Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes
Identifieur interne : 001162 ( Istex/Curation ); précédent : 001161; suivant : 001163Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes
Auteurs : Sylvia Sander [Allemagne] ; Günter Henze [Allemagne]Source :
- Electroanalysis [ 1040-0397 ] ; 1996-03.
English descriptors
Abstract
In adsorptive stripping voltammetry (AdSV) the analyte is accumulated on the electrode surface in the form of a metal complex and the determination step is carried out voltammetrically. Usually the technique is sensitive to the effects of other absorbable organic substances. Alternating‐current (AC) investigations on the complexes of uranium, vanadium and antimony with chloranilic acid, uranium with cupferron and cobalt and nickel with dimethylglyoxime gave information about their adsorption behavior on the electrode surface. Furthermore the AC voltammetric behavior of the nonionic surfactant Triton X100 was shown. By knowing the adsorption potential and range of adsorption, predictions about the effects of organic adsorbates can be made. Importantly the optimal accumulation potential of the complex for its AdSV‐determination may be obtained. With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.
Url:
DOI: 10.1002/elan.1140080310
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: Pour aller vers cette notice dans l'étape Curation :001274
Links to Exploration step
ISTEX:A621457E285FB270CC7C92AC41B4099C123DA67FLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes</title>
<author><name sortKey="Sander, Sylvia" sort="Sander, Sylvia" uniqKey="Sander S" first="Sylvia" last="Sander">Sylvia Sander</name>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Henze, Gunter" sort="Henze, Gunter" uniqKey="Henze G" first="Günter" last="Henze">Günter Henze</name>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:A621457E285FB270CC7C92AC41B4099C123DA67F</idno>
<date when="1996" year="1996">1996</date>
<idno type="doi">10.1002/elan.1140080310</idno>
<idno type="url">https://api.istex.fr/document/A621457E285FB270CC7C92AC41B4099C123DA67F/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001274</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001274</idno>
<idno type="wicri:Area/Istex/Curation">001162</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes</title>
<author><name sortKey="Sander, Sylvia" sort="Sander, Sylvia" uniqKey="Sander S" first="Sylvia" last="Sander">Sylvia Sander</name>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Henze, Gunter" sort="Henze, Gunter" uniqKey="Henze G" first="Günter" last="Henze">Günter Henze</name>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</mods:affiliation>
<country xml:lang="fr">Allemagne</country>
<wicri:regionArea>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier</wicri:regionArea>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Electroanalysis</title>
<title level="j" type="abbrev">Electroanalysis</title>
<idno type="ISSN">1040-0397</idno>
<idno type="eISSN">1521-4109</idno>
<imprint><publisher>VCH Verlagsgesellschaft mbH</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="1996-03">1996-03</date>
<biblScope unit="volume">8</biblScope>
<biblScope unit="issue">3</biblScope>
<biblScope unit="page" from="253">253</biblScope>
<biblScope unit="page" to="262">262</biblScope>
</imprint>
<idno type="ISSN">1040-0397</idno>
</series>
<idno type="istex">A621457E285FB270CC7C92AC41B4099C123DA67F</idno>
<idno type="DOI">10.1002/elan.1140080310</idno>
<idno type="ArticleID">ELAN1140080310</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1040-0397</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Adsorption</term>
<term>Adsorptive stripping voltammetry</term>
<term>Alternating current measurements</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">In adsorptive stripping voltammetry (AdSV) the analyte is accumulated on the electrode surface in the form of a metal complex and the determination step is carried out voltammetrically. Usually the technique is sensitive to the effects of other absorbable organic substances. Alternating‐current (AC) investigations on the complexes of uranium, vanadium and antimony with chloranilic acid, uranium with cupferron and cobalt and nickel with dimethylglyoxime gave information about their adsorption behavior on the electrode surface. Furthermore the AC voltammetric behavior of the nonionic surfactant Triton X100 was shown. By knowing the adsorption potential and range of adsorption, predictions about the effects of organic adsorbates can be made. Importantly the optimal accumulation potential of the complex for its AdSV‐determination may be obtained. With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.</div>
</front>
</TEI>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Rhénanie/explor/UnivTrevesV1/Data/Istex/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001162 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Curation/biblio.hfd -nk 001162 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Rhénanie |area= UnivTrevesV1 |flux= Istex |étape= Curation |type= RBID |clé= ISTEX:A621457E285FB270CC7C92AC41B4099C123DA67F |texte= Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes }}
This area was generated with Dilib version V0.6.31. |