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Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Identifieur interne : 000904 ( Istex/Corpus ); précédent : 000903; suivant : 000905

Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry

Auteurs : W. Wagner ; S. Sander ; G. Henze

Source :

RBID : ISTEX:F670FBF9D0A3AF0C2F6AD9CE22B2974BEF8E41D5

Abstract

Abstract.: A sensitive and selective adsorption stripping voltammetric (AdSV) method for the determination of antimony using chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) as complexing reagent is described. The conditions under which its species of both oxidation states, Sb(III) and Sb(V), can be detected have been established. Sb(III) can be adsorbed onto the hanging mercury drop electrode (HMDE) using an accumulation potential of +100 mV from hydrochloric acid (pH=3.0) solution. Sb(V) can be determined using an accumulation potential of −500 mV in HCl (pH=1.0) solution. The peak potentials in the stripping voltammograms are −400 mV for Sb(III) and −140 mV for antimony (V). The detection limits are 210 ng/L for Sb(III) with 5 min pre-concentration and 560 ng/L for Sb(V) with 10 min pre-concentration. The method is applicable to the trace analysis and speciation of antimony in water samples and phosphoric acid.

Url:
DOI: 10.1007/s002169600002

Links to Exploration step

ISTEX:F670FBF9D0A3AF0C2F6AD9CE22B2974BEF8E41D5

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<SimplePara>Received: 12 December 1994/Revised: 10 April 1995/Accepted: 14 April 1995</SimplePara>
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<ArticleNote Type="Misc">
<SimplePara>
<Emphasis Type="Italic">Correspondence to:</Emphasis>
G. Henze</SimplePara>
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<title>Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry</title>
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<title>Trace analysis of antimony (III) and antimony (V) by adsorptive stripping voltammetry</title>
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<name type="personal">
<namePart type="given">W.</namePart>
<namePart type="family">Wagner</namePart>
<affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D-54228 Trier, Germany, DE</affiliation>
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<name type="personal">
<namePart type="given">S.</namePart>
<namePart type="family">Sander</namePart>
<affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D-54228 Trier, Germany, DE</affiliation>
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<namePart type="family">Henze</namePart>
<affiliation>Fachbereich Chemie, Universität Kaiserslautern und Abteilung für Anorganische und Analytische Chemie, Universität Trier, Postfach 3825, D-54228 Trier, Germany, DE</affiliation>
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<abstract lang="en">Abstract.: A sensitive and selective adsorption stripping voltammetric (AdSV) method for the determination of antimony using chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) as complexing reagent is described. The conditions under which its species of both oxidation states, Sb(III) and Sb(V), can be detected have been established. Sb(III) can be adsorbed onto the hanging mercury drop electrode (HMDE) using an accumulation potential of +100 mV from hydrochloric acid (pH=3.0) solution. Sb(V) can be determined using an accumulation potential of −500 mV in HCl (pH=1.0) solution. The peak potentials in the stripping voltammograms are −400 mV for Sb(III) and −140 mV for antimony (V). The detection limits are 210 ng/L for Sb(III) with 5 min pre-concentration and 560 ng/L for Sb(V) with 10 min pre-concentration. The method is applicable to the trace analysis and speciation of antimony in water samples and phosphoric acid.</abstract>
<note>Original papers</note>
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<title>Fresenius' Journal of Analytical Chemistry</title>
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<titleInfo type="abbreviated">
<title>Fresenius J Anal Chem</title>
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<originInfo>
<dateIssued encoding="w3cdtf">1996-01-01</dateIssued>
<copyrightDate encoding="w3cdtf">1996</copyrightDate>
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<subject>
<genre>Legacy</genre>
</subject>
<identifier type="ISSN">0937-0633</identifier>
<identifier type="eISSN">1432-1130</identifier>
<identifier type="JournalID">216</identifier>
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<date>1996</date>
<detail type="volume">
<number>354</number>
<caption>vol.</caption>
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<number>1</number>
<caption>no.</caption>
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<start>11</start>
<end>15</end>
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