Effect of thermal treatment with water, H2SO4 and NaOH aqueous solution on color, cell wall and chemical structure of poplar wood.
Identifieur interne : 000B42 ( Main/Corpus ); précédent : 000B41; suivant : 000B43Effect of thermal treatment with water, H2SO4 and NaOH aqueous solution on color, cell wall and chemical structure of poplar wood.
Auteurs : Jiangtao Shi ; Yu Lu ; Yaoli Zhang ; Liping Cai ; Sheldon Q. ShiSource :
- Scientific reports [ 2045-2322 ] ; 2018.
Abstract
Thermal treatments with water, diluted acid, and diluted alkali aqueous solution of poplar wood blocks were carried out in a Teflon-lined autoclave at three temperatures. The effects of different liquids and temperatures on wood surface color, cell wall microstructure, and chemical structures were investigated by the chromameter, scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FTIR). From the chromameter, it was observed that the lightness value decreased with temperature for all treatment conditions. The a* value increased with temperature in all liquid treatments. The b* value increased with temperature in hydrothermal and thermal with H2SO4 treatment but decreased with temperature in thermal with NaOH treatment. The total color difference (ΔE) was slightly changed in the hydrothermal treatment, but dramatically changed in the thermal with H2SO4 and NaOH aqueous treatments. SEM showed that the cell wall structure was damaged differently with different reagents and temperature. Middle lamella layers were always fractured in hydrothermal and NaOH treatments. However, both middle lamella and secondary cell wall were damaged after the H2SO4 treatment and intensified with temperature. These fractures usually parallel with the S2 layer microfibril angle (MFA) in the fiber cell wall. The FTIR analysis suggested that the chemical structure was obviously changed after the thermal with H2SO4 and NaOH treatments. And the missing or decreasing C=O absorption peak indicated hemicellulose is degraded and new compounds produced during thermal with H2SO4 and NaOH treatment. On the other hand, lignin was partly degraded in the H2SO4 treatment and guaiacyl nuclei was degraded before syringyl nuclei.
DOI: 10.1038/s41598-018-36086-9
PubMed: 30531958
PubMed Central: PMC6286344
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pubmed:30531958Le document en format XML
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SO<sub>4</sub>
and NaOH aqueous solution on color, cell wall and chemical structure of poplar wood.</title>
<author><name sortKey="Shi, Jiangtao" sort="Shi, Jiangtao" uniqKey="Shi J" first="Jiangtao" last="Shi">Jiangtao Shi</name>
<affiliation><nlm:affiliation>College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, China. shijt@njfu.edu.cn.</nlm:affiliation>
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<affiliation><nlm:affiliation>Mechanical and Energy Engineering, University of North Texas, Denton, TX, 76207, USA. shijt@njfu.edu.cn.</nlm:affiliation>
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<author><name sortKey="Lu, Yu" sort="Lu, Yu" uniqKey="Lu Y" first="Yu" last="Lu">Yu Lu</name>
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<author><name sortKey="Zhang, Yaoli" sort="Zhang, Yaoli" uniqKey="Zhang Y" first="Yaoli" last="Zhang">Yaoli Zhang</name>
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<author><name sortKey="Cai, Liping" sort="Cai, Liping" uniqKey="Cai L" first="Liping" last="Cai">Liping Cai</name>
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<affiliation><nlm:affiliation>Mechanical and Energy Engineering, University of North Texas, Denton, TX, 76207, USA.</nlm:affiliation>
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<author><name sortKey="Shi, Sheldon Q" sort="Shi, Sheldon Q" uniqKey="Shi S" first="Sheldon Q" last="Shi">Sheldon Q. Shi</name>
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SO<sub>4</sub>
and NaOH aqueous solution on color, cell wall and chemical structure of poplar wood.</title>
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<front><div type="abstract" xml:lang="en">Thermal treatments with water, diluted acid, and diluted alkali aqueous solution of poplar wood blocks were carried out in a Teflon-lined autoclave at three temperatures. The effects of different liquids and temperatures on wood surface color, cell wall microstructure, and chemical structures were investigated by the chromameter, scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FTIR). From the chromameter, it was observed that the lightness value decreased with temperature for all treatment conditions. The a* value increased with temperature in all liquid treatments. The b* value increased with temperature in hydrothermal and thermal with H<sub>2</sub>
SO<sub>4</sub>
treatment but decreased with temperature in thermal with NaOH treatment. The total color difference (ΔE) was slightly changed in the hydrothermal treatment, but dramatically changed in the thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH aqueous treatments. SEM showed that the cell wall structure was damaged differently with different reagents and temperature. Middle lamella layers were always fractured in hydrothermal and NaOH treatments. However, both middle lamella and secondary cell wall were damaged after the H<sub>2</sub>
SO<sub>4</sub>
treatment and intensified with temperature. These fractures usually parallel with the S2 layer microfibril angle (MFA) in the fiber cell wall. The FTIR analysis suggested that the chemical structure was obviously changed after the thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH treatments. And the missing or decreasing C=O absorption peak indicated hemicellulose is degraded and new compounds produced during thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH treatment. On the other hand, lignin was partly degraded in the H<sub>2</sub>
SO<sub>4</sub>
treatment and guaiacyl nuclei was degraded before syringyl nuclei.</div>
</front>
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<ArticleTitle>Effect of thermal treatment with water, H<sub>2</sub>
SO<sub>4</sub>
and NaOH aqueous solution on color, cell wall and chemical structure of poplar wood.</ArticleTitle>
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<Abstract><AbstractText>Thermal treatments with water, diluted acid, and diluted alkali aqueous solution of poplar wood blocks were carried out in a Teflon-lined autoclave at three temperatures. The effects of different liquids and temperatures on wood surface color, cell wall microstructure, and chemical structures were investigated by the chromameter, scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FTIR). From the chromameter, it was observed that the lightness value decreased with temperature for all treatment conditions. The a* value increased with temperature in all liquid treatments. The b* value increased with temperature in hydrothermal and thermal with H<sub>2</sub>
SO<sub>4</sub>
treatment but decreased with temperature in thermal with NaOH treatment. The total color difference (ΔE) was slightly changed in the hydrothermal treatment, but dramatically changed in the thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH aqueous treatments. SEM showed that the cell wall structure was damaged differently with different reagents and temperature. Middle lamella layers were always fractured in hydrothermal and NaOH treatments. However, both middle lamella and secondary cell wall were damaged after the H<sub>2</sub>
SO<sub>4</sub>
treatment and intensified with temperature. These fractures usually parallel with the S2 layer microfibril angle (MFA) in the fiber cell wall. The FTIR analysis suggested that the chemical structure was obviously changed after the thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH treatments. And the missing or decreasing C=O absorption peak indicated hemicellulose is degraded and new compounds produced during thermal with H<sub>2</sub>
SO<sub>4</sub>
and NaOH treatment. On the other hand, lignin was partly degraded in the H<sub>2</sub>
SO<sub>4</sub>
treatment and guaiacyl nuclei was degraded before syringyl nuclei.</AbstractText>
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