One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.
Identifieur interne : 001D40 ( Main/Curation ); précédent : 001D39; suivant : 001D41One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.
Auteurs : Remedios Fernández [Espagne] ; Antonia Garrido Frenich ; José Luis Martínez Vidal ; Roberto Romero González ; María Elena Hernández TorresSource :
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry [ 1348-2246 ] ; 2009.
Descripteurs français
- Wicri :
- geographic : Espagne.
English descriptors
- KwdEn :
- Benzimidazoles (analysis), Carbamates (analysis), Chromatography, Liquid (methods), Citrus (chemistry), Citrus sinensis (chemistry), Drug Stability, Fruit (chemistry), Ivermectin (analogs & derivatives), Ivermectin (analysis), Pesticide Residues (analysis), Pesticides (analysis), Plant Extracts (chemistry), Reproducibility of Results, Spain, Tandem Mass Spectrometry (methods), Time Factors.
- MESH :
- chemical , analogs & derivatives : Ivermectin.
- chemical , analysis : Benzimidazoles, Carbamates, Ivermectin, Pesticide Residues, Pesticides.
- geographic : Spain.
- chemistry : Citrus, Citrus sinensis, Fruit, Plant Extracts.
- methods : Chromatography, Liquid, Tandem Mass Spectrometry.
- Drug Stability, Reproducibility of Results, Time Factors.
Abstract
A rapid method has been developed for monitoring five multiclass pesticides commonly used in citrus fruits. The determination is performed by ultra-performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS), after extraction with a mixture of ethyl acetate and sodium sulfate. The method has been validated for orange matrix. Mean recoveries obtained were between 74-110% with a repeatability precision of < 7%, intermediate precision of < 10% and reproducibility precision of < 17%. Linearity over the range 0.010-0.150 mg/kg was demonstrated (r(2) > or = 0.99) with limits of quantification (LOQs) of < or = 0.01 mg/kg. Also, an analytical study focused on the stability of pesticide residues in orange extracts under storage was performed. The method has been applied to the analysis of 365 samples from the agricultural area of the Valencian Community (Spain). Of 103 samples that contained pesticide residues, only abamectin in 2 samples and carbendazim in 5 samples slightly exceeded the European maximum residue limits (MRLs).
PubMed: 19359795
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000962
- to stream PubMed, to step Curation: Pour aller vers cette notice dans l'étape Curation :000962
- to stream PubMed, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000962
- to stream Ncbi, to step Merge: Pour aller vers cette notice dans l'étape Curation :000988
- to stream Ncbi, to step Curation: Pour aller vers cette notice dans l'étape Curation :000988
- to stream Ncbi, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :000988
- to stream Main, to step Merge: Pour aller vers cette notice dans l'étape Curation :001D88
Links to Exploration step
pubmed:19359795Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.</title><author><name sortKey="Fernandez, Remedios" sort="Fernandez, Remedios" uniqKey="Fernandez R" first="Remedios" last="Fernández">Remedios Fernández</name><affiliation wicri:level="2"><nlm:affiliation>Laboratory of Pesticide Residues LAB, Calablanca Bajo, 04009 Almería, Spain.</nlm:affiliation><country xml:lang="fr">Espagne</country><wicri:regionArea>Laboratory of Pesticide Residues LAB, Calablanca Bajo, 04009 Almería</wicri:regionArea><placeName><region nuts="2" type="communauté">Andalousie</region></placeName></affiliation></author><author><name sortKey="Garrido Frenich, Antonia" sort="Garrido Frenich, Antonia" uniqKey="Garrido Frenich A" first="Antonia" last="Garrido Frenich">Antonia Garrido Frenich</name></author><author><name sortKey="Martinez Vidal, Jose Luis" sort="Martinez Vidal, Jose Luis" uniqKey="Martinez Vidal J" first="José Luis" last="Martínez Vidal">José Luis Martínez Vidal</name></author><author><name sortKey="Romero Gonzalez, Roberto" sort="Romero Gonzalez, Roberto" uniqKey="Romero Gonzalez R" first="Roberto" last="Romero González">Roberto Romero González</name></author><author><name sortKey="Hernandez Torres, Maria Elena" sort="Hernandez Torres, Maria Elena" uniqKey="Hernandez Torres M" first="María Elena" last="Hernández Torres">María Elena Hernández Torres</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2009">2009</date><idno type="RBID">pubmed:19359795</idno><idno type="pmid">19359795</idno><idno type="wicri:Area/PubMed/Corpus">000962</idno><idno type="wicri:Area/PubMed/Curation">000962</idno><idno type="wicri:Area/PubMed/Checkpoint">000962</idno><idno type="wicri:Area/Ncbi/Merge">000988</idno><idno type="wicri:Area/Ncbi/Curation">000988</idno><idno type="wicri:Area/Ncbi/Checkpoint">000988</idno><idno type="wicri:Area/Main/Merge">001D88</idno><idno type="wicri:Area/Main/Curation">001D40</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.</title><author><name sortKey="Fernandez, Remedios" sort="Fernandez, Remedios" uniqKey="Fernandez R" first="Remedios" last="Fernández">Remedios Fernández</name><affiliation wicri:level="2"><nlm:affiliation>Laboratory of Pesticide Residues LAB, Calablanca Bajo, 04009 Almería, Spain.</nlm:affiliation><country xml:lang="fr">Espagne</country><wicri:regionArea>Laboratory of Pesticide Residues LAB, Calablanca Bajo, 04009 Almería</wicri:regionArea><placeName><region nuts="2" type="communauté">Andalousie</region></placeName></affiliation></author><author><name sortKey="Garrido Frenich, Antonia" sort="Garrido Frenich, Antonia" uniqKey="Garrido Frenich A" first="Antonia" last="Garrido Frenich">Antonia Garrido Frenich</name></author><author><name sortKey="Martinez Vidal, Jose Luis" sort="Martinez Vidal, Jose Luis" uniqKey="Martinez Vidal J" first="José Luis" last="Martínez Vidal">José Luis Martínez Vidal</name></author><author><name sortKey="Romero Gonzalez, Roberto" sort="Romero Gonzalez, Roberto" uniqKey="Romero Gonzalez R" first="Roberto" last="Romero González">Roberto Romero González</name></author><author><name sortKey="Hernandez Torres, Maria Elena" sort="Hernandez Torres, Maria Elena" uniqKey="Hernandez Torres M" first="María Elena" last="Hernández Torres">María Elena Hernández Torres</name></author></analytic><series><title level="j">Analytical sciences : the international journal of the Japan Society for Analytical Chemistry</title><idno type="eISSN">1348-2246</idno><imprint><date when="2009" type="published">2009</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Benzimidazoles (analysis)</term><term>Carbamates (analysis)</term><term>Chromatography, Liquid (methods)</term><term>Citrus (chemistry)</term><term>Citrus sinensis (chemistry)</term><term>Drug Stability</term><term>Fruit (chemistry)</term><term>Ivermectin (analogs & derivatives)</term><term>Ivermectin (analysis)</term><term>Pesticide Residues (analysis)</term><term>Pesticides (analysis)</term><term>Plant Extracts (chemistry)</term><term>Reproducibility of Results</term><term>Spain</term><term>Tandem Mass Spectrometry (methods)</term><term>Time Factors</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analogs & derivatives" xml:lang="en"><term>Ivermectin</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Benzimidazoles</term><term>Carbamates</term><term>Ivermectin</term><term>Pesticide Residues</term><term>Pesticides</term></keywords><keywords scheme="MESH" type="geographic" xml:lang="en"><term>Spain</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Citrus</term><term>Citrus sinensis</term><term>Fruit</term><term>Plant Extracts</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Chromatography, Liquid</term><term>Tandem Mass Spectrometry</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Drug Stability</term><term>Reproducibility of Results</term><term>Time Factors</term></keywords><keywords scheme="Wicri" type="geographic" xml:lang="fr"><term>Espagne</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A rapid method has been developed for monitoring five multiclass pesticides commonly used in citrus fruits. The determination is performed by ultra-performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS), after extraction with a mixture of ethyl acetate and sodium sulfate. The method has been validated for orange matrix. Mean recoveries obtained were between 74-110% with a repeatability precision of < 7%, intermediate precision of < 10% and reproducibility precision of < 17%. Linearity over the range 0.010-0.150 mg/kg was demonstrated (r(2) > or = 0.99) with limits of quantification (LOQs) of < or = 0.01 mg/kg. Also, an analytical study focused on the stability of pesticide residues in orange extracts under storage was performed. The method has been applied to the analysis of 365 samples from the agricultural area of the Valencian Community (Spain). Of 103 samples that contained pesticide residues, only abamectin in 2 samples and carbendazim in 5 samples slightly exceeded the European maximum residue limits (MRLs).</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Bois/explor/OrangerV1/Data/Main/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001D40 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Curation/biblio.hfd -nk 001D40 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Bois
|area= OrangerV1
|flux= Main
|étape= Curation
|type= RBID
|clé= pubmed:19359795
|texte= One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Curation/RBID.i -Sk "pubmed:19359795" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Curation/biblio.hfd \
| NlmPubMed2Wicri -a OrangerV1
| This area was generated with Dilib version V0.6.25. |  |