Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C
Identifieur interne : 000077 ( Istex/Corpus ); précédent : 000076; suivant : 000078Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C
Auteurs : F. Battin-Leclerc ; F. Baronnet ; G. Paternotte ; J. P Leclerc ; R. GourhanSource :
- Journal of Analytical and Applied Pyrolysis [ 0165-2370 ] ; 2000.
English descriptors
- KwdEn :
- Anal, Appl, Carbon dioxide, Carbon monoxide, Carbon tetrachloride, Chemical weapons, Chloropicrin, Diphosgene, Experimental results, Initial pressure, Maximum temperature, Minor product, Monoxide, Nitrogen oxide, Partial pressure, Partial pressures, Phosgene, Pyrolysis, Reaction times, Residence time, Temperature range, Thermal decomposition, Torr, Total pressure, Trichloromethyl radicals.
- Teeft :
- Anal, Appl, Carbon dioxide, Carbon monoxide, Carbon tetrachloride, Chemical weapons, Chloropicrin, Diphosgene, Experimental results, Initial pressure, Maximum temperature, Minor product, Monoxide, Nitrogen oxide, Partial pressure, Partial pressures, Phosgene, Pyrolysis, Reaction times, Residence time, Temperature range, Thermal decomposition, Torr, Total pressure, Trichloromethyl radicals.
Abstract
Abstract: The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.
Url:
DOI: 10.1016/S0165-2370(99)00052-2
Links to Exploration step
ISTEX:18EB059E728EA4443D04D09E2B60F9960654C19ELe document en format XML
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Paternotte</name><affiliation><mods:affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Leclerc, J P" sort="Leclerc, J P" uniqKey="Leclerc J" first="J. P" last="Leclerc">J. P Leclerc</name><affiliation><mods:affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Gourhan, R" sort="Gourhan, R" uniqKey="Gourhan R" first="R" last="Gourhan">R. 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Battin-Leclerc</name><affiliation><mods:affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Baronnet, F" sort="Baronnet, F" uniqKey="Baronnet F" first="F" last="Baronnet">F. Baronnet</name><affiliation><mods:affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Paternotte, G" sort="Paternotte, G" uniqKey="Paternotte G" first="G" last="Paternotte">G. Paternotte</name><affiliation><mods:affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Leclerc, J P" sort="Leclerc, J P" uniqKey="Leclerc J" first="J. P" last="Leclerc">J. 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Gourhan</name><affiliation><mods:affiliation>501000 Cherbourg, France</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Analytical and Applied Pyrolysis</title><title level="j" type="abbrev">JAAP</title><idno type="ISSN">0165-2370</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000">2000</date><biblScope unit="volume">53</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="95">95</biblScope><biblScope unit="page" to="105">105</biblScope></imprint><idno type="ISSN">0165-2370</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0165-2370</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Anal</term><term>Appl</term><term>Carbon dioxide</term><term>Carbon monoxide</term><term>Carbon tetrachloride</term><term>Chemical weapons</term><term>Chloropicrin</term><term>Diphosgene</term><term>Experimental results</term><term>Initial pressure</term><term>Maximum temperature</term><term>Minor product</term><term>Monoxide</term><term>Nitrogen oxide</term><term>Partial pressure</term><term>Partial pressures</term><term>Phosgene</term><term>Pyrolysis</term><term>Reaction times</term><term>Residence time</term><term>Temperature range</term><term>Thermal decomposition</term><term>Torr</term><term>Total pressure</term><term>Trichloromethyl radicals</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Anal</term><term>Appl</term><term>Carbon dioxide</term><term>Carbon monoxide</term><term>Carbon tetrachloride</term><term>Chemical weapons</term><term>Chloropicrin</term><term>Diphosgene</term><term>Experimental results</term><term>Initial pressure</term><term>Maximum temperature</term><term>Minor product</term><term>Monoxide</term><term>Nitrogen oxide</term><term>Partial pressure</term><term>Partial pressures</term><term>Phosgene</term><term>Pyrolysis</term><term>Reaction times</term><term>Residence time</term><term>Temperature range</term><term>Thermal decomposition</term><term>Torr</term><term>Total pressure</term><term>Trichloromethyl radicals</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.</div></front></TEI><istex><corpusName>elsevier</corpusName><keywords><teeft><json:string>pyrolysis</json:string><json:string>diphosgene</json:string><json:string>chloropicrin</json:string><json:string>phosgene</json:string><json:string>torr</json:string><json:string>initial pressure</json:string><json:string>anal</json:string><json:string>appl</json:string><json:string>monoxide</json:string><json:string>carbon monoxide</json:string><json:string>thermal decomposition</json:string><json:string>residence time</json:string><json:string>carbon tetrachloride</json:string><json:string>total pressure</json:string><json:string>partial pressures</json:string><json:string>chemical weapons</json:string><json:string>minor product</json:string><json:string>experimental results</json:string><json:string>carbon dioxide</json:string><json:string>partial pressure</json:string><json:string>nitrogen oxide</json:string><json:string>maximum temperature</json:string><json:string>reaction times</json:string><json:string>temperature range</json:string><json:string>trichloromethyl radicals</json:string></teeft></keywords><author><json:item><name>F Battin-Leclerc</name><affiliations><json:string>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</json:string></affiliations></json:item><json:item><name>F Baronnet</name><affiliations><json:string>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</json:string></affiliations></json:item><json:item><name>G Paternotte</name><affiliations><json:string>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</json:string></affiliations></json:item><json:item><name>J.P Leclerc</name><affiliations><json:string>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</json:string></affiliations></json:item><json:item><name>R Gourhan</name><affiliations><json:string>501000 Cherbourg, France</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Chloropicrin</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Diphosgene</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Phosgene</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Thermal decomposition</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Chemical weapons</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Pyrolysis</value></json:item></subject><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.</abstract><qualityIndicators><score>3.93</score><pdfVersion>1.2</pdfVersion><pdfPageSize>541 x 687 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>6</keywordCount><abstractCharCount>754</abstractCharCount><pdfWordCount>2526</pdfWordCount><pdfCharCount>15198</pdfCharCount><pdfPageCount>11</pdfPageCount><abstractWordCount>117</abstractWordCount></qualityIndicators><title>Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</title><pii><json:string>S0165-2370(99)00052-2</json:string></pii><genre><json:string>research-article</json:string></genre><host><title>Journal of Analytical and Applied Pyrolysis</title><language><json:string>unknown</json:string></language><publicationDate>2000</publicationDate><issn><json:string>0165-2370</json:string></issn><pii><json:string>S0165-2370(00)X0036-8</json:string></pii><volume>53</volume><issue>1</issue><pages><first>95</first><last>105</last></pages><genre><json:string>journal</json:string></genre></host><categories><wos><json:string>science</json:string><json:string>spectroscopy</json:string><json:string>chemistry, analytical</json:string></wos><scienceMetrix><json:string>applied sciences</json:string><json:string>enabling & strategic technologies</json:string><json:string>energy</json:string></scienceMetrix><inist><json:string>sciences appliquees, technologies et medecines</json:string><json:string>sciences exactes et technologie</json:string><json:string>sciences appliquees</json:string><json:string>pollution</json:string></inist></categories><publicationDate>2000</publicationDate><copyrightDate>2000</copyrightDate><doi><json:string>10.1016/S0165-2370(99)00052-2</json:string></doi><id>18EB059E728EA4443D04D09E2B60F9960654C19E</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/18EB059E728EA4443D04D09E2B60F9960654C19E/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/18EB059E728EA4443D04D09E2B60F9960654C19E/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/18EB059E728EA4443D04D09E2B60F9960654C19E/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>©2000 Elsevier Science B.V.</p></availability><date>2000</date></publicationStmt><notesStmt><note type="content">Fig. 1: Typical profiles of pressure versus time for the thermal decomposition of chloropicrin. Initial pressure, 25 torr.</note><note type="content">Fig. 2: Conversion rate of chloropicrin versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 3: Product formation during the pyrolysis of chloropicrin versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 4: Products formation during the pyrolysis of diphosgene versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 5: Evolution of the total pressure and the partial pressures of COCl2 and CO with residence time during the pyrolysis of diphosgene at (a) 470°C, (b) 500°C and (c) 530°C. Initial pressure of diphosgene, 25 torr; dots are related to experiments and lines to simulations.</note><note type="content">Table 1: Summary of the main experimental resultsa</note><note type="content">Table 2: Mechanism for the thermal decomposition of phosgenea</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</title><author xml:id="author-0000"><persName><forename type="first">F</forename><surname>Battin-Leclerc</surname></persName><note type="correspondence"><p>Corresponding author</p></note><affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation></author><author xml:id="author-0001"><persName><forename type="first">F</forename><surname>Baronnet</surname></persName><affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation></author><author xml:id="author-0002"><persName><forename type="first">G</forename><surname>Paternotte</surname></persName><affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation></author><author xml:id="author-0003"><persName><forename type="first">J.P</forename><surname>Leclerc</surname></persName><affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation></author><author xml:id="author-0004"><persName><forename type="first">R</forename><surname>Gourhan</surname></persName><affiliation>501000 Cherbourg, France</affiliation></author><idno type="istex">18EB059E728EA4443D04D09E2B60F9960654C19E</idno><idno type="DOI">10.1016/S0165-2370(99)00052-2</idno><idno type="PII">S0165-2370(99)00052-2</idno></analytic><monogr><title level="j">Journal of Analytical and Applied Pyrolysis</title><title level="j" type="abbrev">JAAP</title><idno type="pISSN">0165-2370</idno><idno type="PII">S0165-2370(00)X0036-8</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000"></date><biblScope unit="volume">53</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="95">95</biblScope><biblScope unit="page" to="105">105</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2000</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.</p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>Keywords</head><item><term>Chloropicrin</term></item><item><term>Diphosgene</term></item><item><term>Phosgene</term></item><item><term>Thermal decomposition</term></item><item><term>Chemical weapons</term></item><item><term>Pyrolysis</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2000">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/18EB059E728EA4443D04D09E2B60F9960654C19E/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: ce:floats; body; tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"><istex:entity SYSTEM="gr1" NDATA="IMAGE" name="gr1"></istex:entity><istex:entity SYSTEM="gr2" NDATA="IMAGE" name="gr2"></istex:entity><istex:entity SYSTEM="gr3" NDATA="IMAGE" name="gr3"></istex:entity><istex:entity SYSTEM="gr4" NDATA="IMAGE" name="gr4"></istex:entity><istex:entity SYSTEM="gr5" NDATA="IMAGE" name="gr5"></istex:entity></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="en"><item-info><jid>JAAP</jid><aid>1186</aid><ce:pii>S0165-2370(99)00052-2</ce:pii><ce:doi>10.1016/S0165-2370(99)00052-2</ce:doi><ce:copyright type="full-transfer" year="2000">Elsevier Science B.V.</ce:copyright></item-info><head><ce:title>Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</ce:title><ce:author-group><ce:author><ce:given-name>F</ce:given-name><ce:surname>Battin-Leclerc</ce:surname><ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup></ce:cross-ref><ce:cross-ref refid="CORR1">*</ce:cross-ref></ce:author><ce:author><ce:given-name>F</ce:given-name><ce:surname>Baronnet</ce:surname><ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>G</ce:given-name><ce:surname>Paternotte</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>J.P</ce:given-name><ce:surname>Leclerc</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>R</ce:given-name><ce:surname>Gourhan</ce:surname><ce:cross-ref refid="AFF3"><ce:sup>c</ce:sup></ce:cross-ref></ce:author><ce:affiliation id="AFF1"><ce:label>a</ce:label><ce:textfn>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</ce:textfn></ce:affiliation><ce:affiliation id="AFF2"><ce:label>b</ce:label><ce:textfn>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</ce:textfn></ce:affiliation><ce:affiliation id="AFF3"><ce:label>c</ce:label><ce:textfn>501000 Cherbourg, France</ce:textfn></ce:affiliation><ce:correspondence id="CORR1"><ce:label>*</ce:label><ce:text>Corresponding author</ce:text></ce:correspondence></ce:author-group><ce:date-received day="23" month="2" year="1999"></ce:date-received><ce:date-accepted day="4" month="6" year="1999"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Chloropicrin</ce:text></ce:keyword><ce:keyword><ce:text>Diphosgene</ce:text></ce:keyword><ce:keyword><ce:text>Phosgene</ce:text></ce:keyword><ce:keyword><ce:text>Thermal decomposition</ce:text></ce:keyword><ce:keyword><ce:text>Chemical weapons</ce:text></ce:keyword><ce:keyword><ce:text>Pyrolysis</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530°C</title></titleInfo><name type="personal"><namePart type="given">F</namePart><namePart type="family">Battin-Leclerc</namePart><affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation><description>Corresponding author</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">F</namePart><namePart type="family">Baronnet</namePart><affiliation>DCPR-ENSIC-CNRS, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">G</namePart><namePart type="family">Paternotte</namePart><affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J.P</namePart><namePart type="family">Leclerc</namePart><affiliation>PROGEPI, 1, rue Grandville, BP 451-54001 Nancy Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">R</namePart><namePart type="family">Gourhan</namePart><affiliation>501000 Cherbourg, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">2000</dateIssued><copyrightDate encoding="w3cdtf">2000</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: The gas-phase pyrolysis of chloropicrin, diphosgene and phosgene has been investigated in a static reactor at temperatures between 100 and 530°C, at an initial pressure of 25 torr and for reaction times ranging from 10 to 120 min. Phosgene is the main carbon containing reaction product of the pyrolyses of chloropicrin and diphosgene and its decomposition leads to the formation of carbon monoxide and chlorine. A kinetic scheme for the decomposition of phosgene has been proposed and has permitted satisfactory modelling of the experimental results obtained. The study clearly shows the possible industrial use of this process to destroy chemical weapons and a first range of temperatures and reaction times has been selected for future reactor design.</abstract><note type="content">Fig. 1: Typical profiles of pressure versus time for the thermal decomposition of chloropicrin. Initial pressure, 25 torr.</note><note type="content">Fig. 2: Conversion rate of chloropicrin versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 3: Product formation during the pyrolysis of chloropicrin versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 4: Products formation during the pyrolysis of diphosgene versus temperature. Initial pressure, 25 torr; residence time, 10 min.</note><note type="content">Fig. 5: Evolution of the total pressure and the partial pressures of COCl2 and CO with residence time during the pyrolysis of diphosgene at (a) 470°C, (b) 500°C and (c) 530°C. Initial pressure of diphosgene, 25 torr; dots are related to experiments and lines to simulations.</note><note type="content">Table 1: Summary of the main experimental resultsa</note><note type="content">Table 2: Mechanism for the thermal decomposition of phosgenea</note><subject lang="en"><genre>Keywords</genre><topic>Chloropicrin</topic><topic>Diphosgene</topic><topic>Phosgene</topic><topic>Thermal decomposition</topic><topic>Chemical weapons</topic><topic>Pyrolysis</topic></subject><relatedItem type="host"><titleInfo><title>Journal of Analytical and Applied Pyrolysis</title></titleInfo><titleInfo type="abbreviated"><title>JAAP</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">200001</dateIssued></originInfo><identifier type="ISSN">0165-2370</identifier><identifier type="PII">S0165-2370(00)X0036-8</identifier><part><date>200001</date><detail type="volume"><number>53</number><caption>vol.</caption></detail><detail type="issue"><number>1</number><caption>no.</caption></detail><extent unit="issue-pages"><start>1</start><end>122</end></extent><extent unit="pages"><start>95</start><end>105</end></extent></part></relatedItem><identifier type="istex">18EB059E728EA4443D04D09E2B60F9960654C19E</identifier><identifier type="ark">ark:/67375/6H6-GHHGDDZJ-5</identifier><identifier type="DOI">10.1016/S0165-2370(99)00052-2</identifier><identifier type="PII">S0165-2370(99)00052-2</identifier><accessCondition type="use and reproduction" contentType="copyright">©2000 Elsevier Science B.V.</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource><recordOrigin>Elsevier Science B.V., ©2000</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/18EB059E728EA4443D04D09E2B60F9960654C19E/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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