First C3v-symmetrical calix[6](aza)crown.
Identifieur interne : 000067 ( Ncbi/Merge ); précédent : 000066; suivant : 000068First C3v-symmetrical calix[6](aza)crown.
Auteurs : Ivan Jabin [France] ; Olivia ReinaudSource :
- The Journal of organic chemistry [ 0022-3263 ] ; 2003.
Abstract
The first C(3v)-symmetrical calix[6](aza)crown 8 has been obtained in five steps from X(6)H(3)Me(3) 3. The key-step introduction of the triple bridge at the small rim has been achieved through reaction of a tris-arylsulfonamide derivative of tren 1 and tris-tosylcalix[6]arene 6. A (1)H NMR study has shown that the tripodal cap rigidifies the whole edifice, preventing ring inversion and constraining the calixarene core in a straight cone conformation.
DOI: 10.1021/jo026642h
PubMed: 12713340
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 000342
- to stream PubMed, to step Curation: 000342
- to stream PubMed, to step Checkpoint: 000342
Links to Exploration step
pubmed:12713340Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">First C3v-symmetrical calix[6](aza)crown.</title>
<author><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
<affiliation wicri:level="4"><nlm:affiliation>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex, France. ivan.jabin@univ-lehavre.fr</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Région Normandie</region>
<region type="old region" nuts="2">Haute-Normandie</region>
<settlement type="city">Le Havre</settlement>
</placeName>
<orgName type="university">Université du Havre</orgName>
</affiliation>
</author>
<author><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2003">2003</date>
<idno type="RBID">pubmed:12713340</idno>
<idno type="pmid">12713340</idno>
<idno type="doi">10.1021/jo026642h</idno>
<idno type="wicri:Area/PubMed/Corpus">000342</idno>
<idno type="wicri:Area/PubMed/Curation">000342</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000342</idno>
<idno type="wicri:Area/Ncbi/Merge">000067</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">First C3v-symmetrical calix[6](aza)crown.</title>
<author><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
<affiliation wicri:level="4"><nlm:affiliation>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex, France. ivan.jabin@univ-lehavre.fr</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Région Normandie</region>
<region type="old region" nuts="2">Haute-Normandie</region>
<settlement type="city">Le Havre</settlement>
</placeName>
<orgName type="university">Université du Havre</orgName>
</affiliation>
</author>
<author><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</author>
</analytic>
<series><title level="j">The Journal of organic chemistry</title>
<idno type="ISSN">0022-3263</idno>
<imprint><date when="2003" type="published">2003</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The first C(3v)-symmetrical calix[6](aza)crown 8 has been obtained in five steps from X(6)H(3)Me(3) 3. The key-step introduction of the triple bridge at the small rim has been achieved through reaction of a tris-arylsulfonamide derivative of tren 1 and tris-tosylcalix[6]arene 6. A (1)H NMR study has shown that the tripodal cap rigidifies the whole edifice, preventing ring inversion and constraining the calixarene core in a straight cone conformation.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">12713340</PMID>
<DateCreated><Year>2003</Year>
<Month>4</Month>
<Day>25</Day>
</DateCreated>
<DateCompleted><Year>2003</Year>
<Month>12</Month>
<Day>10</Day>
</DateCompleted>
<DateRevised><Year>2003</Year>
<Month>4</Month>
<Day>25</Day>
</DateRevised>
<Article PubModel="Print"><Journal><ISSN IssnType="Print">0022-3263</ISSN>
<JournalIssue CitedMedium="Print"><Volume>68</Volume>
<Issue>9</Issue>
<PubDate><Year>2003</Year>
<Month>May</Month>
<Day>2</Day>
</PubDate>
</JournalIssue>
<Title>The Journal of organic chemistry</Title>
<ISOAbbreviation>J. Org. Chem.</ISOAbbreviation>
</Journal>
<ArticleTitle>First C3v-symmetrical calix[6](aza)crown.</ArticleTitle>
<Pagination><MedlinePgn>3416-9</MedlinePgn>
</Pagination>
<Abstract><AbstractText>The first C(3v)-symmetrical calix[6](aza)crown 8 has been obtained in five steps from X(6)H(3)Me(3) 3. The key-step introduction of the triple bridge at the small rim has been achieved through reaction of a tris-arylsulfonamide derivative of tren 1 and tris-tosylcalix[6]arene 6. A (1)H NMR study has shown that the tripodal cap rigidifies the whole edifice, preventing ring inversion and constraining the calixarene core in a straight cone conformation.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Jabin</LastName>
<ForeName>Ivan</ForeName>
<Initials>I</Initials>
<AffiliationInfo><Affiliation>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex, France. ivan.jabin@univ-lehavre.fr</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Reinaud</LastName>
<ForeName>Olivia</ForeName>
<Initials>O</Initials>
</Author>
</AuthorList>
<Language>ENG</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
</Article>
<MedlineJournalInfo><Country>United States</Country>
<MedlineTA>J Org Chem</MedlineTA>
<NlmUniqueID>2985193R</NlmUniqueID>
<ISSNLinking>0022-3263</ISSNLinking>
</MedlineJournalInfo>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2003</Year>
<Month>4</Month>
<Day>26</Day>
<Hour>5</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2003</Year>
<Month>4</Month>
<Day>26</Day>
<Hour>5</Hour>
<Minute>1</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2003</Year>
<Month>4</Month>
<Day>26</Day>
<Hour>5</Hour>
<Minute>0</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">12713340</ArticleId>
<ArticleId IdType="doi">10.1021/jo026642h</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
<affiliations><list><country><li>France</li>
</country>
<region><li>Haute-Normandie</li>
<li>Région Normandie</li>
</region>
<settlement><li>Le Havre</li>
</settlement>
<orgName><li>Université du Havre</li>
</orgName>
</list>
<tree><noCountry><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</noCountry>
<country name="France"><region name="Région Normandie"><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
</region>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/France/explor/LeHavreV1/Data/Ncbi/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000067 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd -nk 000067 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/France |area= LeHavreV1 |flux= Ncbi |étape= Merge |type= RBID |clé= pubmed:12713340 |texte= First C3v-symmetrical calix[6](aza)crown. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/RBID.i -Sk "pubmed:12713340" \ | HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd \ | NlmPubMed2Wicri -a LeHavreV1
This area was generated with Dilib version V0.6.25. |