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Fe3O4@ZIF-8: magnetically recoverable catalysts by loading Fe3O4 nanoparticles inside a zinc imidazolate framework.

Identifieur interne : 000250 ( Main/Exploration ); précédent : 000249; suivant : 000251

Fe3O4@ZIF-8: magnetically recoverable catalysts by loading Fe3O4 nanoparticles inside a zinc imidazolate framework.

Auteurs : Aleksandra Schejn [France] ; Thomas Mazet ; Véronique Falk ; Lavinia Balan ; Lionel Aranda ; Ghouti Medjahdi ; Raphaël Schneider

Source :

RBID : pubmed:25955275

English descriptors

Abstract

A simple methodology for encapsulating ca. 10 nm-sized superparamagnetic Fe3O4 nanoparticles in zeolitic imidazolate frameworks (ZIF-8) crystals was developed. The corresponding Fe3O4@ZIF-8 heterostructured material exhibits bifunctional properties with both high magnetization (Fe3O4) and high thermal stability, large specific surface, and catalytic properties (ZIF-8). The Fe3O4@ZIF-8 catalyst exhibits fair separation ability and reusability, which can be repeatedly applied for Knoevenagel condensations and Huisgen cycloadditions for at least ten successive cycles.

Url:
DOI: 10.1039/c5dt01191d
PubMed: 25955275


Affiliations:


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