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Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)

Identifieur interne : 001193 ( Main/Exploration ); précédent : 001192; suivant : 001194

Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)

Auteurs : He-Yang Liu [République populaire de Chine] ; Kun Cao [République populaire de Chine] ; Zhen Yao [République populaire de Chine] ; Bo-Geng Li [République populaire de Chine] ; Guo-Hua Hu [France]

Source :

Journal of Applied Polymer Science [ 0021-8995 ] ; 2007-05-15.

RBID : ISTEX:768997C371A428BE44114C29101495698FC5132A

Descripteurs français

Pascal (Inist)
- Acide copolymère, Etude expérimentale, Imidation, Maléamique acide copolymère, Maléimide(N-phényl) copolymère, Maléique anhydride copolymère, Maléique dérivé copolymère, Modification chimique, Relation structure propriété, Styrène copolymère, Température transition vitreuse.
Wicri :
- topic : Anhydride, Polymère.

English descriptors

Abstract

The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007

Url:

https://api.istex.fr/document/768997C371A428BE44114C29101495698FC5132A/fulltext/pdf

DOI: 10.1002/app.25917

Affiliations:

Le document en format XML

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<term>Appl</term>
<term>Appl polym</term>
<term>Bipolymers</term>
<term>Chemical engineering</term>
<term>Chemical modification</term>
<term>Chemical structures</term>
<term>Contract grant sponsor</term>
<term>Copolymer</term>
<term>Differential scanning calorimetry</term>
<term>Experimental data</term>
<term>Experimental study</term>
<term>Ftir spectra</term>
<term>Glass transition temperature</term>
<term>Heating rate</term>
<term>Imidation</term>
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<term>Imidization mechanism</term>
<term>Imidization products</term>
<term>Imidization samples</term>
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<term>Maleamic acid</term>
<term>Maleic anhydride</term>
<term>Maleic anhydride copolymer</term>
<term>Maleic derivative copolymer</term>
<term>Maleimide</term>
<term>Molecular weight</term>
<term>Polym</term>
<term>Polym bull</term>
<term>Polymer</term>
<term>Polymer science</term>
<term>Property structure relationship</term>
<term>Reactivity ratios</term>
<term>Rigid phenyl rings</term>
<term>Snpma</term>
<term>Snpmi</term>
<term>Snpmi bipolymers</term>
<term>Styrene copolymer</term>
<term>Terpolymer</term>
<term>Various compositions</term>
<term>Various imidization products</term>
<term>Weight fraction</term>
<term>Wiley periodicals</term>
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<term>Etude expérimentale</term>
<term>Imidation</term>
<term>Maléamique acide copolymère</term>
<term>Maléimide(N-phényl) copolymère</term>
<term>Maléique anhydride copolymère</term>
<term>Maléique dérivé copolymère</term>
<term>Modification chimique</term>
<term>Relation structure propriété</term>
<term>Styrène copolymère</term>
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<term>Chemical structures</term>
<term>Contract grant sponsor</term>
<term>Copolymer</term>
<term>Differential scanning calorimetry</term>
<term>Experimental data</term>
<term>Ftir spectra</term>
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<term>Imidization</term>
<term>Imidization mechanism</term>
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<front><div type="abstract" xml:lang="en">The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007</div>
</front>
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Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)

Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)

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Descripteurs français

English descriptors

Abstract

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