Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes
Identifieur interne : 001274 ( Istex/Corpus ); précédent : 001273; suivant : 001275Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes
Auteurs : Sylvia Sander ; Günter HenzeSource :
- Electroanalysis [ 1040-0397 ] ; 1996-03.
English descriptors
Abstract
In adsorptive stripping voltammetry (AdSV) the analyte is accumulated on the electrode surface in the form of a metal complex and the determination step is carried out voltammetrically. Usually the technique is sensitive to the effects of other absorbable organic substances. Alternating‐current (AC) investigations on the complexes of uranium, vanadium and antimony with chloranilic acid, uranium with cupferron and cobalt and nickel with dimethylglyoxime gave information about their adsorption behavior on the electrode surface. Furthermore the AC voltammetric behavior of the nonionic surfactant Triton X100 was shown. By knowing the adsorption potential and range of adsorption, predictions about the effects of organic adsorbates can be made. Importantly the optimal accumulation potential of the complex for its AdSV‐determination may be obtained. With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.
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DOI: 10.1002/elan.1140080310
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ISTEX:A621457E285FB270CC7C92AC41B4099C123DA67FLe document en format XML
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Usually the technique is sensitive to the effects of other absorbable organic substances. Alternating‐current (AC) investigations on the complexes of uranium, vanadium and antimony with chloranilic acid, uranium with cupferron and cobalt and nickel with dimethylglyoxime gave information about their adsorption behavior on the electrode surface. Furthermore the AC voltammetric behavior of the nonionic surfactant Triton X100 was shown. By knowing the adsorption potential and range of adsorption, predictions about the effects of organic adsorbates can be made. Importantly the optimal accumulation potential of the complex for its AdSV‐determination may be obtained. With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Sylvia Sander</name><affiliations><json:string>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</json:string></affiliations></json:item><json:item><name>Günter Henze</name><affiliations><json:string>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</json:string><json:string>Fachbereich Chemie, Universität Kaiserslautern and Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D54228 Trier, Germany</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Adsorption</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Alternating current measurements</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Adsorptive stripping voltammetry</value></json:item></subject><articleId><json:string>ELAN1140080310</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>In adsorptive stripping voltammetry (AdSV) the analyte is accumulated on the electrode surface in the form of a metal complex and the determination step is carried out voltammetrically. Usually the technique is sensitive to the effects of other absorbable organic substances. Alternating‐current (AC) investigations on the complexes of uranium, vanadium and antimony with chloranilic acid, uranium with cupferron and cobalt and nickel with dimethylglyoxime gave information about their adsorption behavior on the electrode surface. Furthermore the AC voltammetric behavior of the nonionic surfactant Triton X100 was shown. By knowing the adsorption potential and range of adsorption, predictions about the effects of organic adsorbates can be made. Importantly the optimal accumulation potential of the complex for its AdSV‐determination may be obtained. With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.</abstract><qualityIndicators><score>6.366</score><pdfVersion>1.3</pdfVersion><pdfPageSize>594 x 791.759 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>1028</abstractCharCount><pdfWordCount>4614</pdfWordCount><pdfCharCount>28147</pdfCharCount><pdfPageCount>10</pdfPageCount><abstractWordCount>146</abstractWordCount></qualityIndicators><title>Alternating current investigations at the mercury drop electrode on the adsorption potential of metal complexes</title><refBibs><json:item><host><author></author><title>H. JehringElektrosorptionsanalyse mit der Wechselstrompolarographie,Akademie‐Verlag,Berlin1974.</title></host></json:item><json:item><host><volume>274</volume><pages><first>55</first></pages><author></author><title>Proc. Roy. Soc. (London), Ser. A</title></host></json:item><json:item><host><volume>274</volume><pages><first>792</first></pages><author></author><title>Z. Physik</title></host></json:item><json:item><host><author></author><title>S. SanderDissertation, Department of Chemistry, University of Kaiserslautern, Germany1995.</title></host></json:item><json:item><host><volume>274</volume><pages><first>654</first></pages><author></author><title>Fresenius J. Anal. Chem.</title></host></json:item><json:item><host><volume>274</volume><pages><first>154</first></pages><author></author><title>Anal. Chim. Acta</title></host></json:item><json:item><host><volume>274</volume><pages><first>186</first></pages><author></author><title>Fresenius J. Anal. Chem.</title></host></json:item><json:item><host><author></author><title>S. SanderThesis, Department of Chemistry, University of Kaiserslautern, Germany1992.</title></host></json:item><json:item><host><author></author><title>F. HeppelerThesis, Department of Chemistry, University of Kaiserslautern, Germany1994.</title></host></json:item><json:item><host><author></author><title>Anal. Chim. Acta</title></host></json:item><json:item><host><volume>274</volume><pages><first>11</first></pages><author></author><title>Fresenius J. Anal. Chem.</title></host></json:item><json:item><host><volume>274</volume><pages><first>205</first></pages><author></author><title>Anal. Chim. 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With appropriate potential control the selective accumulation of the analyte complex can be achieved and so avoid the influence of these other adsorbates in favorable cases.</abstract><subject lang="en"><genre>keywords</genre><topic>Adsorption</topic><topic>Alternating current measurements</topic><topic>Adsorptive stripping voltammetry</topic></subject><relatedItem type="host"><titleInfo><title>Electroanalysis</title></titleInfo><titleInfo type="abbreviated"><title>Electroanalysis</title></titleInfo><genre type="journal">journal</genre><subject><genre>article-category</genre><topic>Feature Article</topic></subject><identifier type="ISSN">1040-0397</identifier><identifier type="eISSN">1521-4109</identifier><identifier type="DOI">10.1002/(ISSN)1521-4109</identifier><identifier type="PublisherID">ELAN</identifier><part><date>1996</date><detail type="volume"><caption>vol.</caption><number>8</number></detail><detail type="issue"><caption>no.</caption><number>3</number></detail><extent unit="pages"><start>253</start><end>262</end><total>10</total></extent></part></relatedItem><identifier type="istex">A621457E285FB270CC7C92AC41B4099C123DA67F</identifier><identifier type="DOI">10.1002/elan.1140080310</identifier><identifier type="ArticleID">ELAN1140080310</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 1996 VCH Verlagsgesellschaft mbH</accessCondition><recordInfo><recordContentSource>WILEY</recordContentSource><recordOrigin>VCH Verlagsgesellschaft mbH</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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