Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.
Identifieur interne : 001305 ( PubMed/Curation ); précédent : 001304; suivant : 001306Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.
Auteurs : Wasinee Phonsri [Australie] ; Casey G. Davies [Nouvelle-Zélande] ; Guy N L. Jameson [Nouvelle-Zélande] ; Boujemaa Moubaraki [Australie] ; Jas S. Ward [Nouvelle-Zélande] ; Paul E. Kruger [Nouvelle-Zélande] ; Guillaume Chastanet [France] ; Keith S. Murray [Australie]Source :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2017.
Abstract
[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.
DOI: 10.1039/c6cc10040f
PubMed: 28074968
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<front><div type="abstract" xml:lang="en">[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.</div>
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