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Real time X-ray diffraction study of the formation by SHS of the phases γ′ and H in the ternary system AlNiTi

Identifieur interne : 001663 ( Istex/Corpus ); précédent : 001662; suivant : 001664

Real time X-ray diffraction study of the formation by SHS of the phases γ′ and H in the ternary system AlNiTi

Auteurs : J. F. Javel ; M. Dirand ; J. J. Kuntz ; F. Z. Nassik ; J. C. Gachon

Source :

RBID : ISTEX:ED68500762CD65CCD6619FC9AF1F4C84469F68CF

English descriptors

Abstract

Abstract: The formation of two compounds (Al0.20Ni0.75Ti0.05 (γ′) and Al0.27Ni0.50Ti0.23 (H)) of the ternary system AlNiTi by solid-state high temperature synthesis was investigated by time-resolved X-ray diffraction using a synchroton X-ray beam and a fast detection system to monitor the phase transformations. With a time resolution of 30 ms, it was possible to observe the passage of the combustion front and to know the different steps of the phase formation. These experiments have been completed by electron probe microanalyses of samples in which the reaction had been frozen. They showed concentration gradients and transition states.

Url:
DOI: 10.1016/S0925-8388(96)02592-3

Links to Exploration step

ISTEX:ED68500762CD65CCD6619FC9AF1F4C84469F68CF

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<ce:author>
<ce:given-name>F.Z.</ce:given-name>
<ce:surname>Nassik</ce:surname>
<ce:cross-ref refid="AFF1">
<ce:sup>a</ce:sup>
</ce:cross-ref>
</ce:author>
<ce:author>
<ce:given-name>J.C.</ce:given-name>
<ce:surname>Gachon</ce:surname>
<ce:cross-ref refid="AFF1">
<ce:sup>a</ce:sup>
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<ce:affiliation id="AFF1">
<ce:label>a</ce:label>
<ce:textfn>URA 158, LCSM, Service de Thermodynamique Métallurgique, Université Henri Poincaré Nancy I, BP 239, 54506 Vandoeuvre Cedex, France</ce:textfn>
</ce:affiliation>
<ce:affiliation id="AFF2">
<ce:label>b</ce:label>
<ce:textfn>LTCA, ENSIC, INPL, BP 451, 54001 Nancy Cedex, France</ce:textfn>
</ce:affiliation>
<ce:correspondence id="COR1">
<ce:label></ce:label>
<ce:text>Corresponding author. Tel.: (+19 33) 83 91 25 76; fax: (+19 33) 83 9125 79</ce:text>
</ce:correspondence>
</ce:author-group>
<ce:abstract>
<ce:section-title>Abstract</ce:section-title>
<ce:abstract-sec>
<ce:simple-para>The formation of two compounds (Al
<ce:inf>0.20</ce:inf>
Ni
<ce:inf>0.75</ce:inf>
Ti
<ce:inf>0.05</ce:inf>
(γ′) and Al
<ce:inf>0.27</ce:inf>
Ni
<ce:inf>0.50</ce:inf>
Ti
<ce:inf>0.23</ce:inf>
(H)) of the ternary system AlNiTi by solid-state high temperature synthesis was investigated by time-resolved X-ray diffraction using a synchroton X-ray beam and a fast detection system to monitor the phase transformations. With a time resolution of 30 ms, it was possible to observe the passage of the combustion front and to know the different steps of the phase formation. These experiments have been completed by electron probe microanalyses of samples in which the reaction had been frozen. They showed concentration gradients and transition states.</ce:simple-para>
</ce:abstract-sec>
</ce:abstract>
<ce:keywords>
<ce:section-title>Keywords</ce:section-title>
<ce:keyword>
<ce:text>SHS</ce:text>
</ce:keyword>
<ce:keyword>
<ce:text>Real time X-ray diffraction</ce:text>
</ce:keyword>
<ce:keyword>
<ce:text>Intermetallics</ce:text>
</ce:keyword>
</ce:keywords>
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<title>Real time X-ray diffraction study of the formation by SHS of the phases γ′ and H in the ternary system AlNiTi</title>
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<title>Real time X-ray diffraction study of the formation by SHS of the phases γ′ and H in the ternary system AlNiTi</title>
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<affiliation>E-mail: gachon@ltm.u-nancy.fr</affiliation>
<affiliation>URA 158, LCSM, Service de Thermodynamique Métallurgique, Université Henri Poincaré Nancy I, BP 239, 54506 Vandoeuvre Cedex, France</affiliation>
<description>Corresponding author. Tel.: (+19 33) 83 91 25 76; fax: (+19 33) 83 9125 79</description>
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<abstract lang="en">Abstract: The formation of two compounds (Al0.20Ni0.75Ti0.05 (γ′) and Al0.27Ni0.50Ti0.23 (H)) of the ternary system AlNiTi by solid-state high temperature synthesis was investigated by time-resolved X-ray diffraction using a synchroton X-ray beam and a fast detection system to monitor the phase transformations. With a time resolution of 30 ms, it was possible to observe the passage of the combustion front and to know the different steps of the phase formation. These experiments have been completed by electron probe microanalyses of samples in which the reaction had been frozen. They showed concentration gradients and transition states.</abstract>
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<topic>Real time X-ray diffraction</topic>
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<identifier type="ISSN">0925-8388</identifier>
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