Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)
Identifieur interne : 001193 ( Main/Exploration ); précédent : 001192; suivant : 001194Variations of the glass‐transition temperature in the imidization of poly(styrene‐co‐maleic anhydride)
Auteurs : He-Yang Liu [République populaire de Chine] ; Kun Cao [République populaire de Chine] ; Zhen Yao [République populaire de Chine] ; Bo-Geng Li [République populaire de Chine] ; Guo-Hua Hu [France]Source :
- Journal of Applied Polymer Science [ 0021-8995 ] ; 2007-05-15.
Descripteurs français
- Pascal (Inist)
- Wicri :
English descriptors
- KwdEn :
- Acid copolymer, Anhydride, Appl, Appl polym, Bipolymers, Chemical engineering, Chemical modification, Chemical structures, Contract grant sponsor, Copolymer, Differential scanning calorimetry, Experimental data, Experimental study, Ftir spectra, Glass transition temperature, Heating rate, Imidation, Imidization, Imidization mechanism, Imidization products, Imidization samples, Imidized products, Macromolecule, Maleamic, Maleamic acid, Maleic anhydride, Maleic anhydride copolymer, Maleic derivative copolymer, Maleimide, Molecular weight, Polym, Polym bull, Polymer, Polymer science, Property structure relationship, Reactivity ratios, Rigid phenyl rings, Snpma, Snpmi, Snpmi bipolymers, Styrene copolymer, Terpolymer, Various compositions, Various imidization products, Weight fraction, Wiley periodicals.
- Teeft :
- Anhydride, Appl, Appl polym, Bipolymers, Chemical engineering, Chemical structures, Contract grant sponsor, Copolymer, Differential scanning calorimetry, Experimental data, Ftir spectra, Heating rate, Imidization, Imidization mechanism, Imidization products, Imidization samples, Imidized products, Macromolecule, Maleamic, Maleamic acid, Maleic anhydride, Maleimide, Molecular weight, Polym, Polym bull, Polymer, Polymer science, Reactivity ratios, Rigid phenyl rings, Snpma, Snpmi, Snpmi bipolymers, Terpolymer, Various compositions, Various imidization products, Weight fraction, Wiley periodicals.
Abstract
The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007
Url:
DOI: 10.1002/app.25917
Affiliations:
- France, République populaire de Chine
- Grand Est, Lorraine (région), Zhejiang, Île-de-France
- Hangzhou, Nancy, Paris
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine, Université de Zhejiang
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Le document en format XML
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<term>Appl polym</term>
<term>Bipolymers</term>
<term>Chemical engineering</term>
<term>Chemical modification</term>
<term>Chemical structures</term>
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<term>Copolymer</term>
<term>Differential scanning calorimetry</term>
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<term>Experimental study</term>
<term>Ftir spectra</term>
<term>Glass transition temperature</term>
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<term>Maleic anhydride</term>
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<term>Maleic derivative copolymer</term>
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<front><div type="abstract" xml:lang="en">The imidization of poly(styrene‐co‐maleic anhydride) (SMA) was conducted, and the glass‐transition temperatures (Tg's) of the resulting products were measured with differential scanning calorimetry. The contributions from functional groups of maleic anhydride, N‐phenylmaleamic acid, and N‐phenylmaleimide to Tg were examined. Tg increased in the order of SMA < styrene–N‐phenyl maleimide copolymer < styrene–N‐phenyl maleamic acid copolymer and followed the Fox equation. Tg of the imidized products of SMA could be controlled by the conversions of both ring‐opening and ring‐closing reactions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2418–2422, 2007</div>
</front>
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