Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.
Identifieur interne : 001E42 ( Ncbi/Merge ); précédent : 001E41; suivant : 001E43Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.
Auteurs : Hongyue Guo [États-Unis] ; Leah S. Riter [États-Unis] ; Chad E. Wujcik [États-Unis] ; Daniel W. Armstrong [États-Unis]Source :
- Talanta [ 1873-3573 ] ; 2016.
English descriptors
- KwdEn :
- Chromatography, High Pressure Liquid, Citrus sinensis, Dicamba (analysis), Food Contamination (analysis), Fruit (chemistry), Herbicides (analysis), Indicators and Reagents (chemistry), Pesticide Residues (analysis), Pyrrolidines (chemistry), Seeds (chemistry), Soybeans, Spectrometry, Mass, Electrospray Ionization, Tandem Mass Spectrometry, Zea mays.
- MESH :
- chemical , analysis : Dicamba, Herbicides, Pesticide Residues.
- analysis : Food Contamination.
- chemistry : Fruit, Indicators and Reagents, Pyrrolidines, Seeds.
- Chromatography, High Pressure Liquid, Citrus sinensis, Soybeans, Spectrometry, Mass, Electrospray Ionization, Tandem Mass Spectrometry, Zea mays.
Abstract
A sensitive and selective HPLC-MS/MS method was developed for the quantitative analysis of dicamba residues in raw agricultural commodities (RACs). Instead of analysis in the traditionally used negative electrospray ionization (ESI) mode, these anionic compounds were detected in positive ESI with the use of ion-pairing reagents. In this approach, only a small amount (60µM) of a commercially available dicationic ion-pairing reagent was introduced into the post-column sample stream. This method has been validated in six different types of RACs including corn grain, corn stover, cotton seed, soybean, soy forage and orange with satisfactory quantitative accuracy and precision. The limits of quantitation (LOQ) values for these analytes were 1.0 to 3.0µg/kg. The standard curves were linear over the range of the tested concentrations (3.0 to 500µg/kg), with correlation coefficient (r) values≥0.999. Evaluation of ionization effects in RAC matrix extracts using diluent blanks for comparison showed no significant matrix effects were present.
DOI: 10.1016/j.talanta.2015.11.043
PubMed: 26717820
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 000096
- to stream PubMed, to step Curation: 000096
- to stream PubMed, to step Checkpoint: 000096
Links to Exploration step
pubmed:26717820Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.</title><author><name sortKey="Guo, Hongyue" sort="Guo, Hongyue" uniqKey="Guo H" first="Hongyue" last="Guo">Hongyue Guo</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States; University of Texas at Arlington, Arlington, TX, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO, United States; University of Texas at Arlington, Arlington, TX</wicri:regionArea><placeName><region type="state">Texas</region></placeName></affiliation></author><author><name sortKey="Riter, Leah S" sort="Riter, Leah S" uniqKey="Riter L" first="Leah S" last="Riter">Leah S. Riter</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO</wicri:regionArea><placeName><region type="state">Missouri (État)</region></placeName></affiliation></author><author><name sortKey="Wujcik, Chad E" sort="Wujcik, Chad E" uniqKey="Wujcik C" first="Chad E" last="Wujcik">Chad E. Wujcik</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO</wicri:regionArea><placeName><region type="state">Missouri (État)</region></placeName></affiliation></author><author><name sortKey="Armstrong, Daniel W" sort="Armstrong, Daniel W" uniqKey="Armstrong D" first="Daniel W" last="Armstrong">Daniel W. Armstrong</name><affiliation wicri:level="2"><nlm:affiliation>University of Texas at Arlington, Arlington, TX, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>University of Texas at Arlington, Arlington, TX</wicri:regionArea><placeName><region type="state">Texas</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:26717820</idno><idno type="pmid">26717820</idno><idno type="doi">10.1016/j.talanta.2015.11.043</idno><idno type="wicri:Area/PubMed/Corpus">000096</idno><idno type="wicri:Area/PubMed/Curation">000096</idno><idno type="wicri:Area/PubMed/Checkpoint">000096</idno><idno type="wicri:Area/Ncbi/Merge">001E42</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.</title><author><name sortKey="Guo, Hongyue" sort="Guo, Hongyue" uniqKey="Guo H" first="Hongyue" last="Guo">Hongyue Guo</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States; University of Texas at Arlington, Arlington, TX, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO, United States; University of Texas at Arlington, Arlington, TX</wicri:regionArea><placeName><region type="state">Texas</region></placeName></affiliation></author><author><name sortKey="Riter, Leah S" sort="Riter, Leah S" uniqKey="Riter L" first="Leah S" last="Riter">Leah S. Riter</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO</wicri:regionArea><placeName><region type="state">Missouri (État)</region></placeName></affiliation></author><author><name sortKey="Wujcik, Chad E" sort="Wujcik, Chad E" uniqKey="Wujcik C" first="Chad E" last="Wujcik">Chad E. Wujcik</name><affiliation wicri:level="2"><nlm:affiliation>Monsanto Company, St Louis, MO, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Monsanto Company, St Louis, MO</wicri:regionArea><placeName><region type="state">Missouri (État)</region></placeName></affiliation></author><author><name sortKey="Armstrong, Daniel W" sort="Armstrong, Daniel W" uniqKey="Armstrong D" first="Daniel W" last="Armstrong">Daniel W. Armstrong</name><affiliation wicri:level="2"><nlm:affiliation>University of Texas at Arlington, Arlington, TX, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>University of Texas at Arlington, Arlington, TX</wicri:regionArea><placeName><region type="state">Texas</region></placeName></affiliation></author></analytic><series><title level="j">Talanta</title><idno type="eISSN">1873-3573</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromatography, High Pressure Liquid</term><term>Citrus sinensis</term><term>Dicamba (analysis)</term><term>Food Contamination (analysis)</term><term>Fruit (chemistry)</term><term>Herbicides (analysis)</term><term>Indicators and Reagents (chemistry)</term><term>Pesticide Residues (analysis)</term><term>Pyrrolidines (chemistry)</term><term>Seeds (chemistry)</term><term>Soybeans</term><term>Spectrometry, Mass, Electrospray Ionization</term><term>Tandem Mass Spectrometry</term><term>Zea mays</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Dicamba</term><term>Herbicides</term><term>Pesticide Residues</term></keywords><keywords scheme="MESH" qualifier="analysis" xml:lang="en"><term>Food Contamination</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Fruit</term><term>Indicators and Reagents</term><term>Pyrrolidines</term><term>Seeds</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Chromatography, High Pressure Liquid</term><term>Citrus sinensis</term><term>Soybeans</term><term>Spectrometry, Mass, Electrospray Ionization</term><term>Tandem Mass Spectrometry</term><term>Zea mays</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A sensitive and selective HPLC-MS/MS method was developed for the quantitative analysis of dicamba residues in raw agricultural commodities (RACs). Instead of analysis in the traditionally used negative electrospray ionization (ESI) mode, these anionic compounds were detected in positive ESI with the use of ion-pairing reagents. In this approach, only a small amount (60µM) of a commercially available dicationic ion-pairing reagent was introduced into the post-column sample stream. This method has been validated in six different types of RACs including corn grain, corn stover, cotton seed, soybean, soy forage and orange with satisfactory quantitative accuracy and precision. The limits of quantitation (LOQ) values for these analytes were 1.0 to 3.0µg/kg. The standard curves were linear over the range of the tested concentrations (3.0 to 500µg/kg), with correlation coefficient (r) values≥0.999. Evaluation of ionization effects in RAC matrix extracts using diluent blanks for comparison showed no significant matrix effects were present.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">26717820</PMID><DateCreated><Year>2015</Year><Month>12</Month><Day>31</Day></DateCreated><DateCompleted><Year>2016</Year><Month>09</Month><Day>30</Day></DateCompleted><DateRevised><Year>2015</Year><Month>12</Month><Day>31</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-3573</ISSN><JournalIssue CitedMedium="Internet"><Volume>149</Volume><PubDate><Year>2016</Year></PubDate></JournalIssue><Title>Talanta</Title><ISOAbbreviation>Talanta</ISOAbbreviation></Journal><ArticleTitle>Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.</ArticleTitle><Pagination><MedlinePgn>103-9</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.talanta.2015.11.043</ELocationID><ELocationID EIdType="pii" ValidYN="Y">S0039-9140(15)30497-5</ELocationID><Abstract><AbstractText>A sensitive and selective HPLC-MS/MS method was developed for the quantitative analysis of dicamba residues in raw agricultural commodities (RACs). Instead of analysis in the traditionally used negative electrospray ionization (ESI) mode, these anionic compounds were detected in positive ESI with the use of ion-pairing reagents. In this approach, only a small amount (60µM) of a commercially available dicationic ion-pairing reagent was introduced into the post-column sample stream. This method has been validated in six different types of RACs including corn grain, corn stover, cotton seed, soybean, soy forage and orange with satisfactory quantitative accuracy and precision. The limits of quantitation (LOQ) values for these analytes were 1.0 to 3.0µg/kg. The standard curves were linear over the range of the tested concentrations (3.0 to 500µg/kg), with correlation coefficient (r) values≥0.999. Evaluation of ionization effects in RAC matrix extracts using diluent blanks for comparison showed no significant matrix effects were present.</AbstractText><CopyrightInformation>Copyright © 2015 Elsevier B.V. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Guo</LastName><ForeName>Hongyue</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Monsanto Company, St Louis, MO, United States; University of Texas at Arlington, Arlington, TX, United States.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Riter</LastName><ForeName>Leah S</ForeName><Initials>LS</Initials><AffiliationInfo><Affiliation>Monsanto Company, St Louis, MO, United States.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Wujcik</LastName><ForeName>Chad E</ForeName><Initials>CE</Initials><AffiliationInfo><Affiliation>Monsanto Company, St Louis, MO, United States.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Armstrong</LastName><ForeName>Daniel W</ForeName><Initials>DW</Initials><AffiliationInfo><Affiliation>University of Texas at Arlington, Arlington, TX, United States.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2015</Year><Month>Nov</Month><Day>18</Day></ArticleDate></Article><MedlineJournalInfo><Country>Netherlands</Country><MedlineTA>Talanta</MedlineTA><NlmUniqueID>2984816R</NlmUniqueID><ISSNLinking>0039-9140</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D006540">Herbicides</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D007202">Indicators and Reagents</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010573">Pesticide Residues</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D011759">Pyrrolidines</NameOfSubstance></Chemical><Chemical><RegistryNumber>SJG3M6RY6H</RegistryNumber><NameOfSubstance UI="D003996">Dicamba</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D002851" MajorTopicYN="N">Chromatography, High Pressure Liquid</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D032084" MajorTopicYN="N">Citrus sinensis</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D003996" MajorTopicYN="N">Dicamba</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005506" MajorTopicYN="N">Food Contamination</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005638" MajorTopicYN="N">Fruit</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D006540" MajorTopicYN="N">Herbicides</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D007202" MajorTopicYN="N">Indicators and Reagents</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010573" MajorTopicYN="N">Pesticide Residues</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D011759" MajorTopicYN="N">Pyrrolidines</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D012639" MajorTopicYN="N">Seeds</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013025" MajorTopicYN="N">Soybeans</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D021241" MajorTopicYN="N">Spectrometry, Mass, Electrospray Ionization</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D053719" MajorTopicYN="N">Tandem Mass Spectrometry</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D003313" MajorTopicYN="N">Zea mays</DescriptorName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Dicamba</Keyword><Keyword MajorTopicYN="N">HPLC–MS/MS</Keyword><Keyword MajorTopicYN="N">Ion-pairing reagent</Keyword><Keyword MajorTopicYN="N">Raw agricultural commodities (RACs)</Keyword><Keyword MajorTopicYN="N">Residue analysis</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>10</Month><Day>22</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2015</Year><Month>11</Month><Day>16</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2015</Year><Month>11</Month><Day>17</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>1</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>1</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>10</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">26717820</ArticleId><ArticleId IdType="pii">S0039-9140(15)30497-5</ArticleId><ArticleId IdType="doi">10.1016/j.talanta.2015.11.043</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>États-Unis</li></country><region><li>Missouri (État)</li><li>Texas</li></region></list><tree><country name="États-Unis"><region name="Texas"><name sortKey="Guo, Hongyue" sort="Guo, Hongyue" uniqKey="Guo H" first="Hongyue" last="Guo">Hongyue Guo</name></region><name sortKey="Armstrong, Daniel W" sort="Armstrong, Daniel W" uniqKey="Armstrong D" first="Daniel W" last="Armstrong">Daniel W. Armstrong</name><name sortKey="Riter, Leah S" sort="Riter, Leah S" uniqKey="Riter L" first="Leah S" last="Riter">Leah S. Riter</name><name sortKey="Wujcik, Chad E" sort="Wujcik, Chad E" uniqKey="Wujcik C" first="Chad E" last="Wujcik">Chad E. Wujcik</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Bois/explor/OrangerV1/Data/Ncbi/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001E42 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd -nk 001E42 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Bois
|area= OrangerV1
|flux= Ncbi
|étape= Merge
|type= RBID
|clé= pubmed:26717820
|texte= Quantitative analysis of dicamba residues in raw agricultural commodities with the use of ion-pairing reagents in LC-ESI-MS/MS.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/RBID.i -Sk "pubmed:26717820" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd \
| NlmPubMed2Wicri -a OrangerV1
| This area was generated with Dilib version V0.6.25. |  |