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Fe3O4@ZIF-8: magnetically recoverable catalysts by loading Fe3O4 nanoparticles inside a zinc imidazolate framework.

Identifieur interne : 000026 ( PubMed/Curation ); précédent : 000025; suivant : 000027

Fe3O4@ZIF-8: magnetically recoverable catalysts by loading Fe3O4 nanoparticles inside a zinc imidazolate framework.

Auteurs : Aleksandra Schejn [France] ; Thomas Mazet ; Véronique Falk ; Lavinia Balan ; Lionel Aranda ; Ghouti Medjahdi ; Raphaël Schneider

Source :

RBID : pubmed:25955275

Abstract

A simple methodology for encapsulating ca. 10 nm-sized superparamagnetic Fe3O4 nanoparticles in zeolitic imidazolate frameworks (ZIF-8) crystals was developed. The corresponding Fe3O4@ZIF-8 heterostructured material exhibits bifunctional properties with both high magnetization (Fe3O4) and high thermal stability, large specific surface, and catalytic properties (ZIF-8). The Fe3O4@ZIF-8 catalyst exhibits fair separation ability and reusability, which can be repeatedly applied for Knoevenagel condensations and Huisgen cycloadditions for at least ten successive cycles.

DOI: 10.1039/c5dt01191d
PubMed: 25955275

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pubmed:25955275

Le document en format XML

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