Synthesis of a new styrene monomer: the 3-chloro-4-nitrostyrene
Identifieur interne : 000590 ( Istex/Corpus ); précédent : 000589; suivant : 000591Synthesis of a new styrene monomer: the 3-chloro-4-nitrostyrene
Auteurs : A. Jonquières ; D. Roizard ; P. LochonSource :
- Polymer Bulletin [ 0170-0839 ] ; 1994-09-01.
English descriptors
- KwdEn :
- Aqueous solution, Bulk polymerisation, Bulk polymerization, Chem, Chemical modification, Complex catalyst, Conversion rate, Conversion rates, First order, Fractional distillation, Fractional vacuum distillation, Initiator, Initiator advn, Isomer, Molecular weight, Monomer, Nitro group position, Organic fractions, Overall reactivity, Phosphonium salt, Polymer, Polymer bulletin, Polymerisation, Reaction mixture, Reaction time, Room temperature, Short route, Side reactions, Sodium nitrite, Styrene monomer, Vinyl group.
- Teeft :
- Aqueous solution, Bulk polymerisation, Bulk polymerization, Chem, Chemical modification, Complex catalyst, Conversion rate, Conversion rates, First order, Fractional distillation, Fractional vacuum distillation, Initiator, Initiator advn, Isomer, Molecular weight, Monomer, Nitro group position, Organic fractions, Overall reactivity, Phosphonium salt, Polymer, Polymer bulletin, Polymerisation, Reaction mixture, Reaction time, Room temperature, Short route, Side reactions, Sodium nitrite, Styrene monomer, Vinyl group.
Abstract
Summary: A satisfactory synthesis route to a new monomer, the 3-chloro-4-nitrostyrene (3-CNS) is described. The results of free radical polymerisation experiments (limit of conversion, global kinetics) are reported by comparison with those of the isomer 4-chloro-3-nitrostyrene (4-CNS). They show the great influence of the nitro group position which markedly increases the reactivity of 3-CNS.
Url:
DOI: 10.1007/BF00293481
Links to Exploration step
ISTEX:7AFC573CCBE1BF8B6EFB202C958F8A97CF28AF35Le document en format XML
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The results of free radical polymerisation experiments (limit of conversion, global kinetics) are reported by comparison with those of the isomer 4-chloro-3-nitrostyrene (4-CNS). 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ContainsESM="No"><ArticleID>BF00293481</ArticleID><ArticleDOI>10.1007/BF00293481</ArticleDOI><ArticleSequenceNumber>2</ArticleSequenceNumber><ArticleTitle Language="En">Synthesis of a new styrene monomer: the 3-chloro-4-nitrostyrene</ArticleTitle><ArticleSubTitle Language="En">Free radical polymerization reactivity compared to 4-chloro-3-nitrostyrene</ArticleSubTitle><ArticleFirstPage>389</ArticleFirstPage><ArticleLastPage>395</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2004</Year><Month>8</Month><Day>18</Day></RegistrationDate><Received><Year>1994</Year><Month>5</Month><Day>31</Day></Received><Revised><Year>1994</Year><Month>7</Month><Day>1</Day></Revised><Accepted><Year>1994</Year><Month>7</Month><Day>1</Day></Accepted></ArticleHistory><ArticleCopyright><CopyrightHolderName>Springer-Verlag</CopyrightHolderName><CopyrightYear>1994</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant Grant="Restricted"></ESMGrant></ArticleGrants><ArticleContext><JournalID>289</JournalID><VolumeIDStart>33</VolumeIDStart><VolumeIDEnd>33</VolumeIDEnd><IssueIDStart>4</IssueIDStart><IssueIDEnd>4</IssueIDEnd></ArticleContext></ArticleInfo><ArticleHeader><AuthorGroup><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>A.</GivenName><FamilyName>Jonquières</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>D.</GivenName><FamilyName>Roizard</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>P.</GivenName><FamilyName>Lochon</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgDivision>Laboratoire de Chimie Physique Macromoléculaire, URA CNRS 494</OrgDivision><OrgName>ENSIC-INPL</OrgName><OrgAddress><Street>1, rue Grandville</Street><Postbox>BP 451</Postbox><Postcode>F-54001</Postcode><City>Nancy Cedex</City><Country>France</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Summary</Heading><Para>A satisfactory synthesis route to a new monomer, the 3-chloro-4-nitrostyrene (3-CNS) is described. The results of free radical polymerisation experiments (limit of conversion, global kinetics) are reported by comparison with those of the isomer 4-chloro-3-nitrostyrene (4-CNS). They show the great influence of the nitro group position which markedly increases the reactivity of 3-CNS.</Para></Abstract></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Synthesis of a new styrene monomer: the 3-chloro-4-nitrostyrene</title><subTitle>Free radical polymerization reactivity compared to 4-chloro-3-nitrostyrene</subTitle></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Synthesis of a new styrene monomer: the 3-chloro-4-nitrostyrene</title><subTitle>Free radical polymerization reactivity compared to 4-chloro-3-nitrostyrene</subTitle></titleInfo><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Jonquières</namePart><affiliation>Laboratoire de Chimie Physique Macromoléculaire, URA CNRS 494, ENSIC-INPL, 1, rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D.</namePart><namePart type="family">Roizard</namePart><affiliation>Laboratoire de Chimie Physique Macromoléculaire, URA CNRS 494, ENSIC-INPL, 1, rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">P.</namePart><namePart type="family">Lochon</namePart><affiliation>Laboratoire de Chimie Physique Macromoléculaire, URA CNRS 494, ENSIC-INPL, 1, rue Grandville, BP 451, F-54001, Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>Springer-Verlag</publisher><place><placeTerm type="text">Berlin/Heidelberg</placeTerm></place><dateCreated encoding="w3cdtf">1994-05-31</dateCreated><dateIssued encoding="w3cdtf">1994-09-01</dateIssued><dateIssued encoding="w3cdtf">1994</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract lang="en">Summary: A satisfactory synthesis route to a new monomer, the 3-chloro-4-nitrostyrene (3-CNS) is described. The results of free radical polymerisation experiments (limit of conversion, global kinetics) are reported by comparison with those of the isomer 4-chloro-3-nitrostyrene (4-CNS). They show the great influence of the nitro group position which markedly increases the reactivity of 3-CNS.</abstract><relatedItem type="host"><titleInfo><title>Polymer Bulletin</title></titleInfo><titleInfo type="abbreviated"><title>Polymer Bulletin</title></titleInfo><genre type="journal" displayLabel="Archive Journal" authority="ISTEX" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>Springer</publisher><dateIssued encoding="w3cdtf">1994-09-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Polymer Sciences</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Condensed Matter and Material Sciences</topic><topic>Materials Processing, Characterization, and Design</topic></subject><identifier type="ISSN">0170-0839</identifier><identifier type="eISSN">1436-2449</identifier><identifier type="JournalID">289</identifier><identifier type="IssueArticleCount">19</identifier><identifier type="VolumeIssueCount">6</identifier><part><date>1994</date><detail type="volume"><number>33</number><caption>vol.</caption></detail><detail type="issue"><number>4</number><caption>no.</caption></detail><extent unit="pages"><start>389</start><end>395</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></relatedItem><identifier type="istex">7AFC573CCBE1BF8B6EFB202C958F8A97CF28AF35</identifier><identifier type="ark">ark:/67375/1BB-HWMC9HHN-V</identifier><identifier type="DOI">10.1007/BF00293481</identifier><identifier type="ArticleID">BF00293481</identifier><identifier type="ArticleID">Art2</identifier><accessCondition type="use and reproduction" contentType="copyright">Springer-Verlag, 1994</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</recordContentSource><recordOrigin>Springer-Verlag, 1994</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/7AFC573CCBE1BF8B6EFB202C958F8A97CF28AF35/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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