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The emergence of formulation engineering in emulsion making-transferring know-how from research laboratory to plant

Identifieur interne : 000309 ( PascalFrancis/Curation ); précédent : 000308; suivant : 000310

The emergence of formulation engineering in emulsion making-transferring know-how from research laboratory to plant

Auteurs : Jean L. Salager [Venezuela] ; Raquel E. Anton [Venezuela] ; Maria I. Briceno [Venezuela] ; Lionel Choplin [France] ; Laura Marquez [Venezuela] ; Aldo Pizzino [Venezuela] ; Maria P. Rodriguez [Venezuela]

Source :

RBID : Pascal:03-0354540

Descripteurs français

English descriptors

Abstract

All variables capable of altering the physico-chemical formulation, including temperature, are included in a generalized concept known as the hydrophilic-lipophilic deviation (HLD), which measures the departure from the reference state at which the surfactant-oil-water system exhibits Winsor III three-phase behaviour. The general phenomenology representing the emulsion properties (type, stability, viscosity, drop size) can be qualitatively charted in a three-dimensional map, where each region exhibits definite features. Travelling across the map from one region to another corresponds to modifications in formulation, composition and stirring along a path which can describe the protocol of change in an industrial process dealing with emulsion making, inversion or reworking. Six different path cases, labelled as unit operations, emerge from a systematic categorizing, and allow the interpretation of complex industrial processes such as crude oil dehydration, or the manufacturing of paint, cosmetics or heavy hydrocarbon emulsions.
pA  
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A03   1    @0 Polym. int.
A05       @2 52
A06       @2 4
A08 01  1  ENG  @1 The emergence of formulation engineering in emulsion making-transferring know-how from research laboratory to plant
A09 01  1  ENG  @1 Formula III: new concepts and strategies in formulation: from laboratory to industry, La Grande Motte, France, 13-16 October, 2001
A11 01  1    @1 SALAGER (Jean L.)
A11 02  1    @1 ANTON (Raquel E.)
A11 03  1    @1 BRICENO (Maria I.)
A11 04  1    @1 CHOPLIN (Lionel)
A11 05  1    @1 MARQUEZ (Laura)
A11 06  1    @1 PIZZINO (Aldo)
A11 07  1    @1 RODRIGUEZ (Maria P.)
A12 01  1    @1 LAFUMA (Françoise) @9 ed.
A12 02  1    @1 AUBRY (Jean-Marie) @9 ed.
A12 03  1    @1 SCHUE (François) @9 ed.
A14 01      @1 Lab FIRP, Ingeniería Química, Universidad de Los Andes @2 5101 Mérida @3 VEN @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 5 aut. @Z 6 aut. @Z 7 aut.
A14 02      @1 GEMICO, ENSIC-INPL, 1 Rue Grandville @2 54001 Nancy @3 FRA @Z 4 aut.
A15 01      @1 LPM-ESPC 1, Université Paris VI @3 FRA @Z 1 aut.
A15 02      @1 Université Lille I @3 FRA @Z 2 aut.
A15 03      @1 Université Montpellier II @3 FRA @Z 3 aut.
A18 01  1    @1 Société française de chimie. Groupe Formulation @3 FRA @9 patr.
A20       @1 471-478
A21       @1 2003
A23 01      @0 ENG
A43 01      @1 INIST @2 14717 @5 354000110903220030
A44       @0 0000 @1 © 2003 INIST-CNRS. All rights reserved.
A45       @0 66 ref.
A47 01  1    @0 03-0354540
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Polymer international
A66 01      @0 GBR
C01 01    ENG  @0 All variables capable of altering the physico-chemical formulation, including temperature, are included in a generalized concept known as the hydrophilic-lipophilic deviation (HLD), which measures the departure from the reference state at which the surfactant-oil-water system exhibits Winsor III three-phase behaviour. The general phenomenology representing the emulsion properties (type, stability, viscosity, drop size) can be qualitatively charted in a three-dimensional map, where each region exhibits definite features. Travelling across the map from one region to another corresponds to modifications in formulation, composition and stirring along a path which can describe the protocol of change in an industrial process dealing with emulsion making, inversion or reworking. Six different path cases, labelled as unit operations, emerge from a systematic categorizing, and allow the interpretation of complex industrial processes such as crude oil dehydration, or the manufacturing of paint, cosmetics or heavy hydrocarbon emulsions.
C02 01  X    @0 001C01J04
C03 01  X  FRE  @0 Emulsion @5 01
C03 01  X  ENG  @0 Emulsion @5 01
C03 01  X  SPA  @0 Emulsión @5 01
C03 02  X  FRE  @0 Formulation @5 02
C03 02  X  ENG  @0 Formulation @5 02
C03 02  X  SPA  @0 Formulación @5 02
C03 03  X  FRE  @0 Agent surface @2 FX @5 03
C03 03  X  ENG  @0 Surfactant @2 FX @5 03
C03 03  X  SPA  @0 Agente superficie @2 FX @5 03
C03 04  X  FRE  @0 Emulsification @5 04
C03 04  X  ENG  @0 Emulsification @5 04
C03 04  X  SPA  @0 Emulsificación @5 04
N21       @1 251
N82       @1 PSI
pR  
A30 01  1  ENG  @1 Formula III: New Concepts and Strategies in Formulation: From Laboratory to Industry. Meeting @3 La Grande Motte FRA @4 2001-10-13

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<div type="abstract" xml:lang="en">All variables capable of altering the physico-chemical formulation, including temperature, are included in a generalized concept known as the hydrophilic-lipophilic deviation (HLD), which measures the departure from the reference state at which the surfactant-oil-water system exhibits Winsor III three-phase behaviour. The general phenomenology representing the emulsion properties (type, stability, viscosity, drop size) can be qualitatively charted in a three-dimensional map, where each region exhibits definite features. Travelling across the map from one region to another corresponds to modifications in formulation, composition and stirring along a path which can describe the protocol of change in an industrial process dealing with emulsion making, inversion or reworking. Six different path cases, labelled as unit operations, emerge from a systematic categorizing, and allow the interpretation of complex industrial processes such as crude oil dehydration, or the manufacturing of paint, cosmetics or heavy hydrocarbon emulsions.</div>
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<s5>04</s5>
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<fC03 i1="04" i2="X" l="ENG">
<s0>Emulsification</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Emulsificación</s0>
<s5>04</s5>
</fC03>
<fN21>
<s1>251</s1>
</fN21>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>Formula III: New Concepts and Strategies in Formulation: From Laboratory to Industry. Meeting</s1>
<s3>La Grande Motte FRA</s3>
<s4>2001-10-13</s4>
</fA30>
</pR>
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