UnivTrevesV1, PascalFrancis, Checkpoint, bibRecord, 001190

Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Identifieur interne : 001190 ( PascalFrancis/Checkpoint ); précédent : 001189; suivant : 001191

Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Auteurs : W. Wagner [Allemagne] ; S. Sander ; G. Henze

Source :

Fresenius' journal of analytical chemistry [ 0937-0633 ] ; 1996.

RBID : Pascal:96-0044162

Descripteurs français

Pascal (Inist)
- Analyse chimique, Adsorption, Voltammétrie redissolution anodique, Antimoine, Limite détection, Analyse trace, Complexation, Coordinat organique.
Wicri :
- topic : Antimoine.

English descriptors

KwdEn :
- Adsorption, Anodic stripping voltammetry, Antimony, Chemical analysis, Complexation, Detection limit, Organic ligand, Trace analysis.

Abstract

A sensitive and selective adsorption stripping voltammetric (AdSV) method for the determination of antimony using chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) as complexing reagent is described. The conditions under which its species of both oxidation states, Sb(III) and Sb(V), can be detected have been established. Sb(III) can be adsorbed onto the hanging mercury drop electrode (HMDE) using an accumulation potential of + 100mV from hydrochloric acid (pH = 3.0) solution. Sb(V) can be determined using an accumulation potential of - 500 mV in HCI (pH = 1.0) solution. The peak potentials in the stripping voltammograms are - 400 mV for Sb(III) and - 140 mV for antimony (V). The detection limits are 210 ng/L for Sb(III) with 5 min pre-concentration and 560 ng/L for Sb(V) with 10 min pre-concentration. The method is applicable to the trace analysis and speciation of antimony in water samples and phosphoric acid.

Affiliations:

Allemagne

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 001480
to stream PascalFrancis, to step Curation: 001522

Links to Exploration step

Pascal:96-0044162

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry</title>
<author><name sortKey="Wagner, W" sort="Wagner, W" uniqKey="Wagner W" first="W." last="Wagner">W. Wagner</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Univ. Trier, Univ. Kaiserslautern und Abt. anorganische analytische Chemie</s1>
<s2>54228 Trier</s2>
<s3>DEU</s3>
</inist:fA14>
<country>Allemagne</country>
<wicri:noRegion>54228 Trier</wicri:noRegion>
<wicri:noRegion>Univ. Kaiserslautern und Abt. anorganische analytische Chemie</wicri:noRegion>
<wicri:noRegion>54228 Trier</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Sander, S" sort="Sander, S" uniqKey="Sander S" first="S." last="Sander">S. Sander</name>
</author>
<author><name sortKey="Henze, G" sort="Henze, G" uniqKey="Henze G" first="G." last="Henze">G. Henze</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">96-0044162</idno>
<date when="1996">1996</date>
<idno type="stanalyst">PASCAL 96-0044162 INIST</idno>
<idno type="RBID">Pascal:96-0044162</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">001480</idno>
<idno type="wicri:Area/PascalFrancis/Curation">001522</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">001190</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">001190</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry</title>
<author><name sortKey="Wagner, W" sort="Wagner, W" uniqKey="Wagner W" first="W." last="Wagner">W. Wagner</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Univ. Trier, Univ. Kaiserslautern und Abt. anorganische analytische Chemie</s1>
<s2>54228 Trier</s2>
<s3>DEU</s3>
</inist:fA14>
<country>Allemagne</country>
<wicri:noRegion>54228 Trier</wicri:noRegion>
<wicri:noRegion>Univ. Kaiserslautern und Abt. anorganische analytische Chemie</wicri:noRegion>
<wicri:noRegion>54228 Trier</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Sander, S" sort="Sander, S" uniqKey="Sander S" first="S." last="Sander">S. Sander</name>
</author>
<author><name sortKey="Henze, G" sort="Henze, G" uniqKey="Henze G" first="G." last="Henze">G. Henze</name>
</author>
</analytic>
<series><title level="j" type="main">Fresenius' journal of analytical chemistry</title>
<title level="j" type="abbreviated">Fresenius' j. anal. chem.</title>
<idno type="ISSN">0937-0633</idno>
<imprint><date when="1996">1996</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Fresenius' journal of analytical chemistry</title>
<title level="j" type="abbreviated">Fresenius' j. anal. chem.</title>
<idno type="ISSN">0937-0633</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Adsorption</term>
<term>Anodic stripping voltammetry</term>
<term>Antimony</term>
<term>Chemical analysis</term>
<term>Complexation</term>
<term>Detection limit</term>
<term>Organic ligand</term>
<term>Trace analysis</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Analyse chimique</term>
<term>Adsorption</term>
<term>Voltammétrie redissolution anodique</term>
<term>Antimoine</term>
<term>Limite détection</term>
<term>Analyse trace</term>
<term>Complexation</term>
<term>Coordinat organique</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Antimoine</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">A sensitive and selective adsorption stripping voltammetric (AdSV) method for the determination of antimony using chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) as complexing reagent is described. The conditions under which its species of both oxidation states, Sb(III) and Sb(V), can be detected have been established. Sb(III) can be adsorbed onto the hanging mercury drop electrode (HMDE) using an accumulation potential of + 100mV from hydrochloric acid (pH = 3.0) solution. Sb(V) can be determined using an accumulation potential of - 500 mV in HCI (pH = 1.0) solution. The peak potentials in the stripping voltammograms are - 400 mV for Sb(III) and - 140 mV for antimony (V). The detection limits are 210 ng/L for Sb(III) with 5 min pre-concentration and 560 ng/L for Sb(V) with 10 min pre-concentration. The method is applicable to the trace analysis and speciation of antimony in water samples and phosphoric acid.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0937-0633</s0>
</fA01>
<fA03 i2="1"><s0>Fresenius' j. anal. chem.</s0>
</fA03>
<fA05><s2>354</s2>
</fA05>
<fA06><s2>1</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>WAGNER (W.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>SANDER (S.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>HENZE (G.)</s1>
</fA11>
<fA14 i1="01"><s1>Univ. Trier, Univ. Kaiserslautern und Abt. anorganische analytische Chemie</s1>
<s2>54228 Trier</s2>
<s3>DEU</s3>
</fA14>
<fA20><s1>11-15</s1>
</fA20>
<fA21><s1>1996</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>853</s2>
<s5>354000054958420030</s5>
</fA43>
<fA44><s0>0000</s0>
</fA44>
<fA45><s0>7 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>96-0044162</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Fresenius' journal of analytical chemistry</s0>
</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>A sensitive and selective adsorption stripping voltammetric (AdSV) method for the determination of antimony using chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) as complexing reagent is described. The conditions under which its species of both oxidation states, Sb(III) and Sb(V), can be detected have been established. Sb(III) can be adsorbed onto the hanging mercury drop electrode (HMDE) using an accumulation potential of + 100mV from hydrochloric acid (pH = 3.0) solution. Sb(V) can be determined using an accumulation potential of - 500 mV in HCI (pH = 1.0) solution. The peak potentials in the stripping voltammograms are - 400 mV for Sb(III) and - 140 mV for antimony (V). The detection limits are 210 ng/L for Sb(III) with 5 min pre-concentration and 560 ng/L for Sb(V) with 10 min pre-concentration. The method is applicable to the trace analysis and speciation of antimony in water samples and phosphoric acid.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C04E</s0>
</fC02>
<fC03 i1="01" i2="1" l="FRE"><s0>Analyse chimique</s0>
<s3>P</s3>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="1" l="ENG"><s0>Chemical analysis</s0>
<s3>P</s3>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="1" l="FRE"><s0>Adsorption</s0>
<s5>51</s5>
</fC03>
<fC03 i1="02" i2="1" l="ENG"><s0>Adsorption</s0>
<s5>51</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Voltammétrie redissolution anodique</s0>
<s5>52</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Anodic stripping voltammetry</s0>
<s5>52</s5>
</fC03>
<fC03 i1="03" i2="X" l="GER"><s0>Inversvoltammetrie</s0>
<s5>52</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Voltametría redisolución anódica</s0>
<s5>52</s5>
</fC03>
<fC03 i1="04" i2="1" l="FRE"><s0>Antimoine</s0>
<s1>ANA</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>FR</s2>
<s5>53</s5>
</fC03>
<fC03 i1="04" i2="1" l="ENG"><s0>Antimony</s0>
<s1>ANA</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>FR</s2>
<s5>53</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Limite détection</s0>
<s5>54</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Detection limit</s0>
<s5>54</s5>
</fC03>
<fC03 i1="05" i2="X" l="GER"><s0>Nachweisgrenze</s0>
<s5>54</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Límite detección</s0>
<s5>54</s5>
</fC03>
<fC03 i1="06" i2="1" l="FRE"><s0>Analyse trace</s0>
<s5>55</s5>
</fC03>
<fC03 i1="06" i2="1" l="ENG"><s0>Trace analysis</s0>
<s5>55</s5>
</fC03>
<fC03 i1="07" i2="1" l="FRE"><s0>Complexation</s0>
<s5>56</s5>
</fC03>
<fC03 i1="07" i2="1" l="ENG"><s0>Complexation</s0>
<s5>56</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>57</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Organic ligand</s0>
<s5>57</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>57</s5>
</fC03>
<fN21><s1>022</s1>
</fN21>
</pA>
</standard>
</inist>
<affiliations><list><country><li>Allemagne</li>
</country>
</list>
<tree><noCountry><name sortKey="Henze, G" sort="Henze, G" uniqKey="Henze G" first="G." last="Henze">G. Henze</name>
<name sortKey="Sander, S" sort="Sander, S" uniqKey="Sander S" first="S." last="Sander">S. Sander</name>
</noCountry>
<country name="Allemagne"><noRegion><name sortKey="Wagner, W" sort="Wagner, W" uniqKey="Wagner W" first="W." last="Wagner">W. Wagner</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Rhénanie/explor/UnivTrevesV1/Data/PascalFrancis/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001190 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PascalFrancis/Checkpoint/biblio.hfd -nk 001190 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Rhénanie
   |area=    UnivTrevesV1
   |flux=    PascalFrancis
   |étape=   Checkpoint
   |type=    RBID
   |clé=     Pascal:96-0044162
   |texte=   Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry
}}

This area was generated with Dilib version V0.6.31.
Data generation: Sat Jul 22 16:29:01 2017. Site generation: Wed Feb 28 14:55:37 2024

	Serveur d'exploration sur l'Université de Trèves
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur l'Université de Trèves

Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri