Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions††Electronic supplementary information (ESI) available: Characterisation of materials. CCDC 1038403–1038407. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03114eClick here for additional data file.Click here for additional data file.
Identifieur interne : 000929 ( Pmc/Checkpoint ); précédent : 000928; suivant : 000930Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions††Electronic supplementary information (ESI) available: Characterisation of materials. CCDC 1038403–1038407. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03114eClick here for additional data file.Click here for additional data file.
Auteurs : Natasha F. Sciortino ; Katrina A. Zenere ; Maggie E. Corrigan ; Gregory J. Halder [États-Unis] ; Guillaume Chastanet [France] ; Jean-François Létard [France] ; Cameron J. Kepert ; Suzanne M. NevilleSource :
- Chemical Science [ 2041-6520 ] ; 2016.
Abstract
A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.
Url:
DOI: 10.1039/c6sc03114e
PubMed: 28451220
PubMed Central: 5297924
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Four-step iron(<sc>ii</sc>) spin state cascade driven by antagonistic solid state interactions<xref ref-type="fn" rid="fn1">†</xref><fn id="fn1"><p>†Electronic supplementary information (ESI) available: Characterisation of materials. CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:aff id="affb"> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</nlm:aff><country xml:lang="fr">États-Unis</country><wicri:regionArea> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">28451220</idno><idno type="pmc">5297924</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5297924</idno><idno type="RBID">PMC:5297924</idno><idno type="doi">10.1039/c6sc03114e</idno><date when="2016">2016</date><idno type="wicri:Area/Pmc/Corpus">002377</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">002377</idno><idno type="wicri:Area/Pmc/Curation">002227</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">002227</idno><idno type="wicri:Area/Pmc/Checkpoint">000929</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000929</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Four-step iron(<sc>ii</sc>) spin state cascade driven by antagonistic solid state interactions<xref ref-type="fn" rid="fn1">†</xref><fn id="fn1"><p>†Electronic supplementary information (ESI) available: Characterisation of materials. CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:aff id="affb"> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</nlm:aff><country xml:lang="fr">États-Unis</country><wicri:regionArea> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author></analytic><series><title level="j">Chemical Science</title><idno type="ISSN">2041-6520</idno><idno type="eISSN">2041-6539</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p><graphic xlink:href="c6sc03114e-ga.jpg" id="ga" position="float" orientation="portrait"></graphic>A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Kahn, O" uniqKey="Kahn O">O. Kahn</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Gutlich, P" uniqKey="Gutlich P">P. 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<front><journal-meta><journal-id journal-id-type="nlm-ta">Chem Sci</journal-id><journal-id journal-id-type="iso-abbrev">Chem Sci</journal-id><journal-title-group><journal-title>Chemical Science</journal-title></journal-title-group><issn pub-type="ppub">2041-6520</issn><issn pub-type="epub">2041-6539</issn><publisher><publisher-name>Royal Society of Chemistry</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">28451220</article-id><article-id pub-id-type="pmc">5297924</article-id><article-id pub-id-type="publisher-id">c6sc03114e</article-id><article-id pub-id-type="doi">10.1039/c6sc03114e</article-id><article-categories><subj-group subj-group-type="heading"><subject>Chemistry</subject></subj-group></article-categories><title-group><article-title>Four-step iron(<sc>ii</sc>) spin state cascade driven by antagonistic solid state interactions<xref ref-type="fn" rid="fn1">†</xref><fn id="fn1"><p>†Electronic supplementary information (ESI) available: Characterisation of materials. CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Sciortino</surname><given-names>Natasha F.</given-names></name><xref ref-type="aff" rid="affa">a</xref></contrib><contrib contrib-type="author"><name><surname>Zenere</surname><given-names>Katrina A.</given-names></name><xref ref-type="aff" rid="affa">a</xref></contrib><contrib contrib-type="author"><name><surname>Corrigan</surname><given-names>Maggie E.</given-names></name><xref ref-type="aff" rid="affa">a</xref></contrib><contrib contrib-type="author"><name><surname>Halder</surname><given-names>Gregory J.</given-names></name><xref ref-type="aff" rid="affb">b</xref></contrib><contrib contrib-type="author"><name><surname>Chastanet</surname><given-names>Guillaume</given-names></name><xref ref-type="aff" rid="affc">c</xref></contrib><contrib contrib-type="author"><name><surname>Létard</surname><given-names>Jean-François</given-names></name><xref ref-type="aff" rid="affc">c</xref></contrib><contrib contrib-type="author" corresp="yes"><name><surname>Kepert</surname><given-names>Cameron J.</given-names></name><xref ref-type="aff" rid="affa">a</xref></contrib><contrib contrib-type="author" corresp="yes"><name><surname>Neville</surname><given-names>Suzanne M.</given-names></name><xref ref-type="aff" rid="affa">a</xref></contrib></contrib-group><aff id="affa"><label>a</label> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</aff><aff id="affb"><label>b</label> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</aff><aff id="affc"><label>c</label> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</aff><pub-date pub-type="ppub"><day>1</day><month>1</month><year>2017</year></pub-date><pub-date pub-type="epub"><day>12</day><month>9</month><year>2016</year></pub-date><volume>8</volume><issue>1</issue><fpage>701</fpage><lpage>707</lpage><history><date date-type="received"><day>14</day><month>7</month><year>2016</year></date><date date-type="accepted"><day>11</day><month>9</month><year>2016</year></date></history><permissions><copyright-statement>This journal is © The Royal Society of Chemistry 2016</copyright-statement><copyright-year>2016</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by-nc/3.0/"><license-p><pmc-comment>CREATIVE COMMONS</pmc-comment>This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (<ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by-nc/3.0/">http://creativecommons.org/licenses/by-nc/3.0/</ext-link>) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.</license-p></license></permissions><abstract abstract-type="toc"><p><graphic xlink:href="c6sc03114e-ga.jpg" id="ga" position="float" orientation="portrait"></graphic>A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.</p></abstract><abstract><p>A four-stepped cascade of Fe(<sc>ii</sc>) high spin (HS) to low spin (LS) states is demonstrated in a family of 2-D Hofmann materials, [Fe<sub>3</sub><sup>II</sup>(saltrz)<sub>6</sub>(M<sup>II</sup>(CN)<sub>4</sub>)<sub>3</sub>]·8(H<sub>2</sub>O) (M<sup>II</sup> = Pd (<bold>1<sup>Pd</sup></bold>), Pt (<bold>1<sup>Pt</sup></bold>); saltrz = (<italic>E</italic>)-2-(((4<italic>H</italic>-1,2,4-triazol-4-yl)imino)methyl)phenol). Alongside the fully HS and LS Fe(<sc>ii</sc>) states, fractional spin state stabilization occurs at HS/LS values of 5/6, 2/3, and 1/6. This unconventional spin state periodicity is driven by the presence of multiple spin crossover (SCO) active Fe(<sc>ii</sc>) sites which are in subtly distinct environments driven by a network of antagonistic host–host and host–guest interactions. Alternating long- and short-range magnetostructural ordering is achieved over the five distinct spin state ratios HS<sup>1.0</sup>LS<sup>0.0</sup>, HS<sup>0.833</sup>LS<sup>0.167</sup>, HS<sup>0.667</sup>LS<sup>0.333</sup>, HS<sup>0.167</sup>LS<sup>0.833</sup>, and HS<sup>0.0</sup>LS<sup>1.0</sup> owing to the flexibility of this 2-D interdigitated lattice topology interconnected by intermolecular interactions. A distinct wave-like spin state patterning is structurally evidenced for each intermediate phase.</p></abstract></article-meta></front></pmc><affiliations><list><country><li>France</li><li>États-Unis</li></country><region><li>Aquitaine</li><li>Illinois</li><li>Nouvelle-Aquitaine</li></region><settlement><li>, Pessac </li></settlement></list><tree><noCountry><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name></noCountry><country name="États-Unis"><region name="Illinois"><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name></region></country><country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name></region><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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