Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)
Identifieur interne : 000A68 ( Istex/Corpus ); précédent : 000A67; suivant : 000A69Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)
Auteurs : He-Yang Liu ; Kun Cao ; Zhen Yao ; Bo-Geng Li ; Guo-Hua HuSource :
- Journal of Applied Polymer Science [ 0021-8995 ] ; 2007-05-15.
English descriptors
- KwdEn :
- Anhydride, Appl, Appl polym, Bipolymers, Chemical engineering, Chemical structures, Contract grant sponsor, Copolymer, Differential scanning calorimetry, Experimental data, Ftir spectra, Heating rate, Imidization, Imidization mechanism, Imidization products, Imidization samples, Imidized products, Macromolecule, Maleamic, Maleamic acid, Maleic anhydride, Maleimide, Molecular weight, Polym, Polym bull, Polymer, Polymer science, Reactivity ratios, Rigid phenyl rings, Snpma, Snpmi, Snpmi bipolymers, Terpolymer, Various compositions, Various imidization products, Weight fraction, Wiley periodicals.
- Teeft :
- Anhydride, Appl, Appl polym, Bipolymers, Chemical engineering, Chemical structures, Contract grant sponsor, Copolymer, Differential scanning calorimetry, Experimental data, Ftir spectra, Heating rate, Imidization, Imidization mechanism, Imidization products, Imidization samples, Imidized products, Macromolecule, Maleamic, Maleamic acid, Maleic anhydride, Maleimide, Molecular weight, Polym, Polym bull, Polymer, Polymer science, Reactivity ratios, Rigid phenyl rings, Snpma, Snpmi, Snpmi bipolymers, Terpolymer, Various compositions, Various imidization products, Weight fraction, Wiley periodicals.
Abstract
The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007
Url:
DOI: 10.1002/app.25917
Links to Exploration step
ISTEX:768997C371A428BE44114C29101495698FC5132ALe document en format XML
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xml:id="author-0000"><persName><forename type="first">He‐Yang</forename><surname>Liu</surname></persName><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0001" role="corresp"><persName><forename type="first">Kun</forename><surname>Cao</surname></persName><email>kcao@che.zju.edu.cn</email><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China<address><country key="CN"></country></address></affiliation><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China===</affiliation></author><author xml:id="author-0002"><persName><forename type="first">Zhen</forename><surname>Yao</surname></persName><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Bo‐Geng</forename><surname>Li</surname></persName><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0004"><persName><forename type="first">Guo‐Hua</forename><surname>Hu</surname></persName><affiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 Rue Grandville, BP 20451, 54001 Nancy Cedex, France<address><country key="FR"></country></address></affiliation><affiliation>Institut Universitaire de France, Maison des Universités, 103 Boulevard Saint‐Michel, 75005 Paris, France<address><country key="FR"></country></address></affiliation></author><idno type="istex">768997C371A428BE44114C29101495698FC5132A</idno><idno type="ark">ark:/67375/WNG-XT5559N0-G</idno><idno type="DOI">10.1002/app.25917</idno><idno type="unit">APP25917</idno><idno type="toTypesetVersion">file:APP.APP25917.pdf</idno></analytic><monogr><title level="j" type="main">Journal of Applied Polymer Science</title><title level="j" type="alt">JOURNAL OF APPLIED POLYMER SCIENCE</title><idno type="pISSN">0021-8995</idno><idno type="eISSN">1097-4628</idno><idno type="book-DOI">10.1002/(ISSN)1097-4628</idno><idno type="book-part-DOI">10.1002/app.v104:4</idno><idno type="product">APP</idno><imprint><biblScope unit="vol">104</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="2418">2418</biblScope><biblScope unit="page" to="2422">2422</biblScope><biblScope unit="page-count">5</biblScope><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>Hoboken</pubPlace><date type="published" when="2007-05-15"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>The imidization of poly(styrene‐<hi rend="italic">co</hi>‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (<hi rend="italic">T<hi rend="subscript">g</hi></hi>'s) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, <hi rend="italic">N</hi>‐phenylmaleamic acid, and <hi rend="italic">N</hi>‐phenylmaleimide to <hi rend="italic">T<hi rend="subscript">g</hi></hi> were examined. <hi rend="italic">T<hi rend="subscript">g</hi></hi> increased in the order of SMA < styrene–<hi rend="italic">N</hi>‐phenyl maleimide copolymer < styrene–<hi rend="italic">N</hi>‐phenyl maleamic acid copolymer and followed the Fox equation. <hi rend="italic">T<hi rend="subscript">g</hi></hi> of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007</p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">poly(styrene‐<hi rend="italic">co</hi>‐maleic anhydride)</term><term xml:id="kwd2">imidization</term><term xml:id="kwd3">glass‐transition temperature</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/768997C371A428BE44114C29101495698FC5132A/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Wiley Subscription Services, Inc., A Wiley Company</publisherName><publisherLoc>Hoboken</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1097-4628</doi><issn type="print">0021-8995</issn><issn type="electronic">1097-4628</issn><idGroup><id type="product" value="APP"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="JOURNAL OF APPLIED POLYMER SCIENCE">Journal of Applied Polymer Science</title><title type="short">J. 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Sci.</title></titleGroup></publicationMeta><publicationMeta level="part" position="40"><doi origin="wiley" registered="yes">10.1002/app.v104:4</doi><numberingGroup><numbering type="journalVolume" number="104">104</numbering><numbering type="journalIssue">4</numbering></numberingGroup><coverDate startDate="2007-05-15">15 May 2007</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="230" status="forIssue"><doi origin="wiley" registered="yes">10.1002/app.25917</doi><idGroup><id type="unit" value="APP25917"></id></idGroup><countGroup><count type="pageTotal" number="5"></count></countGroup><copyright ownership="publisher">Copyright © 2007 Wiley Periodicals, Inc.</copyright><eventGroup><event type="manuscriptReceived" date="2006-04-12"></event><event type="manuscriptAccepted" date="2006-12-04"></event><event type="firstOnline" date="2007-02-27"></event><event type="publishedOnlineFinalForm" date="2007-02-27"></event><event type="xmlConverted" 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href="file:APP.APP25917.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="7"></count><count type="tableTotal" number="4"></count><count type="referenceTotal" number="18"></count><count type="wordTotal" number="2366"></count></countGroup><titleGroup><title type="main" xml:lang="en">Variations of the glass‐transition temperature in the imidization of poly(styrene‐<i>co</i>‐maleic anhydride)</title><title type="short" xml:lang="en">Variations of the Glass‐Transition Temperature</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>He‐Yang</givenNames><familyName>Liu</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><givenNames>Kun</givenNames><familyName>Cao</familyName></personName><contactDetails><email>kcao@che.zju.edu.cn</email></contactDetails></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Zhen</givenNames><familyName>Yao</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Bo‐Geng</givenNames><familyName>Li</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af2 #af3"><personName><givenNames>Guo‐Hua</givenNames><familyName>Hu</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="CN" type="organization"><unparsedAffiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 Rue Grandville, BP 20451, 54001 Nancy Cedex, France</unparsedAffiliation></affiliation><affiliation xml:id="af3" countryCode="FR" type="organization"><unparsedAffiliation>Institut Universitaire de France, Maison des Universités, 103 Boulevard Saint‐Michel, 75005 Paris, France</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">poly(styrene‐<i>co</i>‐maleic anhydride)</keyword><keyword xml:id="kwd2">imidization</keyword><keyword xml:id="kwd3">glass‐transition temperature</keyword></keywordGroup><fundingInfo><fundingAgency>National Natural Science Foundation of China</fundingAgency><fundingNumber>50390097</fundingNumber><fundingNumber>20310285</fundingNumber></fundingInfo><fundingInfo><fundingAgency>Association Franco‐Chinoise pour la Recherche Scientifique et Technique</fundingAgency><fundingNumber>PRA Mx02‐07</fundingNumber></fundingInfo><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The imidization of poly(styrene‐<i>co</i>‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (<i>T<sub>g</sub></i>'s) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, <i>N</i>‐phenylmaleamic acid, and <i>N</i>‐phenylmaleimide to <i>T<sub>g</sub></i> were examined. <i>T<sub>g</sub></i> increased in the order of SMA < styrene–<i>N</i>‐phenyl maleimide copolymer < styrene–<i>N</i>‐phenyl maleamic acid copolymer and followed the Fox equation. <i>T<sub>g</sub></i> of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Variations of the Glass‐Transition Temperature</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)</title></titleInfo><name type="personal"><namePart type="given">He‐Yang</namePart><namePart type="family">Liu</namePart><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Kun</namePart><namePart type="family">Cao</namePart><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China</affiliation><affiliation>E-mail: kcao@che.zju.edu.cn</affiliation><affiliation>Correspondence address: State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China===</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Zhen</namePart><namePart type="family">Yao</namePart><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Bo‐Geng</namePart><namePart type="family">Li</namePart><affiliation>State Key Laboratory of Chemical Engineering (Polymerization Division), Institute of Polymer Engineering, Department of Chemical and Biochemical Engineering, College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Guo‐Hua</namePart><namePart type="family">Hu</namePart><affiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 Rue Grandville, BP 20451, 54001 Nancy Cedex, France</affiliation><affiliation>Institut Universitaire de France, Maison des Universités, 103 Boulevard Saint‐Michel, 75005 Paris, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><place><placeTerm type="text">Hoboken</placeTerm></place><dateIssued encoding="w3cdtf">2007-05-15</dateIssued><dateCaptured encoding="w3cdtf">2006-04-12</dateCaptured><dateValid encoding="w3cdtf">2006-12-04</dateValid><copyrightDate encoding="w3cdtf">2007</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">7</extent><extent unit="tables">4</extent><extent unit="references">18</extent><extent unit="words">2366</extent></physicalDescription><abstract lang="en">The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007</abstract><note type="funding">National Natural Science Foundation of China - No. 50390097; No. 20310285; </note><note type="funding">Association Franco‐Chinoise pour la Recherche Scientifique et Technique - No. PRA Mx02‐07; </note><subject lang="en"><genre>keywords</genre><topic>poly(styrene‐co‐maleic anhydride)</topic><topic>imidization</topic><topic>glass‐transition temperature</topic></subject><relatedItem type="host"><titleInfo><title>Journal of Applied Polymer Science</title></titleInfo><titleInfo type="abbreviated"><title>J. Appl. Polym. Sci.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><identifier type="ISSN">0021-8995</identifier><identifier type="eISSN">1097-4628</identifier><identifier type="DOI">10.1002/(ISSN)1097-4628</identifier><identifier type="PublisherID">APP</identifier><part><date>2007</date><detail type="volume"><caption>vol.</caption><number>104</number></detail><detail type="issue"><caption>no.</caption><number>4</number></detail><extent unit="pages"><start>2418</start><end>2422</end><total>5</total></extent></part></relatedItem><identifier type="istex">768997C371A428BE44114C29101495698FC5132A</identifier><identifier type="ark">ark:/67375/WNG-XT5559N0-G</identifier><identifier type="DOI">10.1002/app.25917</identifier><identifier type="ArticleID">APP25917</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2007 Wiley Periodicals, Inc.</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Wiley Subscription Services, Inc., A Wiley Company</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/768997C371A428BE44114C29101495698FC5132A/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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