Determination of tin traces in water samples by adsorptive stripping voltammetry
Identifieur interne : 002789 ( Main/Exploration ); précédent : 002788; suivant : 002790Determination of tin traces in water samples by adsorptive stripping voltammetry
Auteurs : F. Heppeler [Allemagne] ; S. Sander [Allemagne] ; G. Henze [Allemagne]Source :
- Analytica Chimica Acta [ 0003-2670 ] ; 1996.
Descripteurs français
- Wicri :
- topic : étain.
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Abstract
A sensitive and selective adsorptive stripping voltammetric method was employed to determine traces of tin in water samples. The spontaneously formed tin complex with 2,5-dichloro-1,4-dihydroxy-3,6-benzoquinone (chloranilic acid) is adsorbed at the surface of a mercury drop electrode. The analyte can be preconcentrated in this way applying a potential between +100 and −200 mV to the working electrode. The adsorption behaviour is investigated by means of alternating current voltammetry. Tin traces were determined after UV-digestion in drainage water samples.
Url:
DOI: 10.1016/0003-2670(95)00480-7
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