One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.
Identifieur interne : 000962 ( PubMed/Corpus ); précédent : 000961; suivant : 000963One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.
Auteurs : Remedios Fernández ; Antonia Garrido Frenich ; José Luis Martínez Vidal ; Roberto Romero González ; María Elena Hernández TorresSource :
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry [ 1348-2246 ] ; 2009.
English descriptors
- KwdEn :
- Benzimidazoles (analysis), Carbamates (analysis), Chromatography, Liquid (methods), Citrus (chemistry), Citrus sinensis (chemistry), Drug Stability, Fruit (chemistry), Ivermectin (analogs & derivatives), Ivermectin (analysis), Pesticide Residues (analysis), Pesticides (analysis), Plant Extracts (chemistry), Reproducibility of Results, Spain, Tandem Mass Spectrometry (methods), Time Factors.
- MESH :
- chemical , analogs & derivatives : Ivermectin.
- chemical , analysis : Benzimidazoles, Carbamates, Ivermectin, Pesticide Residues, Pesticides.
- geographic : Spain.
- chemistry : Citrus, Citrus sinensis, Fruit, Plant Extracts.
- methods : Chromatography, Liquid, Tandem Mass Spectrometry.
- Drug Stability, Reproducibility of Results, Time Factors.
Abstract
A rapid method has been developed for monitoring five multiclass pesticides commonly used in citrus fruits. The determination is performed by ultra-performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS), after extraction with a mixture of ethyl acetate and sodium sulfate. The method has been validated for orange matrix. Mean recoveries obtained were between 74-110% with a repeatability precision of < 7%, intermediate precision of < 10% and reproducibility precision of < 17%. Linearity over the range 0.010-0.150 mg/kg was demonstrated (r(2) > or = 0.99) with limits of quantification (LOQs) of < or = 0.01 mg/kg. Also, an analytical study focused on the stability of pesticide residues in orange extracts under storage was performed. The method has been applied to the analysis of 365 samples from the agricultural area of the Valencian Community (Spain). Of 103 samples that contained pesticide residues, only abamectin in 2 samples and carbendazim in 5 samples slightly exceeded the European maximum residue limits (MRLs).
PubMed: 19359795
Links to Exploration step
pubmed:19359795Le document en format XML
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The determination is performed by ultra-performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS), after extraction with a mixture of ethyl acetate and sodium sulfate. The method has been validated for orange matrix. Mean recoveries obtained were between 74-110% with a repeatability precision of < 7%, intermediate precision of < 10% and reproducibility precision of < 17%. Linearity over the range 0.010-0.150 mg/kg was demonstrated (r(2) > or = 0.99) with limits of quantification (LOQs) of < or = 0.01 mg/kg. Also, an analytical study focused on the stability of pesticide residues in orange extracts under storage was performed. The method has been applied to the analysis of 365 samples from the agricultural area of the Valencian Community (Spain). Of 103 samples that contained pesticide residues, only abamectin in 2 samples and carbendazim in 5 samples slightly exceeded the European maximum residue limits (MRLs).</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">19359795</PMID><DateCreated><Year>2009</Year><Month>4</Month><Day>10</Day></DateCreated><DateCompleted><Year>2009</Year><Month>06</Month><Day>08</Day></DateCompleted><DateRevised><Year>2013</Year><Month>5</Month><Day>28</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1348-2246</ISSN><JournalIssue CitedMedium="Internet"><Volume>25</Volume><Issue>4</Issue><PubDate><Year>2009</Year><Month>Apr</Month></PubDate></JournalIssue><Title>Analytical sciences : the international journal of the Japan Society for Analytical Chemistry</Title><ISOAbbreviation>Anal Sci</ISOAbbreviation></Journal><ArticleTitle>One-year routine application of a new and rapid method based on ultra performance liquid chromatography-tandem mass spectrometry to the analysis of selected pesticides in citrus fruits.</ArticleTitle><Pagination><MedlinePgn>535-40</MedlinePgn></Pagination><Abstract><AbstractText>A rapid method has been developed for monitoring five multiclass pesticides commonly used in citrus fruits. The determination is performed by ultra-performance liquid chromatography coupled to tandem mass spectrometry (UPLC-MS/MS), after extraction with a mixture of ethyl acetate and sodium sulfate. The method has been validated for orange matrix. Mean recoveries obtained were between 74-110% with a repeatability precision of < 7%, intermediate precision of < 10% and reproducibility precision of < 17%. Linearity over the range 0.010-0.150 mg/kg was demonstrated (r(2) > or = 0.99) with limits of quantification (LOQs) of < or = 0.01 mg/kg. Also, an analytical study focused on the stability of pesticide residues in orange extracts under storage was performed. The method has been applied to the analysis of 365 samples from the agricultural area of the Valencian Community (Spain). Of 103 samples that contained pesticide residues, only abamectin in 2 samples and carbendazim in 5 samples slightly exceeded the European maximum residue limits (MRLs).</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Fernández</LastName><ForeName>Remedios</ForeName><Initials>R</Initials><AffiliationInfo><Affiliation>Laboratory of Pesticide Residues LAB, Calablanca Bajo, 04009 Almería, Spain.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Garrido Frenich</LastName><ForeName>Antonia</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Martínez Vidal</LastName><ForeName>José Luis</ForeName><Initials>JL</Initials></Author><Author ValidYN="Y"><LastName>Romero González</LastName><ForeName>Roberto</ForeName><Initials>R</Initials></Author><Author ValidYN="Y"><LastName>Hernández Torres</LastName><ForeName>María Elena</ForeName><Initials>ME</Initials></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>Japan</Country><MedlineTA>Anal Sci</MedlineTA><NlmUniqueID>8511078</NlmUniqueID><ISSNLinking>0910-6340</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D001562">Benzimidazoles</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D002219">Carbamates</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010573">Pesticide Residues</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010575">Pesticides</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010936">Plant Extracts</NameOfSubstance></Chemical><Chemical><RegistryNumber>70288-86-7</RegistryNumber><NameOfSubstance UI="D007559">Ivermectin</NameOfSubstance></Chemical><Chemical><RegistryNumber>71751-41-2</RegistryNumber><NameOfSubstance UI="C048324">abamectin</NameOfSubstance></Chemical><Chemical><RegistryNumber>H75J14AA89</RegistryNumber><NameOfSubstance UI="C006698">carbendazim</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D001562" MajorTopicYN="N">Benzimidazoles</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D002219" MajorTopicYN="N">Carbamates</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D002853" MajorTopicYN="N">Chromatography, Liquid</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D002957" MajorTopicYN="N">Citrus</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D032084" MajorTopicYN="N">Citrus sinensis</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D004355" MajorTopicYN="N">Drug Stability</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D005638" MajorTopicYN="N">Fruit</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D007559" MajorTopicYN="N">Ivermectin</DescriptorName><QualifierName UI="Q000031" MajorTopicYN="N">analogs & derivatives</QualifierName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010573" MajorTopicYN="N">Pesticide Residues</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010575" MajorTopicYN="N">Pesticides</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D010936" MajorTopicYN="N">Plant Extracts</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D015203" MajorTopicYN="N">Reproducibility of Results</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013030" MajorTopicYN="N" Type="Geographic">Spain</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D053719" MajorTopicYN="N">Tandem Mass Spectrometry</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013997" MajorTopicYN="N">Time Factors</DescriptorName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2009</Year><Month>4</Month><Day>11</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2009</Year><Month>4</Month><Day>11</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2009</Year><Month>6</Month><Day>9</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">19359795</ArticleId><ArticleId IdType="pii">JST.JSTAGE/analsci/25.535</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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