(η6-Benzophenone)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate
Identifieur interne : 002071 ( Pmc/Curation ); précédent : 002070; suivant : 002072(η6-Benzophenone)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate
Auteurs : Bradley T. Loughrey [Australie] ; Kevin Nadin [France] ; Michael L. Williams [Australie] ; Peter C. Healy [Australie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.
Abstract
The structure of the title compound, [Ru(C10H15)(C13H10O)](C24H20B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.
Url:
DOI: 10.1107/S1600536809042731
PubMed: 21578208
PubMed Central: 2971317
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PMC:2971317Le document en format XML
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-Benzophenone)(η<sup>5</sup>
-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate</title>
<author><name sortKey="Loughrey, Bradley T" sort="Loughrey, Bradley T" uniqKey="Loughrey B" first="Bradley T." last="Loughrey">Bradley T. Loughrey</name>
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<country xml:lang="fr">Australie</country>
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<author><name sortKey="Nadin, Kevin" sort="Nadin, Kevin" uniqKey="Nadin K" first="Kevin" last="Nadin">Kevin Nadin</name>
<affiliation wicri:level="1"><nlm:aff id="b">Département de Chimie, Faculté des Sciences, Université d’Orléans, Orléans BP 6759 45067,<country>France</country>
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<country xml:lang="fr">France</country>
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<author><name sortKey="Williams, Michael L" sort="Williams, Michael L" uniqKey="Williams M" first="Michael L." last="Williams">Michael L. Williams</name>
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</nlm:aff>
<country xml:lang="fr">Australie</country>
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<author><name sortKey="Healy, Peter C" sort="Healy, Peter C" uniqKey="Healy P" first="Peter C." last="Healy">Peter C. Healy</name>
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</nlm:aff>
<country xml:lang="fr">Australie</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">(η<sup>6</sup>
-Benzophenone)(η<sup>5</sup>
-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate</title>
<author><name sortKey="Loughrey, Bradley T" sort="Loughrey, Bradley T" uniqKey="Loughrey B" first="Bradley T." last="Loughrey">Bradley T. Loughrey</name>
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</nlm:aff>
<country xml:lang="fr">Australie</country>
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</author>
<author><name sortKey="Nadin, Kevin" sort="Nadin, Kevin" uniqKey="Nadin K" first="Kevin" last="Nadin">Kevin Nadin</name>
<affiliation wicri:level="1"><nlm:aff id="b">Département de Chimie, Faculté des Sciences, Université d’Orléans, Orléans BP 6759 45067,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Williams, Michael L" sort="Williams, Michael L" uniqKey="Williams M" first="Michael L." last="Williams">Michael L. Williams</name>
<affiliation wicri:level="1"><nlm:aff id="a">Eskitis Institute for Cell and Molecular Therapies, Griffith University, Brisbane 4111,<country>Australia</country>
</nlm:aff>
<country xml:lang="fr">Australie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</author>
<author><name sortKey="Healy, Peter C" sort="Healy, Peter C" uniqKey="Healy P" first="Peter C." last="Healy">Peter C. Healy</name>
<affiliation wicri:level="1"><nlm:aff id="a">Eskitis Institute for Cell and Molecular Therapies, Griffith University, Brisbane 4111,<country>Australia</country>
</nlm:aff>
<country xml:lang="fr">Australie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2009">2009</date>
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<front><div type="abstract" xml:lang="en"><p>The structure of the title compound, [Ru(C<sub>10</sub>
H<sub>15</sub>
)(C<sub>13</sub>
H<sub>10</sub>
O)](C<sub>24</sub>
H<sub>20</sub>
B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.</p>
</div>
</front>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
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<article-meta><article-id pub-id-type="pmid">21578208</article-id>
<article-id pub-id-type="pmc">2971317</article-id>
<article-id pub-id-type="publisher-id">lh2927</article-id>
<article-id pub-id-type="doi">10.1107/S1600536809042731</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536809042731</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>(η<sup>6</sup>
-Benzophenone)(η<sup>5</sup>
-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate</article-title>
<alt-title><italic>[Ru(C<sub>10</sub>
H<sub>15</sub>
)(C<sub>13</sub>
H<sub>10</sub>
O)](C<sub>24</sub>
H<sub>20</sub>
B)</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Loughrey</surname>
<given-names>Bradley T.</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Nadin</surname>
<given-names>Kevin</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Williams</surname>
<given-names>Michael L.</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Healy</surname>
<given-names>Peter C.</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<aff id="a"><label>a</label>
Eskitis Institute for Cell and Molecular Therapies, Griffith University, Brisbane 4111,<country>Australia</country>
</aff>
<aff id="b"><label>b</label>
Département de Chimie, Faculté des Sciences, Université d’Orléans, Orléans BP 6759 45067,<country>France</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>P.Healy@griffith.edu.au</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>11</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="epub"><day>31</day>
<month>10</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>31</day>
<month>10</month>
<year>2009</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
. </pmc-comment>
<volume>65</volume>
<issue>Pt 11</issue>
<issue-id pub-id-type="publisher-id">e091100</issue-id>
<fpage>m1486</fpage>
<lpage>m1486</lpage>
<history><date date-type="received"><day>13</day>
<month>10</month>
<year>2009</year>
</date>
<date date-type="accepted"><day>17</day>
<month>10</month>
<year>2009</year>
</date>
</history>
<permissions><copyright-statement>© Loughrey et al. 2009</copyright-statement>
<copyright-year>2009</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536809042731">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The structure of the title compound, [Ru(C<sub>10</sub>
H<sub>15</sub>
)(C<sub>13</sub>
H<sub>10</sub>
O)](C<sub>24</sub>
H<sub>20</sub>
B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetraphenylborate anions (Cp* = pentamethylcyclopentadienyl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.</p>
</abstract>
</article-meta>
</front>
</pmc>
</record>
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