Voltammetric determination of Ioxynil and 2-methyl-3-nitroaniline using C18 modified carbon paste electrodes
Identifieur interne : 002C89 ( Main/Merge ); précédent : 002C88; suivant : 002C90Voltammetric determination of Ioxynil and 2-methyl-3-nitroaniline using C18 modified carbon paste electrodes
Auteurs : C. Faller [Allemagne] ; A. Meyer [Allemagne] ; G. Henze [Allemagne]Source :
- Fresenius' journal of analytical chemistry [ 0937-0633 ] ; 1996.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Pesticide, Eau, Eau potable.
English descriptors
- KwdEn :
Abstract
The stripping voltammetric behaviour of Ioxynil and 2-methyl-3-nitroaniline has been studied by means of a C18 modified carbon paste electrode. The analytes are preconcentrated under open-circuit conditions (Ioxynil at pH 3.9 ; 2-methyl-3-nitroaniline at pH 10). For the determination of Ioxynil and 2-methyl-3-nitroaniline 0.01 mol/l HCl and 1 mol/l KOH, respectively, have been used as supporting electrolyte. Under optimized conditions detection limits up to 0.1 μg/ml Ioxynil and 0.3 μg/ml 2-methyl-3-nitroaniline have been obtained. The methods have been applied to the determination of Ioxynil and 2-methyl-3-nitroaniline in drinking water.
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Pascal:96-0461440Le document en format XML
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Benzenic compound</term>
<term>Carbon electrode</term>
<term>Chemical analysis</term>
<term>Chemical modification</term>
<term>Iodine Organic compounds</term>
<term>Nitro compound</term>
<term>Paste electrode</term>
<term>Pesticides</term>
<term>Potable water</term>
<term>Trace analysis</term>
<term>Voltammetry</term>
<term>Water</term>
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<term>Analyse trace</term>
<term>Pesticide</term>
<term>Composé benzénique</term>
<term>Composé nitro</term>
<term>Iode Composé organique</term>
<term>Eau</term>
<term>Eau potable</term>
<term>Voltammétrie</term>
<term>Electrode carbone</term>
<term>Electrode pâte</term>
<term>Modification chimique</term>
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<front><div type="abstract" xml:lang="en">The stripping voltammetric behaviour of Ioxynil and 2-methyl-3-nitroaniline has been studied by means of a C<sub>18</sub>
modified carbon paste electrode. The analytes are preconcentrated under open-circuit conditions (Ioxynil at pH 3.9 ; 2-methyl-3-nitroaniline at pH 10). For the determination of Ioxynil and 2-methyl-3-nitroaniline 0.01 mol/l HCl and 1 mol/l KOH, respectively, have been used as supporting electrolyte. Under optimized conditions detection limits up to 0.1 μg/ml Ioxynil and 0.3 μg/ml 2-methyl-3-nitroaniline have been obtained. The methods have been applied to the determination of Ioxynil and 2-methyl-3-nitroaniline in drinking water.</div>
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