Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.
Identifieur interne : 000309 ( PubMed/Checkpoint ); précédent : 000308; suivant : 000310Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.
Auteurs : Wasinee Phonsri [Australie] ; Casey G. Davies [Nouvelle-Zélande] ; Guy N L. Jameson [Nouvelle-Zélande] ; Boujemaa Moubaraki [Australie] ; Jas S. Ward [Nouvelle-Zélande] ; Paul E. Kruger [Nouvelle-Zélande] ; Guillaume Chastanet [France] ; Keith S. Murray [Australie]Source :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2017.
Abstract
[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.
DOI: 10.1039/c6cc10040f
PubMed: 28074968
Affiliations:
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Davies</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054, New Zealand.</nlm:affiliation><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054</wicri:regionArea><wicri:noRegion>9054</wicri:noRegion></affiliation></author><author><name sortKey="Jameson, Guy N L" sort="Jameson, Guy N L" uniqKey="Jameson G" first="Guy N L" last="Jameson">Guy N L. Jameson</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054, New Zealand.</nlm:affiliation><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054</wicri:regionArea><wicri:noRegion>9054</wicri:noRegion></affiliation></author><author><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. keith.murray@monash.edu.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Clayton, Victoria 3800</wicri:regionArea><wicri:noRegion>Victoria 3800</wicri:noRegion></affiliation></author><author><name sortKey="Ward, Jas S" sort="Ward, Jas S" uniqKey="Ward J" first="Jas S" last="Ward">Jas S. Ward</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand.</nlm:affiliation><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041</wicri:regionArea><wicri:noRegion>Christchurch 8041</wicri:noRegion></affiliation></author><author><name sortKey="Kruger, Paul E" sort="Kruger, Paul E" uniqKey="Kruger P" first="Paul E" last="Kruger">Paul E. Kruger</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand.</nlm:affiliation><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041</wicri:regionArea><wicri:noRegion>Christchurch 8041</wicri:noRegion></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="4"><nlm:affiliation>CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac 33608, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac 33608</wicri:regionArea><wicri:noRegion>33608</wicri:noRegion><orgName type="university">Université de Bordeaux</orgName><placeName><settlement type="city">Bordeaux</settlement><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region></placeName></affiliation></author><author><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S" last="Murray">Keith S. Murray</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. keith.murray@monash.edu.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, Monash University, Clayton, Victoria 3800</wicri:regionArea><wicri:noRegion>Victoria 3800</wicri:noRegion></affiliation></author></analytic><series><title level="j">Chemical communications (Cambridge, England)</title><idno type="eISSN">1364-548X</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.</div></front></TEI><pubmed><MedlineCitation Status="In-Data-Review" Owner="NLM"><PMID Version="1">28074968</PMID><DateCreated><Year>2017</Year><Month>01</Month><Day>11</Day></DateCreated><DateRevised><Year>2017</Year><Month>08</Month><Day>25</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1364-548X</ISSN><JournalIssue CitedMedium="Internet"><Volume>53</Volume><Issue>8</Issue><PubDate><Year>2017</Year><Month>Jan</Month><Day>24</Day></PubDate></JournalIssue><Title>Chemical communications (Cambridge, England)</Title><ISOAbbreviation>Chem. Commun. (Camb.)</ISOAbbreviation></Journal><ArticleTitle>Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.</ArticleTitle><Pagination><MedlinePgn>1374-1377</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c6cc10040f</ELocationID><Abstract><AbstractText>[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Phonsri</LastName><ForeName>Wasinee</ForeName><Initials>W</Initials><Identifier Source="ORCID">http://orcid.org/0000-0001-7377-7484</Identifier><AffiliationInfo><Affiliation>School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. keith.murray@monash.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Davies</LastName><ForeName>Casey G</ForeName><Initials>CG</Initials><AffiliationInfo><Affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054, New Zealand.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Jameson</LastName><ForeName>Guy N L</ForeName><Initials>GNL</Initials><AffiliationInfo><Affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin, 9054, New Zealand.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Moubaraki</LastName><ForeName>Boujemaa</ForeName><Initials>B</Initials><AffiliationInfo><Affiliation>School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. keith.murray@monash.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ward</LastName><ForeName>Jas S</ForeName><Initials>JS</Initials><AffiliationInfo><Affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Kruger</LastName><ForeName>Paul E</ForeName><Initials>PE</Initials><AffiliationInfo><Affiliation>Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Private Bag 4800, Christchurch 8041, New Zealand.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Chastanet</LastName><ForeName>Guillaume</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac 33608, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Murray</LastName><ForeName>Keith S</ForeName><Initials>KS</Initials><Identifier Source="ORCID">http://orcid.org/0000-0003-4098-9389</Identifier><AffiliationInfo><Affiliation>School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. keith.murray@monash.edu.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Chem Commun (Camb)</MedlineTA><NlmUniqueID>9610838</NlmUniqueID><ISSNLinking>1359-7345</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2017</Year><Month>1</Month><Day>12</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2017</Year><Month>1</Month><Day>12</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2017</Year><Month>1</Month><Day>12</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">28074968</ArticleId><ArticleId IdType="doi">10.1039/c6cc10040f</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Australie</li><li>France</li><li>Nouvelle-Zélande</li></country><region><li>Aquitaine</li><li>Nouvelle-Aquitaine</li></region><settlement><li>Bordeaux</li></settlement><orgName><li>Université de Bordeaux</li></orgName></list><tree><country name="Australie"><noRegion><name sortKey="Phonsri, Wasinee" sort="Phonsri, Wasinee" uniqKey="Phonsri W" first="Wasinee" last="Phonsri">Wasinee Phonsri</name></noRegion><name sortKey="Moubaraki, Boujemaa" sort="Moubaraki, Boujemaa" uniqKey="Moubaraki B" first="Boujemaa" last="Moubaraki">Boujemaa Moubaraki</name><name sortKey="Murray, Keith S" sort="Murray, Keith S" uniqKey="Murray K" first="Keith S" last="Murray">Keith S. Murray</name></country><country name="Nouvelle-Zélande"><noRegion><name sortKey="Davies, Casey G" sort="Davies, Casey G" uniqKey="Davies C" first="Casey G" last="Davies">Casey G. Davies</name></noRegion><name sortKey="Jameson, Guy N L" sort="Jameson, Guy N L" uniqKey="Jameson G" first="Guy N L" last="Jameson">Guy N L. Jameson</name><name sortKey="Kruger, Paul E" sort="Kruger, Paul E" uniqKey="Kruger P" first="Paul E" last="Kruger">Paul E. Kruger</name><name sortKey="Ward, Jas S" sort="Ward, Jas S" uniqKey="Ward J" first="Jas S" last="Ward">Jas S. Ward</name></country><country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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