A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.
Identifieur interne : 002B02 ( PubMed/Corpus ); précédent : 002B01; suivant : 002B03A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.
Auteurs : Jamie Hicks ; Emma J. Underhill ; Christos E. Kefalidis ; Laurent Maron ; Cameron JonesSource :
- Angewandte Chemie (International ed. in English) [ 1521-3773 ] ; 2015.
Abstract
Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.
DOI: 10.1002/anie.201504818
PubMed: 26126428
Links to Exploration step
pubmed:26126428Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</title>
<author><name sortKey="Hicks, Jamie" sort="Hicks, Jamie" uniqKey="Hicks J" first="Jamie" last="Hicks">Jamie Hicks</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Underhill, Emma J" sort="Underhill, Emma J" uniqKey="Underhill E" first="Emma J" last="Underhill">Emma J. Underhill</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name>
<affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name>
<affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Jones, Cameron" sort="Jones, Cameron" uniqKey="Jones C" first="Cameron" last="Jones">Cameron Jones</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</nlm:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2015">2015</date>
<idno type="RBID">pubmed:26126428</idno>
<idno type="pmid">26126428</idno>
<idno type="doi">10.1002/anie.201504818</idno>
<idno type="wicri:Area/PubMed/Corpus">002B02</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002B02</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</title>
<author><name sortKey="Hicks, Jamie" sort="Hicks, Jamie" uniqKey="Hicks J" first="Jamie" last="Hicks">Jamie Hicks</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Underhill, Emma J" sort="Underhill, Emma J" uniqKey="Underhill E" first="Emma J" last="Underhill">Emma J. Underhill</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Kefalidis, Christos E" sort="Kefalidis, Christos E" uniqKey="Kefalidis C" first="Christos E" last="Kefalidis">Christos E. Kefalidis</name>
<affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Maron, Laurent" sort="Maron, Laurent" uniqKey="Maron L" first="Laurent" last="Maron">Laurent Maron</name>
<affiliation><nlm:affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Jones, Cameron" sort="Jones, Cameron" uniqKey="Jones C" first="Cameron" last="Jones">Cameron Jones</name>
<affiliation><nlm:affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</nlm:affiliation>
</affiliation>
</author>
</analytic>
<series><title level="j">Angewandte Chemie (International ed. in English)</title>
<idno type="eISSN">1521-3773</idno>
<imprint><date when="2015" type="published">2015</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26126428</PMID>
<DateCreated><Year>2015</Year>
<Month>08</Month>
<Day>10</Day>
</DateCreated>
<DateCompleted><Year>2015</Year>
<Month>10</Month>
<Day>19</Day>
</DateCompleted>
<DateRevised><Year>2015</Year>
<Month>08</Month>
<Day>10</Day>
</DateRevised>
<Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1521-3773</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>54</Volume>
<Issue>34</Issue>
<PubDate><Year>2015</Year>
<Month>Aug</Month>
<Day>17</Day>
</PubDate>
</JournalIssue>
<Title>Angewandte Chemie (International ed. in English)</Title>
<ISOAbbreviation>Angew. Chem. Int. Ed. Engl.</ISOAbbreviation>
</Journal>
<ArticleTitle>A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms.</ArticleTitle>
<Pagination><MedlinePgn>10000-4</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1002/anie.201504818</ELocationID>
<Abstract><AbstractText>Reduction of a variety of extremely bulky amido Group 12 metal halide complexes, [LMX(THF)(0,1)] (L=amide; M=Zn, Cd, or Hg; X=halide) with a magnesium(I) dimer gave a homologous series of two-coordinate metal(I) dimers, [L'MML'] (L'=N(Ar(†))(SiMe3), Ar(†)=C6H2{C(H)Ph2}2Pr(i)-2,6,4); and the formally zinc(0) complex, [L*ZnMg((Mes)Nacnac)] (L*=N(Ar*)(SiPr(i)3); Ar*=C6H2{C(H)Ph2}2Me-2,6,4; (Mes)Nacnac=[(MesNCMe)2CH](-), Mes=mesityl), which contains the first unsupported Zn-Mg bond. Two equivalents of [L*ZnMg((Mes)Nacnac)] react with ZnBr2 or ZnBr2(tmeda) to give the mixed valence, two-coordinate, linear tri-zinc complex, [L*Zn(I)Zn(0)Zn(I)L*], and the first zinc(I) halide complex, [L*ZnZnBr(tmeda)], respectively. The analogues [L*ZnMZnL*] (M=Cd or Hg), were also prepared, the Cd species contains the first Zn-Cd bond in a molecular compound. Metal-metal bonding was studied by DFT calculations.</AbstractText>
<CopyrightInformation>© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Hicks</LastName>
<ForeName>Jamie</ForeName>
<Initials>J</Initials>
<AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Underhill</LastName>
<ForeName>Emma J</ForeName>
<Initials>EJ</Initials>
<AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Kefalidis</LastName>
<ForeName>Christos E</ForeName>
<Initials>CE</Initials>
<AffiliationInfo><Affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France).</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Maron</LastName>
<ForeName>Laurent</ForeName>
<Initials>L</Initials>
<AffiliationInfo><Affiliation>Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse (France). laurent.maron@irsamc.ups-tlse.fr.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Jones</LastName>
<ForeName>Cameron</ForeName>
<Initials>C</Initials>
<AffiliationInfo><Affiliation>School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia) http://monash.edu/science/jonesgroup. cameron.jones@monash.edu.</Affiliation>
</AffiliationInfo>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2015</Year>
<Month>06</Month>
<Day>30</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>Germany</Country>
<MedlineTA>Angew Chem Int Ed Engl</MedlineTA>
<NlmUniqueID>0370543</NlmUniqueID>
<ISSNLinking>1433-7851</ISSNLinking>
</MedlineJournalInfo>
<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">DFT calculations</Keyword>
<Keyword MajorTopicYN="N">magnesium</Keyword>
<Keyword MajorTopicYN="N">metal-metal bonding</Keyword>
<Keyword MajorTopicYN="N">mixed valence</Keyword>
<Keyword MajorTopicYN="N">zinc</Keyword>
</KeywordList>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year>
<Month>05</Month>
<Day>27</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2015</Year>
<Month>7</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2015</Year>
<Month>7</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2015</Year>
<Month>7</Month>
<Day>2</Day>
<Hour>6</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">26126428</ArticleId>
<ArticleId IdType="doi">10.1002/anie.201504818</ArticleId>
</ArticleIdList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/PubMed/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002B02 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 002B02 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Asie |area= AustralieFrV1 |flux= PubMed |étape= Corpus |type= RBID |clé= pubmed:26126428 |texte= A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i -Sk "pubmed:26126428" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd \ | NlmPubMed2Wicri -a AustralieFrV1
This area was generated with Dilib version V0.6.33. |