A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.
Identifieur interne : 003033 ( PubMed/Checkpoint ); précédent : 003032; suivant : 003034A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.
Auteurs : Jamie Hicks ; Emma J. Underhill ; Christos E. Kefalidis ; Laurent Maron [France] ; Cameron Jones [États-Unis]Source :
- Angewandte Chemie (International ed. in English) [ 1521-3773 ] ; 2015.
Abstract
Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.
DOI: 10.1002/anie.201504818
PubMed: 26126428
Affiliations:
Links toward previous steps (curation, corpus...)
Links to Exploration step
pubmed:26126428Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</title><author><name sortKey="Hicks, Jamie" sort="Hicks, Jamie" uniqKey="Hicks J" first="Jamie" last="Hicks">Jamie Hicks</name><affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation><wicri:noCountry code="subField">3800 (Australia) http://monash.edu/science/jonesgroup.</wicri:noCountry></affiliation></author><author><name sortKey="Underhill, Emma J" sort="Underhill, Emma J" uniqKey="Underhill E" first="Emma J" last="Underhill">Emma J. Underhill</name><affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation><wicri:noCountry code="subField">3800 (Australia) http://monash.edu/science/jonesgroup.</wicri:noCountry></affiliation></author><author><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name><affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</nlm:affiliation><wicri:noCountry code="subField">31077 Toulouse (France)</wicri:noCountry></affiliation></author><author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name><affiliation wicri:level="1"><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</nlm:affiliation><country wicri:rule="url">France</country></affiliation></author><author><name sortKey="Jones, Cameron" sort="Jones, Cameron" uniqKey="Jones C" first="Cameron" last="Jones">Cameron Jones</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</nlm:affiliation><country wicri:rule="url">États-Unis</country></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2015">2015</date><idno type="RBID">pubmed:26126428</idno><idno type="pmid">26126428</idno><idno type="doi">10.1002/anie.201504818</idno><idno type="wicri:Area/PubMed/Corpus">002B02</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002B02</idno><idno type="wicri:Area/PubMed/Curation">002A31</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">002A31</idno><idno type="wicri:Area/PubMed/Checkpoint">002A31</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">002A31</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</title><author><name sortKey="Hicks, Jamie" sort="Hicks, Jamie" uniqKey="Hicks J" first="Jamie" last="Hicks">Jamie Hicks</name><affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation><wicri:noCountry code="subField">3800 (Australia) http://monash.edu/science/jonesgroup.</wicri:noCountry></affiliation></author><author><name sortKey="Underhill, Emma J" sort="Underhill, Emma J" uniqKey="Underhill E" first="Emma J" last="Underhill">Emma J. Underhill</name><affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation><wicri:noCountry code="subField">3800 (Australia) http://monash.edu/science/jonesgroup.</wicri:noCountry></affiliation></author><author><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name><affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</nlm:affiliation><wicri:noCountry code="subField">31077 Toulouse (France)</wicri:noCountry></affiliation></author><author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name><affiliation wicri:level="1"><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</nlm:affiliation><country wicri:rule="url">France</country></affiliation></author><author><name sortKey="Jones, Cameron" sort="Jones, Cameron" uniqKey="Jones C" first="Cameron" last="Jones">Cameron Jones</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</nlm:affiliation><country wicri:rule="url">États-Unis</country></affiliation></author></analytic><series><title level="j">Angewandte Chemie (International ed. in English)</title><idno type="eISSN">1521-3773</idno><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26126428</PMID><DateCreated><Year>2015</Year><Month>08</Month><Day>10</Day></DateCreated><DateCompleted><Year>2015</Year><Month>10</Month><Day>19</Day></DateCompleted><DateRevised><Year>2015</Year><Month>08</Month><Day>10</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1521-3773</ISSN><JournalIssue CitedMedium="Internet"><Volume>54</Volume><Issue>34</Issue><PubDate><Year>2015</Year><Month>Aug</Month><Day>17</Day></PubDate></JournalIssue><Title>Angewandte Chemie (International ed. in English)</Title><ISOAbbreviation>Angew. Chem. Int. Ed. Engl.</ISOAbbreviation></Journal><ArticleTitle>A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</ArticleTitle><Pagination><MedlinePgn>10000-4</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1002/anie.201504818</ELocationID><Abstract><AbstractText>Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.</AbstractText><CopyrightInformation>© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Hicks</LastName><ForeName>Jamie</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Underhill</LastName><ForeName>Emma J</ForeName><Initials>EJ</Initials><AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kefalidis</LastName><ForeName>Christos E</ForeName><Initials>CE</Initials><AffiliationInfo><Affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Maron</LastName><ForeName>Laurent</ForeName><Initials>L</Initials><AffiliationInfo><Affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jones</LastName><ForeName>Cameron</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2015</Year><Month>06</Month><Day>30</Day></ArticleDate></Article><MedlineJournalInfo><Country>Germany</Country><MedlineTA>Angew Chem Int Ed Engl</MedlineTA><NlmUniqueID>0370543</NlmUniqueID><ISSNLinking>1433-7851</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">DFT calculations</Keyword><Keyword MajorTopicYN="N">magnesium</Keyword><Keyword MajorTopicYN="N">metal-metal bonding</Keyword><Keyword MajorTopicYN="N">mixed valence</Keyword><Keyword MajorTopicYN="N">zinc</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>05</Month><Day>27</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2015</Year><Month>7</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2015</Year><Month>7</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2015</Year><Month>7</Month><Day>2</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">26126428</ArticleId><ArticleId IdType="doi">10.1002/anie.201504818</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>France</li><li>États-Unis</li></country></list><tree><noCountry><name sortKey="Hicks, Jamie" sort="Hicks, Jamie" uniqKey="Hicks J" first="Jamie" last="Hicks">Jamie Hicks</name><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name><name sortKey="Underhill, Emma J" sort="Underhill, Emma J" uniqKey="Underhill E" first="Emma J" last="Underhill">Emma J. Underhill</name></noCountry><country name="France"><noRegion><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name></noRegion></country><country name="États-Unis"><noRegion><name sortKey="Jones, Cameron" sort="Jones, Cameron" uniqKey="Jones C" first="Cameron" last="Jones">Cameron Jones</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/PubMed/Checkpoint
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 003033 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd -nk 003033 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Asie
|area= AustralieFrV1
|flux= PubMed
|étape= Checkpoint
|type= RBID
|clé= pubmed:26126428
|texte= A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/RBID.i -Sk "pubmed:26126428" \
| HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd \
| NlmPubMed2Wicri -a AustralieFrV1
| This area was generated with Dilib version V0.6.33. |  |