold">I</hi>) und [Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">3</hi>]<formula><math><msub><mtext> </mtext><mrow><mtext>2</mtext><msup><mtext> </mtext><mrow><mtext>—</mtext></mrow></msup></mrow></msub></math></formula>[Mn(C<hi rend="subscript">6</hi>H<hi rend="subscript">14</hi>N<hi rend="subscript">2</hi>)<hi rend="subscript">2</hi>(SbS<hi rend="subscript">4</hi>)<hi rend="subscript">2</hi>]·6H<hi rend="subscript">2</hi>O (<hi rend="bold">II</hi>) werden unter solvothermalen Bedingungen bei der Reaktion von Mangan, Antimon und Schwefel im stöchiometrischen Verhältnis in 5 ml Tris(2‐Aminoethyl)amin (tren) bei 140 °C oder chxn (<hi rend="italic">trans</hi>‐1, 2‐Diaminocyclohexan, 50 %‐ige Lösung) bei 130 °C gebildet. Verbindung <hi rend="bold">I</hi> kristallisiert in der triklinen Raumgruppe <hi rend="italic">P</hi>1¯, a = 9, 578(2)Å, b = 11, 541(2)Å, c = 12, 297(2)Å, α = 62, 55(1)°, β = 85, 75(1)°, γ = 89, 44(1)°, V = 1202, 6(4)Å<hi rend="superscript">3</hi>, Z = 2, und <hi rend="bold">II</hi> in der monoklinen Raumgruppe <hi rend="italic">C</hi>2/c, a = 32, 611(2)Å, b = 13, 680(1)Å, c = 19, 997(1)Å, β = 117, 237(5)°, V = 7931, 7(8)Å<hi rend="superscript">3</hi>, Z = 4. In <hi rend="bold">I</hi> ist das Mn<hi rend="superscript">2+</hi>‐Kation von einem vierzähnigen tren‐Liganden, einem einfach protonierten, einzähnigen tren‐Liganden sowie einem einzähnig wirkenden [SbS<hi rend="subscript">4</hi>]<hi rend="superscript">3—</hi>‐Anion verzerrt oktaedrisch umgeben. In <hi rend="bold">II</hi> befindet sich ein unabhängiges Mn<hi rend="superscript">2+</hi>‐Ion in einer oktaedrischen Umgebung aus drei zweizähnigen chxn‐Liganden, das zweite unabhängige Mn<hi rend="superscript">2+</hi>‐Ion ist verzerrt oktaedrisch von zwei chxn‐Liganden sowie zwei einzähnigen [SbS<hi rend="subscript">4</hi>]<hi rend="superscript">3—</hi>‐Einheiten koordiniert. Die Verbindungen wurden mit thermischen und spektroskopischen Methoden untersucht und charakterisiert.</p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">Thioantimonate</term><term xml:id="kwd2">Solvothermal synthesis</term><term xml:id="kwd3">Thermal stability</term><term xml:id="kwd4">Raman spectroscopy</term></keywords><keywords rend="articleCategory"><term>Article</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc><revisionDesc><change when="2019-12-20" who="#istex" xml:id="pub2tei">formatting</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-H98WL9R5-X/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3749</doi><issn type="print">0044-2313</issn><issn type="electronic">1521-3749</issn><idGroup><id type="product" value="ZAAC"></id></idGroup><titleGroup><title type="main" xml:lang="en">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="tocForm">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="short">Z. anorg. allg. Chem.</title></titleGroup></publicationMeta><publicationMeta level="part" position="110"><doi origin="wiley" registered="yes">10.1002/zaac.v629:11</doi><numberingGroup><numbering type="journalVolume" number="629">629</numbering><numbering type="journalIssue">11</numbering></numberingGroup><coverDate startDate="2003-10">October 2003</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="9" status="forIssue"><doi origin="wiley" registered="yes">10.1002/zaac.200300158</doi><idGroup><id type="unit" value="ZAAC200300158"></id></idGroup><countGroup><count type="pageTotal" number="7"></count></countGroup><titleGroup><title type="articleCategory">Article</title></titleGroup><copyright ownership="publisher">Copyright © 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2003-05-09"></event><event type="firstOnline" date="2003-10-15"></event><event type="publishedOnlineFinalForm" date="2003-10-15"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.12 mode:FullText source:HeaderRef result:HeaderRef mathml2tex" date="2010-07-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-11"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-11-04"></event></eventGroup><numberingGroup><numbering type="pageFirst">1912</numbering><numbering type="pageLast">1918</numbering></numberingGroup><correspondenceTo>Institut für Anorganische Chemie der Universität Kiel, Olshausenstr. 40, D‐24098 Kiel, Fax: +49 (0)431/880 — 1520</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:ZAAC.ZAAC200300158.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="8"></count><count type="tableTotal" number="5"></count><count type="referenceTotal" number="22"></count></countGroup><titleGroup><title type="main" xml:lang="en">Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS<sub>4</sub>]<sup>3—</sup> Anion Acting as a Monodentate Ligand: [Mn(C<sub>6</sub>H<sub>18</sub>N<sub>4</sub>)(C<sub>6</sub>H<sub>19</sub>N<sub>4</sub>)]SbS<sub>4</sub> and [Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>2</sub>(SbS<sub>4</sub>)<sub>2</sub>]·6H<sub>2</sub>O</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Michael</givenNames><familyName>Schaefer</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Lars</givenNames><familyName>Engelke</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#a1" corresponding="yes"><personName><givenNames>Wolfgang</givenNames><familyName>Bensch</familyName><degrees>Prof. Dr.</degrees></personName><contactDetails><email normalForm="wbensch@ac.uni-kiel.de">wbensch@ac.uni‐kiel.de</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="DE" type="organization"><unparsedAffiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Thioantimonate</keyword><keyword xml:id="kwd2">Solvothermal synthesis</keyword><keyword xml:id="kwd3">Thermal stability</keyword><keyword xml:id="kwd4">Raman spectroscopy</keyword></keywordGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The two novel thioantimonate(V) compounds [Mn(C<sub>6</sub>H<sub>18</sub>N<sub>4</sub>)(C<sub>6</sub>H<sub>19</sub>N<sub>4</sub>)]SbS<sub>4</sub> (<b>I</b>) and [Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>3</sub>]<math altimg="urn:x-wiley:00442313:media:ZAAC200300158:tex2gif-inf-32" wiley:location="equation/tex2gif-inf-32.gif"><msub><mtext> </mtext><mrow><msup><mtext> </mtext><mrow><mtext>2—</mtext></mrow></msup></mrow></msub></math>[Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>2</sub>(SbS<sub>4</sub>)<sub>2</sub>]·6H<sub>2</sub>O (<b>II</b>) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (<i>trans</i>‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound <b>I</b> crystallises in the triclinic space group <i>P</i>1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å<sup>3</sup>, Z = 2, and <b>II</b> in the monoclinic space group <i>C</i>2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å<sup>3</sup>, Z = 4. In <b>I</b> the Mn<sup>2+</sup> cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS<sub>4</sub>]<sup>3—</sup> anion yielding a distorted octahedral environment. In <b>II</b> one unique Mn<sup>2+</sup> ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn<sup>2+</sup> ion is coordinated by two chxn ligands and two monodentate [SbS<sub>4</sub>]<sup>3—</sup> units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.</p></abstract><abstract type="main" xml:lang="de"><p><b>Solvothermale Synthese und Kristallstrukturen zweier Thioantimonat(V)‐Verbindungen mit dem einzähnig wirkenden [SbS<sub>4</sub>]<sup>3—</sup>‐Anion: [Mn(C<sub>6</sub>H<sub>18</sub>N<sub>4</sub>)(C<sub>6</sub>H<sub>19</sub>N<sub>4</sub>)]SbS<sub>4</sub> und [Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>2</sub>(SbS<sub>4</sub>)<sub>2</sub>]·6H<sub>2</sub>O</b></p><p>Die beiden neuen Thioantimonate(V) [Mn(C<sub>6</sub>H<sub>18</sub>N<sub>4</sub>)(C<sub>6</sub>H<sub>19</sub>N<sub>4</sub>)]SbS<sub>4</sub> (<b>I</b>) und [Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>3</sub>]<math altimg="urn:x-wiley:00442313:media:ZAAC200300158:tex2gif-inf-73" wiley:location="equation/tex2gif-inf-73.gif"><msub><mtext> </mtext><mrow><mtext>2</mtext><msup><mtext> </mtext><mrow><mtext>—</mtext></mrow></msup></mrow></msub></math>[Mn(C<sub>6</sub>H<sub>14</sub>N<sub>2</sub>)<sub>2</sub>(SbS<sub>4</sub>)<sub>2</sub>]·6H<sub>2</sub>O (<b>II</b>) werden unter solvothermalen Bedingungen bei der Reaktion von Mangan, Antimon und Schwefel im stöchiometrischen Verhältnis in 5 ml Tris(2‐Aminoethyl)amin (tren) bei 140 °C oder chxn (<i>trans</i>‐1, 2‐Diaminocyclohexan, 50 %‐ige Lösung) bei 130 °C gebildet. Verbindung <b>I</b> kristallisiert in der triklinen Raumgruppe <i>P</i>1¯, a = 9, 578(2)Å, b = 11, 541(2)Å, c = 12, 297(2)Å, α = 62, 55(1)°, β = 85, 75(1)°, γ = 89, 44(1)°, V = 1202, 6(4)Å<sup>3</sup>, Z = 2, und <b>II</b> in der monoklinen Raumgruppe <i>C</i>2/c, a = 32, 611(2)Å, b = 13, 680(1)Å, c = 19, 997(1)Å, β = 117, 237(5)°, V = 7931, 7(8)Å<sup>3</sup>, Z = 4. In <b>I</b> ist das Mn<sup>2+</sup>‐Kation von einem vierzähnigen tren‐Liganden, einem einfach protonierten, einzähnigen tren‐Liganden sowie einem einzähnig wirkenden [SbS<sub>4</sub>]<sup>3—</sup>‐Anion verzerrt oktaedrisch umgeben. In <b>II</b> befindet sich ein unabhängiges Mn<sup>2+</sup>‐Ion in einer oktaedrischen Umgebung aus drei zweizähnigen chxn‐Liganden, das zweite unabhängige Mn<sup>2+</sup>‐Ion ist verzerrt oktaedrisch von zwei chxn‐Liganden sowie zwei einzähnigen [SbS<sub>4</sub>]<sup>3—</sup>‐Einheiten koordiniert. Die Verbindungen wurden mit thermischen und spektroskopischen Methoden untersucht und charakterisiert.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Solvothermal Synthesis and Crystal Structures of Two Thioantimonate(V) Compounds with the [SbS4]3— Anion Acting as a Monodentate Ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O</title></titleInfo><name type="personal"><namePart type="given">Michael</namePart><namePart type="family">Schaefer</namePart><affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Lars</namePart><namePart type="family">Engelke</namePart><affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Wolfgang</namePart><namePart type="family">Bensch</namePart><namePart type="termsOfAddress">Prof. Dr.</namePart><affiliation>Kiel, Institut für Anorganische Chemie der Christian‐Albrechts Universität</affiliation><affiliation>E-mail: wbensch@ac.uni‐kiel.de</affiliation><affiliation>Correspondence address: Institut für Anorganische Chemie der Universität Kiel, Olshausenstr. 40, D‐24098 Kiel, Fax: +49 (0)431/880 — 1520</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2003-10</dateIssued><dateCaptured encoding="w3cdtf">2003-05-09</dateCaptured><copyrightDate encoding="w3cdtf">2003</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">8</extent><extent unit="tables">5</extent><extent unit="references">22</extent></physicalDescription><abstract lang="en">The two novel thioantimonate(V) compounds [Mn(C6H18N4)(C6H19N4)]SbS4 (I) and [Mn(C6H14N2)3] 2—[Mn(C6H14N2)2(SbS4)2]·6H2O (II) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in the stoichiometric ratio in 5 ml tris(2‐aminoethyl)amine (tren) at 140 °C or chxn (trans‐1, 2‐diaminocyclohexane, aqueous solution 50 %) at 130 °C. Compound I crystallises in the triclinic space group P1¯, a = 9.578(2), b = 11.541(2), c = 12.297(2)Å, α = 62.55(1), β = 85.75(1), γ = 89.44(1)°, V = 1202.6(4)Å3, Z = 2, and II in the monoclinic space group C2/c, a = 32.611(2), b = 13.680(1), c = 19.997(1)Å, β = 117.237(5)°, V = 7931.7(8)Å3, Z = 4. In I the Mn2+ cation is surrounded by one tetradentate tren molecule, one protonated tren acting as a monodentate ligand and a monodentate [SbS4]3— anion yielding a distorted octahedral environment. In II one unique Mn2+ ion is in an octahedral environment of three bidentate chxn molecules and the second independent Mn2+ ion is coordinated by two chxn ligands and two monodentate [SbS4]3— units leading to a distorted octahedral surrounding. The compounds were investigated and characterized with thermal and spectroscopic methods.</abstract><abstract lang="de">Solvothermale Synthese und Kristallstrukturen zweier Thioantimonat(V)‐Verbindungen mit dem einzähnig wirkenden [SbS4]3—‐Anion: [Mn(C6H18N4)(C6H19N4)]SbS4 und [Mn(C6H14N2)3]2[Mn(C6H14N2)2(SbS4)2]·6H2O Die beiden neuen Thioantimonate(V) [Mn(C6H18N4)(C6H19N4)]SbS4 (I) und [Mn(C6H14N2)3] 2 —[Mn(C6H14N2)2(SbS4)2]·6H2O (II) werden unter solvothermalen Bedingungen bei der Reaktion von Mangan, Antimon und Schwefel im stöchiometrischen Verhältnis in 5 ml Tris(2‐Aminoethyl)amin (tren) bei 140 °C oder chxn (trans‐1, 2‐Diaminocyclohexan, 50 %‐ige Lösung) bei 130 °C gebildet. Verbindung I kristallisiert in der triklinen Raumgruppe P1¯, a = 9, 578(2)Å, b = 11, 541(2)Å, c = 12, 297(2)Å, α = 62, 55(1)°, β = 85, 75(1)°, γ = 89, 44(1)°, V = 1202, 6(4)Å3, Z = 2, und II in der monoklinen Raumgruppe C2/c, a = 32, 611(2)Å, b = 13, 680(1)Å, c = 19, 997(1)Å, β = 117, 237(5)°, V = 7931, 7(8)Å3, Z = 4. In I ist das Mn2+‐Kation von einem vierzähnigen tren‐Liganden, einem einfach protonierten, einzähnigen tren‐Liganden sowie einem einzähnig wirkenden [SbS4]3—‐Anion verzerrt oktaedrisch umgeben. In II befindet sich ein unabhängiges Mn2+‐Ion in einer oktaedrischen Umgebung aus drei zweizähnigen chxn‐Liganden, das zweite unabhängige Mn2+‐Ion ist verzerrt oktaedrisch von zwei chxn‐Liganden sowie zwei einzähnigen [SbS4]3—‐Einheiten koordiniert. Die Verbindungen wurden mit thermischen und spektroskopischen Methoden untersucht und charakterisiert.</abstract><subject lang="en"><genre>keywords</genre><topic>Thioantimonate</topic><topic>Solvothermal synthesis</topic><topic>Thermal stability</topic><topic>Raman spectroscopy</topic></subject><relatedItem type="host"><titleInfo><title>ZAAC ‐ Journal of Inorganic and General Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Z. anorg. allg. Chem.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Article</topic></subject><identifier type="ISSN">0044-2313</identifier><identifier type="eISSN">1521-3749</identifier><identifier type="DOI">10.1002/(ISSN)1521-3749</identifier><identifier type="PublisherID">ZAAC</identifier><part><date>2003</date><detail type="volume"><caption>vol.</caption><number>629</number></detail><detail type="issue"><caption>no.</caption><number>11</number></detail><extent unit="pages"><start>1912</start><end>1918</end><total>7</total></extent></part></relatedItem><relatedItem type="references" displayLabel="cit1"><titleInfo><title>J. Chem. Soc., Chem. Commun.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">W. Bensch, C. Näther, R. Stähler, J. Chem. Soc., Chem. Commun., 2001, 477.</note><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Stähler</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><extent unit="pages"><start>477</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit2"><titleInfo><title>J. Chem. Soc., Dalton Trans</title></titleInfo><genre>journal-article</genre><note type="citation/reference">R. Stähler, W. Bensch, J. Chem. Soc., Dalton Trans, 2001, 2518.</note><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Stähler</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><extent unit="pages"><start>2518</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit3"><titleInfo><title>Eur. J. Inorg. Chem</title></titleInfo><genre>journal-article</genre><note type="citation/reference">R. Stähler, W. Bensch, Eur. J. Inorg. Chem, 2001, 3073.</note><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Stähler</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><extent unit="pages"><start>3073</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit4"><titleInfo><title>Z. Anorg. Allg. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">H. A. Graf, H. Schäfer, Z. Anorg. Allg. Chem., 1976, 425, 67.</note><name type="personal"><namePart type="given">H. A.</namePart><namePart type="family">Graf</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">H.</namePart><namePart type="family">Schäfer</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1976</date><detail type="volume"><caption>vol.</caption><number>425</number></detail><extent unit="pages"><start>67</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit5"><titleInfo><title>Polyhedron</title></titleInfo><genre>journal-article</genre><note type="citation/reference">M. Schur, H. Rijnberk, C. Näther, W. Bensch, Polyhedron, 1998, 18, 101.</note><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Schur</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">H.</namePart><namePart type="family">Rijnberk</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1998</date><detail type="volume"><caption>vol.</caption><number>18</number></detail><extent unit="pages"><start>101</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit6"><titleInfo><title>Z. Kristallogr.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">A. Pfitzner, S. Reiser, Z. Kristallogr., 2002, 217, 51.</note><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Pfitzner</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">S.</namePart><namePart type="family">Reiser</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2002</date><detail type="volume"><caption>vol.</caption><number>217</number></detail><extent unit="pages"><start>51</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit7"><titleInfo><title>Acta Crystallogr.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">R. Stähler, C. Näther, W. Bensch, Acta Crystallogr., 2001, C57, 26.</note><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Stähler</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><detail type="volume"><caption>vol.</caption><number>C57</number></detail><extent unit="pages"><start>26</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit8"><titleInfo><title>Acta Crystallogr.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">R. Stähler, W. Bensch, Acta Crystallogr., 2001, C58, m537.</note><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Stähler</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><detail type="volume"><caption>vol.</caption><number>C58</number></detail><extent unit="pages"><start>537</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit9"><titleInfo><title>J. Alloys Comp.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">J. A. Hanko, M. G. Kanatzidis, J. Alloys Comp., 1998, 280, 71.</note><name type="personal"><namePart type="given">J. A.</namePart><namePart type="family">Hanko</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M. G.</namePart><namePart type="family">Kanatzidis</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1998</date><detail type="volume"><caption>vol.</caption><number>280</number></detail><extent unit="pages"><start>71</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit10"><titleInfo><title>J. Solid State Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">G. L. Schimek, W. T. Pennington, P. T. Wood, J. W. Kolis J. Solid State Chem., 1996, 123, 277.</note><name type="personal"><namePart type="given">G. L.</namePart><namePart type="family">Schimek</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W. T.</namePart><namePart type="family">Pennington</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">P. T.</namePart><namePart type="family">Wood</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J. W.</namePart><namePart type="family">Kolis</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1996</date><detail type="volume"><caption>vol.</caption><number>123</number></detail><extent unit="pages"><start>277</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit11"><titleInfo><title>Inorg. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">G. Sakane, K. Hashimoto, M. Takahashi, M. Takeda, T. Shibahara, Inorg. Chem., 1998, 37, 4231.</note><name type="personal"><namePart type="given">G.</namePart><namePart type="family">Sakane</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">K.</namePart><namePart type="family">Hashimoto</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Takahashi</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Takeda</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">T.</namePart><namePart type="family">Shibahara</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1998</date><detail type="volume"><caption>vol.</caption><number>37</number></detail><extent unit="pages"><start>4231</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit12"><titleInfo><title>Acta Crystallogr.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">K. Mereiter, A. Preisinger, H. Guth, Acta Crystallogr., 1979, B35, 19.</note><name type="personal"><namePart type="given">K.</namePart><namePart type="family">Mereiter</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Preisinger</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">H.</namePart><namePart type="family">Guth</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1979</date><detail type="volume"><caption>vol.</caption><number>B35</number></detail><extent unit="pages"><start>19</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit13"><titleInfo><title>Inorg. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">K. S. Hagen, W. H. Armstrong, H. Hope, Inorg. Chem., 1998, 27, 969.</note><name type="personal"><namePart type="given">K. S.</namePart><namePart type="family">Hagen</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W. H.</namePart><namePart type="family">Armstrong</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">H.</namePart><namePart type="family">Hope</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1998</date><detail type="volume"><caption>vol.</caption><number>27</number></detail><extent unit="pages"><start>969</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit14"><titleInfo><title>Trans. Met. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">J. Ellermeier, W. Bensch, Trans. Met. Chem., 2002, 27, 763.</note><name type="personal"><namePart type="given">J.</namePart><namePart type="family">Ellermeier</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2002</date><detail type="volume"><caption>vol.</caption><number>27</number></detail><extent unit="pages"><start>763</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit15"><titleInfo><title>Inorg. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">E. J. Laskowski, D. N. Hendrickson, Inorg. Chem., 1978, 17, 457.</note><name type="personal"><namePart type="given">E. J.</namePart><namePart type="family">Laskowski</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D. N.</namePart><namePart type="family">Hendrickson</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>1978</date><detail type="volume"><caption>vol.</caption><number>17</number></detail><extent unit="pages"><start>457</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit16"><titleInfo><title>Z. Naturforsch</title></titleInfo><genre>journal-article</genre><note type="citation/reference">M. Schur, C. Näther, W. Bensch, Z. Naturforsch, 2001, 56b, 79.</note><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Schur</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2001</date><detail type="volume"><caption>vol.</caption><number>56b</number></detail><extent unit="pages"><start>79</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit17"><titleInfo><title>Z. Naturforsch.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">F. Wendland, C. Näther, W. Bensch, Z. Naturforsch., 2000, 55b, 871.</note><name type="personal"><namePart type="given">F.</namePart><namePart type="family">Wendland</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2000</date><detail type="volume"><caption>vol.</caption><number>55b</number></detail><extent unit="pages"><start>871</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit18"><titleInfo><title>Z. Anorg. Allg. Chem.</title></titleInfo><genre>journal-article</genre><note type="citation/reference">F. Wendland, C. Näther, W. Bensch, Z. Anorg. Allg. Chem., 2000, 626, 456.</note><name type="personal"><namePart type="given">F.</namePart><namePart type="family">Wendland</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Näther</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">W.</namePart><namePart type="family">Bensch</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2000</date><detail type="volume"><caption>vol.</caption><number>626</number></detail><extent unit="pages"><start>456</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit19"><titleInfo><title>Z. Kristallogr</title></titleInfo><genre>journal-article</genre><note type="citation/reference">A. Pfitzner, D. Kurowski, Z. Kristallogr, 2000, 215, 373.</note><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Pfitzner</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D.</namePart><namePart type="family">Kurowski</namePart><role><roleTerm type="text">author</roleTerm></role></name><part><date>2000</date><detail type="volume"><caption>vol.</caption><number>215</number></detail><extent unit="pages"><start>373</start></extent></part></relatedItem><relatedItem type="references" displayLabel="cit20"><titleInfo><title>J. Weidlein, U. Müller, K. Dehnicke, Schwingungsfrequenzen I, Thieme, Stuttgart 1981, 155.</title></titleInfo><genre>other</genre></relatedItem><relatedItem type="references" displayLabel="cit21"><titleInfo><title>G. M. Sheldrick, SHELXS 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany 1997.</title></titleInfo><genre>other</genre></relatedItem><relatedItem type="references" displayLabel="cit22"><titleInfo><title>G. M. Sheldrick, SHELXL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany 1997.</title></titleInfo><genre>other</genre></relatedItem><identifier type="istex">637949FA0E71F965F680DAB35125392C426BED64</identifier><identifier type="ark">ark:/67375/WNG-H98WL9R5-X</identifier><identifier type="DOI">10.1002/zaac.200300158</identifier><identifier type="ArticleID">ZAAC200300158</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2003 WILEY‐VCH Verlag GmbH & Co. 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