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Activation of lignocellulosic biomass by ionic liquid for biorefinery fractionation.

Identifieur interne : 002C28 ( Main/Corpus ); précédent : 002C27; suivant : 002C29

Activation of lignocellulosic biomass by ionic liquid for biorefinery fractionation.

Auteurs : Nicole Labbé ; Lindsey M. Kline ; Luc Moens ; Keonhee Kim ; Pyoung Chung Kim ; Douglas G. Hayes

Source :

RBID : pubmed:22079688

English descriptors

Abstract

Fractionation of lignocellulosic biomass is an attractive solution to develop an economically viable biorefinery by providing a saccharide fraction to produce fuels and a lignin stream that can be converted into high value products such as carbon fibers. In this study, the analysis of ionic liquid-activated biomass demonstrates that in addition of decreasing crystallinity, the selected ILs (1-butyl-3-methylimidazolium acetate, 1-butyl-3-methylimidazolium chloride and 1-ethyl-3-methylimidazolium acetate) deacetylate Yellow poplar under mild conditions (dissolution at 60-80 °C), and lower the degradation temperature of each biomass polymeric component, thereby reducing the recalcitrance of biomass. Among the three tested ILs, 1-ethyl-3-methylimidazolium acetate performed the best, providing a strong linear relationship between the level of deacetylation and the rate of enzymatic saccharification for Yellow poplar.

DOI: 10.1016/j.biortech.2011.10.062
PubMed: 22079688

Links to Exploration step

pubmed:22079688

Le document en format XML

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<div type="abstract" xml:lang="en">Fractionation of lignocellulosic biomass is an attractive solution to develop an economically viable biorefinery by providing a saccharide fraction to produce fuels and a lignin stream that can be converted into high value products such as carbon fibers. In this study, the analysis of ionic liquid-activated biomass demonstrates that in addition of decreasing crystallinity, the selected ILs (1-butyl-3-methylimidazolium acetate, 1-butyl-3-methylimidazolium chloride and 1-ethyl-3-methylimidazolium acetate) deacetylate Yellow poplar under mild conditions (dissolution at 60-80 °C), and lower the degradation temperature of each biomass polymeric component, thereby reducing the recalcitrance of biomass. Among the three tested ILs, 1-ethyl-3-methylimidazolium acetate performed the best, providing a strong linear relationship between the level of deacetylation and the rate of enzymatic saccharification for Yellow poplar.</div>
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