LrgpV1, PascalFrancis, Corpus, bibRecord, 000432

Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials

Identifieur interne : 000432 ( PascalFrancis/Corpus ); précédent : 000431; suivant : 000433

Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials

Auteurs : Michel Bouquey ; Christophe Serra ; Nicolas Benon ; Laurent Prat ; Georges Hadziioannou

Source :

Chemical engineering journal : (1996) [ 1385-8947 ] ; 2008.

RBID : Pascal:08-0055157

Descripteurs français

Pascal (Inist)
- Microfluidique, Agent surface, Emulsion, Polymérisation, Rayonnement UV, Viscosité, Phase continue, Gouttelette, Phase dispersée, Microparticule, Microréacteur.

English descriptors

KwdEn :
- Continuous phase, Dispersed phase, Droplet, Emulsion, Microfluidics, Microparticle, Microreactor, Polymerization, Surfactant, Ultraviolet radiation, Viscosity.

Abstract

Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 1385-8947`
A03		`1`		`@0 Chem. eng. j. : (1996)`
A05				`@2 135`
A06				`@3 SUP1`
A08	`01`	`1`	`ENG`	`@1 Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials`
A09	`01`	`1`	`ENG`	`@1 Microreaction Technology, IMRET 9: Proceedings of the Ninth International Conference on Microreaction Technology`
A11	`01`	`1`		`@1 BOUQUEY (Michel)`
A11	`02`	`1`		`@1 SERRA (Christophe)`
A11	`03`	`1`		`@1 BENON (Nicolas)`
A11	`04`	`1`		`@1 PRAT (Laurent)`
A11	`05`	`1`		`@1 HADZIIOANNOU (Georges)`
A12	`01`	`1`		`@1 SCHÜTTE (Rüdiger) @9 ed.`
A12	`02`	`1`		`@1 RENKEN (Albert) @9 ed.`
A12	`03`	`1`		`@1 KLEMM (Elias) @9 ed.`
A12	`04`	`1`		`@1 LIAUW (Marcel A.) @9 ed.`
A12	`05`	`1`		`@1 MATLOSZ (Michael) @9 ed.`
A14	`01`			`@1 Laboratoire d'Ingénierie des Polymères pour les Hautes Technologies, CNRS UMR 7165, ECPM, 25 rue Becquerel @2 67087 Strasbourg @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 5 aut.`
A14	`02`			`@1 Laboratoire de Génie Chimique, CNRS UMR 5503, INPT, 5 rue Paulin Talabot @2 31106 Toulouse @3 FRA @Z 4 aut.`
A15	`01`			`@1 Process Technology & Engineering, Evonik Degussa GmbH, Rodenbacher Chaussee 4 @2 63457 Hanau (Wolfgang) @3 DEU @Z 1 aut.`
A15	`02`			`@1 Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC-LGRC-Station 6, Bâtiment CH / CH J2 500 @2 1015 Lausanne @3 CHE @Z 2 aut.`
A15	`03`			`@1 Chemnitz University of Technology, Faculty of Natural Sciences, Department of Chemical Technology @2 09107 Chemnitz @3 DEU @Z 3 aut.`
A15	`04`			`@1 Technical Chemistry and Reaction Engineering, ITMC, RWTH Aachen, Worringerweg 1 @2 52074 Aachen @3 DEU @Z 4 aut.`
A15	`05`			`@1 CNRS-ENSIC, Laboratoire des Sciences du Genie Chimique, 1, rue Grandville @2 54001 Nancy @3 FRA @Z 5 aut.`
A20				`@2 S93-S98`
A21				`@1 2008`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14678 @5 354000173568260130`
A44				`@0 0000 @1 © 2008 INIST-CNRS. All rights reserved.`
A45				`@0 29 ref.`
A47	`01`	`1`		`@0 08-0055157`
A60				`@1 P @2 C`
A61				`@0 A`
A64	`01`	`1`		`@0 Chemical engineering journal : (1996)`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.
C02	`01`	`X`		`@0 001D07H`
C03	`01`	`X`	`FRE`	`@0 Microfluidique @5 01`
C03	`01`	`X`	`ENG`	`@0 Microfluidics @5 01`
C03	`01`	`X`	`SPA`	`@0 Microfluidic @5 01`
C03	`02`	`X`	`FRE`	`@0 Agent surface @2 FX @5 02`
C03	`02`	`X`	`ENG`	`@0 Surfactant @2 FX @5 02`
C03	`02`	`X`	`SPA`	`@0 Agente superficie @2 FX @5 02`
C03	`03`	`X`	`FRE`	`@0 Emulsion @5 03`
C03	`03`	`X`	`ENG`	`@0 Emulsion @5 03`
C03	`03`	`X`	`SPA`	`@0 Emulsión @5 03`
C03	`04`	`X`	`FRE`	`@0 Polymérisation @5 04`
C03	`04`	`X`	`ENG`	`@0 Polymerization @5 04`
C03	`04`	`X`	`SPA`	`@0 Polimerización @5 04`
C03	`05`	`X`	`FRE`	`@0 Rayonnement UV @5 05`
C03	`05`	`X`	`ENG`	`@0 Ultraviolet radiation @5 05`
C03	`05`	`X`	`SPA`	`@0 Radiación ultravioleta @5 05`
C03	`06`	`X`	`FRE`	`@0 Viscosité @5 06`
C03	`06`	`X`	`ENG`	`@0 Viscosity @5 06`
C03	`06`	`X`	`SPA`	`@0 Viscosidad @5 06`
C03	`07`	`X`	`FRE`	`@0 Phase continue @5 07`
C03	`07`	`X`	`ENG`	`@0 Continuous phase @5 07`
C03	`07`	`X`	`SPA`	`@0 Fase continua @5 07`
C03	`08`	`X`	`FRE`	`@0 Gouttelette @5 08`
C03	`08`	`X`	`ENG`	`@0 Droplet @5 08`
C03	`08`	`X`	`SPA`	`@0 Gotita @5 08`
C03	`09`	`X`	`FRE`	`@0 Phase dispersée @5 09`
C03	`09`	`X`	`ENG`	`@0 Dispersed phase @5 09`
C03	`09`	`X`	`SPA`	`@0 Fase dispersada @5 09`
C03	`10`	`X`	`FRE`	`@0 Microparticule @5 10`
C03	`10`	`X`	`ENG`	`@0 Microparticle @5 10`
C03	`10`	`X`	`SPA`	`@0 Micropartícula @5 10`
C03	`11`	`X`	`FRE`	`@0 Microréacteur @5 11`
C03	`11`	`X`	`ENG`	`@0 Microreactor @5 11`
C03	`11`	`X`	`SPA`	`@0 Microreactor @5 11`
C07	`01`	`X`	`FRE`	`@0 Mécanique fluide`
C07	`01`	`X`	`ENG`	`@0 Fluid mechanics`
C07	`01`	`X`	`SPA`	`@0 Mecánica flúido`
N21				`@1 028`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

A30	`01`	`1`	`ENG`	`@1 IMRET 9 : International Conference on Microreaction Technology @2 9 @3 Potsdam DEU @4 2006-09-06`

Format Inist (serveur)

NO :	PASCAL 08-0055157 INIST
ET :	Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials
AU :	BOUQUEY (Michel); SERRA (Christophe); BENON (Nicolas); PRAT (Laurent); HADZIIOANNOU (Georges); SCHÜTTE (Rüdiger); RENKEN (Albert); KLEMM (Elias); LIAUW (Marcel A.); MATLOSZ (Michael)
AF :	Laboratoire d'Ingénierie des Polymères pour les Hautes Technologies, CNRS UMR 7165, ECPM, 25 rue Becquerel/67087 Strasbourg/France (1 aut., 2 aut., 3 aut., 5 aut.); Laboratoire de Génie Chimique, CNRS UMR 5503, INPT, 5 rue Paulin Talabot/31106 Toulouse/France (4 aut.); Process Technology & Engineering, Evonik Degussa GmbH, Rodenbacher Chaussee 4/63457 Hanau (Wolfgang)/Allemagne (1 aut.); Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC-LGRC-Station 6, Bâtiment CH / CH J2 500/1015 Lausanne/Suisse (2 aut.); Chemnitz University of Technology, Faculty of Natural Sciences, Department of Chemical Technology/09107 Chemnitz/Allemagne (3 aut.); Technical Chemistry and Reaction Engineering, ITMC, RWTH Aachen, Worringerweg 1/52074 Aachen/Allemagne (4 aut.); CNRS-ENSIC, Laboratoire des Sciences du Genie Chimique, 1, rue Grandville/54001 Nancy/France (5 aut.)
DT :	Publication en série; Congrès; Niveau analytique
SO :	Chemical engineering journal : (1996); ISSN 1385-8947; Pays-Bas; Da. 2008; Vol. 135; No. SUP1; S93-S98; Bibl. 29 ref.
LA :	Anglais
EA :	Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.
CC :	001D07H
FD :	Microfluidique; Agent surface; Emulsion; Polymérisation; Rayonnement UV; Viscosité; Phase continue; Gouttelette; Phase dispersée; Microparticule; Microréacteur
FG :	Mécanique fluide
ED :	Microfluidics; Surfactant; Emulsion; Polymerization; Ultraviolet radiation; Viscosity; Continuous phase; Droplet; Dispersed phase; Microparticle; Microreactor
EG :	Fluid mechanics
SD :	Microfluidic; Agente superficie; Emulsión; Polimerización; Radiación ultravioleta; Viscosidad; Fase continua; Gotita; Fase dispersada; Micropartícula; Microreactor
LO :	INIST-14678.354000173568260130
ID :	08-0055157

Links to Exploration step

Pascal:08-0055157

Le document en format XML

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<front><div type="abstract" xml:lang="en">Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.</div>
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<sZ>4 aut.</sZ>
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<fA15 i1="01"><s1>Process Technology & Engineering, Evonik Degussa GmbH, Rodenbacher Chaussee 4</s1>
<s2>63457 Hanau (Wolfgang)</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
</fA15>
<fA15 i1="02"><s1>Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC-LGRC-Station 6, Bâtiment CH / CH J2 500</s1>
<s2>1015 Lausanne</s2>
<s3>CHE</s3>
<sZ>2 aut.</sZ>
</fA15>
<fA15 i1="03"><s1>Chemnitz University of Technology, Faculty of Natural Sciences, Department of Chemical Technology</s1>
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<s3>DEU</s3>
<sZ>3 aut.</sZ>
</fA15>
<fA15 i1="04"><s1>Technical Chemistry and Reaction Engineering, ITMC, RWTH Aachen, Worringerweg 1</s1>
<s2>52074 Aachen</s2>
<s3>DEU</s3>
<sZ>4 aut.</sZ>
</fA15>
<fA15 i1="05"><s1>CNRS-ENSIC, Laboratoire des Sciences du Genie Chimique, 1, rue Grandville</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
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<fA20><s2>S93-S98</s2>
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<fA60><s1>P</s1>
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<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Chemical engineering journal : (1996)</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D07H</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Microfluidique</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Microfluidics</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Microfluidic</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Agent surface</s0>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Surfactant</s0>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Agente superficie</s0>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Emulsion</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Emulsion</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Emulsión</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Polymérisation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Polymerization</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Polimerización</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Rayonnement UV</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Ultraviolet radiation</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Radiación ultravioleta</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Viscosité</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Viscosity</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Viscosidad</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Phase continue</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Continuous phase</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Fase continua</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Gouttelette</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Droplet</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Gotita</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Phase dispersée</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Dispersed phase</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Fase dispersada</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Microparticule</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Microparticle</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Micropartícula</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Microréacteur</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Microreactor</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Microreactor</s0>
<s5>11</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Mécanique fluide</s0>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Fluid mechanics</s0>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Mecánica flúido</s0>
</fC07>
<fN21><s1>028</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>IMRET 9 : International Conference on Microreaction Technology</s1>
<s2>9</s2>
<s3>Potsdam DEU</s3>
<s4>2006-09-06</s4>
</fA30>
</pR>
</standard>
<server><NO>PASCAL 08-0055157 INIST</NO>
<ET>Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials</ET>
<AU>BOUQUEY (Michel); SERRA (Christophe); BENON (Nicolas); PRAT (Laurent); HADZIIOANNOU (Georges); SCHÜTTE (Rüdiger); RENKEN (Albert); KLEMM (Elias); LIAUW (Marcel A.); MATLOSZ (Michael)</AU>
<AF>Laboratoire d'Ingénierie des Polymères pour les Hautes Technologies, CNRS UMR 7165, ECPM, 25 rue Becquerel/67087 Strasbourg/France (1 aut., 2 aut., 3 aut., 5 aut.); Laboratoire de Génie Chimique, CNRS UMR 5503, INPT, 5 rue Paulin Talabot/31106 Toulouse/France (4 aut.); Process Technology & Engineering, Evonik Degussa GmbH, Rodenbacher Chaussee 4/63457 Hanau (Wolfgang)/Allemagne (1 aut.); Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC-LGRC-Station 6, Bâtiment CH / CH J2 500/1015 Lausanne/Suisse (2 aut.); Chemnitz University of Technology, Faculty of Natural Sciences, Department of Chemical Technology/09107 Chemnitz/Allemagne (3 aut.); Technical Chemistry and Reaction Engineering, ITMC, RWTH Aachen, Worringerweg 1/52074 Aachen/Allemagne (4 aut.); CNRS-ENSIC, Laboratoire des Sciences du Genie Chimique, 1, rue Grandville/54001 Nancy/France (5 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Chemical engineering journal : (1996); ISSN 1385-8947; Pays-Bas; Da. 2008; Vol. 135; No. SUP1; S93-S98; Bibl. 29 ref.</SO>
<LA>Anglais</LA>
<EA>Monodisperse and size-controlled polymer particles were produced without surfactant or washcoat from O/W monomer emulsions and "on the fly" polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.</EA>
<CC>001D07H</CC>
<FD>Microfluidique; Agent surface; Emulsion; Polymérisation; Rayonnement UV; Viscosité; Phase continue; Gouttelette; Phase dispersée; Microparticule; Microréacteur</FD>
<FG>Mécanique fluide</FG>
<ED>Microfluidics; Surfactant; Emulsion; Polymerization; Ultraviolet radiation; Viscosity; Continuous phase; Droplet; Dispersed phase; Microparticle; Microreactor</ED>
<EG>Fluid mechanics</EG>
<SD>Microfluidic; Agente superficie; Emulsión; Polimerización; Radiación ultravioleta; Viscosidad; Fase continua; Gotita; Fase dispersada; Micropartícula; Microreactor</SD>
<LO>INIST-14678.354000173568260130</LO>
<ID>08-0055157</ID>
</server>
</inist>
</record>

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Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials

Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials

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