AustralieFrV1, PascalFrancis, Curation, bibRecord, 004833

Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)

Identifieur interne : 004833 ( PascalFrancis/Curation ); précédent : 004832; suivant : 004834

Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)

Auteurs : Gordon J. Thorogood [Australie] ; Pierre-Yves Orain [France] ; Mickael Ouvry [Australie] ; Bruno Piriou [France] ; Tony Tedesco [Australie] ; Kia S. Wallwork [Australie] ; Jan Herrmann [Australie] ; Michael James [Australie]

Source :

Solid state sciences [ 1293-2558 ] ; 2011.

RBID : Pascal:12-0042967

Descripteurs français

Pascal (Inist)
- Structure cristalline, Magnétisme, Addition lanthanide, Calcium, Addition europium, Europium, Diffraction RX, Solution solide, Thermogravimétrie, Cobalt, Valence, Méthode Rietveld, Diagramme poudre, Réseau quadratique, Oxyde de cobalt, Gadolinium, Réseau orthorhombique, Haute température, Mesure magnétique, Paramagnétisme, Antiferromagnétisme, Interaction faible, Interaction échange, Etat spin, Addition calcium, Etat mixte, Transition phase, Sm, K2NiF4, 6166.
Wicri :
- geographic : Valence (Drôme).
- topic : Calcium, Cobalt.

English descriptors

KwdEn :
- Antiferromagnetism, Calcium, Calcium additions, Cobalt, Cobalt oxide, Crystal structure, Europium, Europium additions, Exchange interactions, Gadolinium, High temperature, Magnetic measurement, Magnetism, Mixed state, Orthorhombic lattices, Paramagnetism, Phase transitions, Powder pattern, Rare earth additions, Rietveld method, Solid solutions, Spin state, Tetragonal lattices, Thermogravimetry, Valence, Weak interactions, XRD.

Abstract

Single-phase samples of Ln2 xCaxCoO4+δ (Ln = Pr3+ - Gd3+) around x ˜ 1 have been prepared. For the first time, the phase field for these compounds has been defined using powder X-ray diffraction and a very narrow solid solution was observed. Under our synthetic conditions, the K2NiF4 structure was not formed for the large La3+ ion, or for compositions containing the smaller rare earths ions (

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A03		`1`		`@0 Solid state sci.`
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A08	`01`	`1`	`ENG`	`@1 Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)`
A11	`01`	`1`		`@1 THOROGOOD (Gordon J.)`
A11	`02`	`1`		`@1 ORAIN (Pierre-Yves)`
A11	`03`	`1`		`@1 OUVRY (Mickael)`
A11	`04`	`1`		`@1 PIRIOU (Bruno)`
A11	`05`	`1`		`@1 TEDESCO (Tony)`
A11	`06`	`1`		`@1 WALLWORK (Kia S.)`
A11	`07`	`1`		`@1 HERRMANN (Jan)`
A11	`08`	`1`		`@1 JAMES (Michael)`
A14	`01`			`@1 Australian Nuclear Science and Technology Organisation, Locked Bag 2001 @2 Kirrawee DC NSW 2232 @3 AUS @Z 1 aut. @Z 3 aut. @Z 5 aut. @Z 8 aut.`
A14	`02`			`@1 ISM2/BiosCiences UMR-CNRS 6263, Université Paul Cézanne Aix-Marseille III, Avenue Escadrille Normandie-Niemen @2 13397 Marseille @3 FRA @Z 2 aut.`
A14	`03`			`@1 CIRAD, unite de recherche Biomasse-Energie, TA B-42/16, 73 rue J.F. Breton @2 34398 Montpellier @3 FRA @Z 4 aut.`
A14	`04`			`@1 Australian Synchrotron, 800 Blackburn Road @2 Clayton VIC. 3168 @3 AUS @Z 6 aut.`
A14	`05`			`@1 National Measurement Institute, PO Box 264 @2 Lindfield NSW 2070 @3 AUS @Z 7 aut.`
A14	`06`			`@1 School of Chemistry, University of New South Wales @2 Kensington NSW 2052 @3 AUS @Z 8 aut.`
A20				`@1 2113-2123`
A21				`@1 2011`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 11118 @5 354000505954880080`
A44				`@0 0000 @1 © 2012 INIST-CNRS. All rights reserved.`
A45				`@0 70 ref.`
A47	`01`	`1`		`@0 12-0042967`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Solid state sciences`
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C01	`01`		`ENG`	@0 Single-phase samples of Ln2 xCaxCoO4+δ (Ln = Pr3+ - Gd3+) around x ˜ 1 have been prepared. For the first time, the phase field for these compounds has been defined using powder X-ray diffraction and a very narrow solid solution was observed. Under our synthetic conditions, the K2NiF4 structure was not formed for the large La3+ ion, or for compositions containing the smaller rare earths ions (<Gd3+) and Y3+. Thermogravimetric analysis indicates average cobalt oxidation states ranging between ˜3.2+ and ˜3.3+. Rietveld refinement of structures using synchrotron powder X-ray diffraction data indicates that the larger rare earth ions LnCaCoO4+δ (Ln = Pr3+ - Sm3+) form tetragonal (I4/mmm) structures at room temperature, while (Ln = Eu3+, Gd3+) crystallised with orthorhombic (Bmab) structures. The evolution of structure between the low temperature orthorhombic form and the high temperature tetragonal form was investigated between 80 K and 575 K using high-resolution synchrotron X-ray powder diffraction. Orthorhombic to tetragonal transitions were observed for SmCaCoO4.17 (T˜230 K), EuCaCoO4.13 (T˜320 K) and GdCaCoO4.11 (T˜465 K). Magnetic measurements for LnCaCoO4+δ (Ln = Pr3+ - Gd3+) indicate paramagnetic behaviour along with weak antiferromagnetic interactions and Co3+ in a 6t2g low-spin state. PrCaCoO4.17 was found to order antiferromagnetically below 15 K.
C02	`01`	`3`		`@0 001B60A66`
C03	`01`	`3`	`FRE`	`@0 Structure cristalline @5 01`
C03	`01`	`3`	`ENG`	`@0 Crystal structure @5 01`
C03	`02`	`3`	`FRE`	`@0 Magnétisme @5 02`
C03	`02`	`3`	`ENG`	`@0 Magnetism @5 02`
C03	`03`	`3`	`FRE`	`@0 Addition lanthanide @5 03`
C03	`03`	`3`	`ENG`	`@0 Rare earth additions @5 03`
C03	`04`	`3`	`FRE`	`@0 Calcium @2 NC @5 04`
C03	`04`	`3`	`ENG`	`@0 Calcium @2 NC @5 04`
C03	`05`	`3`	`FRE`	`@0 Addition europium @5 05`
C03	`05`	`3`	`ENG`	`@0 Europium additions @5 05`
C03	`06`	`3`	`FRE`	`@0 Europium @2 NC @5 06`
C03	`06`	`3`	`ENG`	`@0 Europium @2 NC @5 06`
C03	`07`	`3`	`FRE`	`@0 Diffraction RX @5 07`
C03	`07`	`3`	`ENG`	`@0 XRD @5 07`
C03	`08`	`3`	`FRE`	`@0 Solution solide @5 08`
C03	`08`	`3`	`ENG`	`@0 Solid solutions @5 08`
C03	`09`	`3`	`FRE`	`@0 Thermogravimétrie @5 09`
C03	`09`	`3`	`ENG`	`@0 Thermogravimetry @5 09`
C03	`10`	`3`	`FRE`	`@0 Cobalt @2 NC @5 10`
C03	`10`	`3`	`ENG`	`@0 Cobalt @2 NC @5 10`
C03	`11`	`3`	`FRE`	`@0 Valence @5 11`
C03	`11`	`3`	`ENG`	`@0 Valence @5 11`
C03	`12`	`X`	`FRE`	`@0 Méthode Rietveld @5 12`
C03	`12`	`X`	`ENG`	`@0 Rietveld method @5 12`
C03	`12`	`X`	`SPA`	`@0 Método Rietveld @5 12`
C03	`13`	`X`	`FRE`	`@0 Diagramme poudre @5 13`
C03	`13`	`X`	`ENG`	`@0 Powder pattern @5 13`
C03	`13`	`X`	`SPA`	`@0 Diagrama polvo @5 13`
C03	`14`	`3`	`FRE`	`@0 Réseau quadratique @5 14`
C03	`14`	`3`	`ENG`	`@0 Tetragonal lattices @5 14`
C03	`15`	`X`	`FRE`	`@0 Oxyde de cobalt @5 15`
C03	`15`	`X`	`ENG`	`@0 Cobalt oxide @5 15`
C03	`15`	`X`	`SPA`	`@0 Cobalto óxido @5 15`
C03	`16`	`3`	`FRE`	`@0 Gadolinium @2 NC @5 16`
C03	`16`	`3`	`ENG`	`@0 Gadolinium @2 NC @5 16`
C03	`17`	`3`	`FRE`	`@0 Réseau orthorhombique @5 17`
C03	`17`	`3`	`ENG`	`@0 Orthorhombic lattices @5 17`
C03	`18`	`X`	`FRE`	`@0 Haute température @5 29`
C03	`18`	`X`	`ENG`	`@0 High temperature @5 29`
C03	`18`	`X`	`SPA`	`@0 Alta temperatura @5 29`
C03	`19`	`X`	`FRE`	`@0 Mesure magnétique @5 30`
C03	`19`	`X`	`ENG`	`@0 Magnetic measurement @5 30`
C03	`19`	`X`	`SPA`	`@0 Medida magnética @5 30`
C03	`20`	`3`	`FRE`	`@0 Paramagnétisme @5 31`
C03	`20`	`3`	`ENG`	`@0 Paramagnetism @5 31`
C03	`21`	`3`	`FRE`	`@0 Antiferromagnétisme @5 32`
C03	`21`	`3`	`ENG`	`@0 Antiferromagnetism @5 32`
C03	`22`	`3`	`FRE`	`@0 Interaction faible @5 33`
C03	`22`	`3`	`ENG`	`@0 Weak interactions @5 33`
C03	`23`	`3`	`FRE`	`@0 Interaction échange @5 34`
C03	`23`	`3`	`ENG`	`@0 Exchange interactions @5 34`
C03	`24`	`X`	`FRE`	`@0 Etat spin @5 35`
C03	`24`	`X`	`ENG`	`@0 Spin state @5 35`
C03	`24`	`X`	`SPA`	`@0 Estado espín @5 35`
C03	`25`	`3`	`FRE`	`@0 Addition calcium @5 36`
C03	`25`	`3`	`ENG`	`@0 Calcium additions @5 36`
C03	`26`	`3`	`FRE`	`@0 Etat mixte @5 37`
C03	`26`	`3`	`ENG`	`@0 Mixed state @5 37`
C03	`27`	`X`	`FRE`	`@0 Transition phase @5 38`
C03	`27`	`X`	`ENG`	`@0 Phase transitions @5 38`
C03	`27`	`X`	`SPA`	`@0 Transición fase @5 38`
C03	`28`	`3`	`FRE`	`@0 Sm @4 INC @5 46`
C03	`29`	`3`	`FRE`	`@0 K2NiF4 @4 INC @5 47`
C03	`30`	`3`	`FRE`	`@0 6166 @4 INC @5 71`
N21				`@1 023`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

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Pascal:12-0042967

Le document en format XML

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<author><name sortKey="James, Michael" sort="James, Michael" uniqKey="James M" first="Michael" last="James">Michael James</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)</title>
<author><name sortKey="Thorogood, Gordon J" sort="Thorogood, Gordon J" uniqKey="Thorogood G" first="Gordon J." last="Thorogood">Gordon J. Thorogood</name>
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<author><name sortKey="Orain, Pierre Yves" sort="Orain, Pierre Yves" uniqKey="Orain P" first="Pierre-Yves" last="Orain">Pierre-Yves Orain</name>
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<s2>13397 Marseille</s2>
<s3>FRA</s3>
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<author><name sortKey="Ouvry, Mickael" sort="Ouvry, Mickael" uniqKey="Ouvry M" first="Mickael" last="Ouvry">Mickael Ouvry</name>
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<author><name sortKey="Piriou, Bruno" sort="Piriou, Bruno" uniqKey="Piriou B" first="Bruno" last="Piriou">Bruno Piriou</name>
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<author><name sortKey="Tedesco, Tony" sort="Tedesco, Tony" uniqKey="Tedesco T" first="Tony" last="Tedesco">Tony Tedesco</name>
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<author><name sortKey="Wallwork, Kia S" sort="Wallwork, Kia S" uniqKey="Wallwork K" first="Kia S." last="Wallwork">Kia S. Wallwork</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Australian Synchrotron, 800 Blackburn Road</s1>
<s2>Clayton VIC. 3168</s2>
<s3>AUS</s3>
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</inist:fA14>
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</affiliation>
</author>
<author><name sortKey="Herrmann, Jan" sort="Herrmann, Jan" uniqKey="Herrmann J" first="Jan" last="Herrmann">Jan Herrmann</name>
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<s2>Lindfield NSW 2070</s2>
<s3>AUS</s3>
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</inist:fA14>
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</affiliation>
</author>
<author><name sortKey="James, Michael" sort="James, Michael" uniqKey="James M" first="Michael" last="James">Michael James</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Australian Nuclear Science and Technology Organisation, Locked Bag 2001</s1>
<s2>Kirrawee DC NSW 2232</s2>
<s3>AUS</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>Australie</country>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="06"><s1>School of Chemistry, University of New South Wales</s1>
<s2>Kensington NSW 2052</s2>
<s3>AUS</s3>
<sZ>8 aut.</sZ>
</inist:fA14>
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</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
<idno type="ISSN">1293-2558</idno>
<imprint><date when="2011">2011</date>
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<seriesStmt><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
<idno type="ISSN">1293-2558</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term>
<term>Calcium</term>
<term>Calcium additions</term>
<term>Cobalt</term>
<term>Cobalt oxide</term>
<term>Crystal structure</term>
<term>Europium</term>
<term>Europium additions</term>
<term>Exchange interactions</term>
<term>Gadolinium</term>
<term>High temperature</term>
<term>Magnetic measurement</term>
<term>Magnetism</term>
<term>Mixed state</term>
<term>Orthorhombic lattices</term>
<term>Paramagnetism</term>
<term>Phase transitions</term>
<term>Powder pattern</term>
<term>Rare earth additions</term>
<term>Rietveld method</term>
<term>Solid solutions</term>
<term>Spin state</term>
<term>Tetragonal lattices</term>
<term>Thermogravimetry</term>
<term>Valence</term>
<term>Weak interactions</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Magnétisme</term>
<term>Addition lanthanide</term>
<term>Calcium</term>
<term>Addition europium</term>
<term>Europium</term>
<term>Diffraction RX</term>
<term>Solution solide</term>
<term>Thermogravimétrie</term>
<term>Cobalt</term>
<term>Valence</term>
<term>Méthode Rietveld</term>
<term>Diagramme poudre</term>
<term>Réseau quadratique</term>
<term>Oxyde de cobalt</term>
<term>Gadolinium</term>
<term>Réseau orthorhombique</term>
<term>Haute température</term>
<term>Mesure magnétique</term>
<term>Paramagnétisme</term>
<term>Antiferromagnétisme</term>
<term>Interaction faible</term>
<term>Interaction échange</term>
<term>Etat spin</term>
<term>Addition calcium</term>
<term>Etat mixte</term>
<term>Transition phase</term>
<term>Sm</term>
<term>K2NiF4</term>
<term>6166</term>
</keywords>
<keywords scheme="Wicri" type="geographic" xml:lang="fr"><term>Valence (Drôme)</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Calcium</term>
<term>Cobalt</term>
</keywords>
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<front><div type="abstract" xml:lang="en">Single-phase samples of Ln2 xCaxCoO4+δ (Ln = Pr3+ - Gd3+) around x ˜ 1 have been prepared. For the first time, the phase field for these compounds has been defined using powder X-ray diffraction and a very narrow solid solution was observed. Under our synthetic conditions, the K2NiF4 structure was not formed for the large La3+ ion, or for compositions containing the smaller rare earths ions (</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1293-2558</s0>
</fA01>
<fA03 i2="1"><s0>Solid state sci.</s0>
</fA03>
<fA05><s2>13</s2>
</fA05>
<fA06><s2>12</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>THOROGOOD (Gordon J.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>ORAIN (Pierre-Yves)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>OUVRY (Mickael)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>PIRIOU (Bruno)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>TEDESCO (Tony)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>WALLWORK (Kia S.)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>HERRMANN (Jan)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>JAMES (Michael)</s1>
</fA11>
<fA14 i1="01"><s1>Australian Nuclear Science and Technology Organisation, Locked Bag 2001</s1>
<s2>Kirrawee DC NSW 2232</s2>
<s3>AUS</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>ISM2/BiosCiences UMR-CNRS 6263, Université Paul Cézanne Aix-Marseille III, Avenue Escadrille Normandie-Niemen</s1>
<s2>13397 Marseille</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>CIRAD, unite de recherche Biomasse-Energie, TA B-42/16, 73 rue J.F. Breton</s1>
<s2>34398 Montpellier</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>Australian Synchrotron, 800 Blackburn Road</s1>
<s2>Clayton VIC. 3168</s2>
<s3>AUS</s3>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="05"><s1>National Measurement Institute, PO Box 264</s1>
<s2>Lindfield NSW 2070</s2>
<s3>AUS</s3>
<sZ>7 aut.</sZ>
</fA14>
<fA14 i1="06"><s1>School of Chemistry, University of New South Wales</s1>
<s2>Kensington NSW 2052</s2>
<s3>AUS</s3>
<sZ>8 aut.</sZ>
</fA14>
<fA20><s1>2113-2123</s1>
</fA20>
<fA21><s1>2011</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>11118</s2>
<s5>354000505954880080</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>70 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0042967</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Solid state sciences</s0>
</fA64>
<fA66 i1="01"><s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Single-phase samples of Ln2 xCaxCoO4+δ (Ln = Pr3+ - Gd3+) around x ˜ 1 have been prepared. For the first time, the phase field for these compounds has been defined using powder X-ray diffraction and a very narrow solid solution was observed. Under our synthetic conditions, the K2NiF4 structure was not formed for the large La3+ ion, or for compositions containing the smaller rare earths ions (</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Magnétisme</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Magnetism</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Addition lanthanide</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Rare earth additions</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Calcium</s0>
<s2>NC</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Calcium</s0>
<s2>NC</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Addition europium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Europium additions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Europium</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Europium</s0>
<s2>NC</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>XRD</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Solution solide</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Solid solutions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Thermogravimétrie</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Thermogravimetry</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Cobalt</s0>
<s2>NC</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Cobalt</s0>
<s2>NC</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Valence</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Valence</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Méthode Rietveld</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Rietveld method</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Método Rietveld</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Diagramme poudre</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Powder pattern</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Diagrama polvo</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Réseau quadratique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Tetragonal lattices</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Oxyde de cobalt</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Cobalt oxide</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Cobalto óxido</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Gadolinium</s0>
<s2>NC</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>Gadolinium</s0>
<s2>NC</s2>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Réseau orthorhombique</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG"><s0>Orthorhombic lattices</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Haute température</s0>
<s5>29</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>High temperature</s0>
<s5>29</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Alta temperatura</s0>
<s5>29</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Mesure magnétique</s0>
<s5>30</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Magnetic measurement</s0>
<s5>30</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Medida magnética</s0>
<s5>30</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Paramagnétisme</s0>
<s5>31</s5>
</fC03>
<fC03 i1="20" i2="3" l="ENG"><s0>Paramagnetism</s0>
<s5>31</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Antiferromagnétisme</s0>
<s5>32</s5>
</fC03>
<fC03 i1="21" i2="3" l="ENG"><s0>Antiferromagnetism</s0>
<s5>32</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE"><s0>Interaction faible</s0>
<s5>33</s5>
</fC03>
<fC03 i1="22" i2="3" l="ENG"><s0>Weak interactions</s0>
<s5>33</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE"><s0>Interaction échange</s0>
<s5>34</s5>
</fC03>
<fC03 i1="23" i2="3" l="ENG"><s0>Exchange interactions</s0>
<s5>34</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE"><s0>Etat spin</s0>
<s5>35</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG"><s0>Spin state</s0>
<s5>35</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA"><s0>Estado espín</s0>
<s5>35</s5>
</fC03>
<fC03 i1="25" i2="3" l="FRE"><s0>Addition calcium</s0>
<s5>36</s5>
</fC03>
<fC03 i1="25" i2="3" l="ENG"><s0>Calcium additions</s0>
<s5>36</s5>
</fC03>
<fC03 i1="26" i2="3" l="FRE"><s0>Etat mixte</s0>
<s5>37</s5>
</fC03>
<fC03 i1="26" i2="3" l="ENG"><s0>Mixed state</s0>
<s5>37</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE"><s0>Transition phase</s0>
<s5>38</s5>
</fC03>
<fC03 i1="27" i2="X" l="ENG"><s0>Phase transitions</s0>
<s5>38</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA"><s0>Transición fase</s0>
<s5>38</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE"><s0>Sm</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE"><s0>K2NiF4</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="30" i2="3" l="FRE"><s0>6166</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fN21><s1>023</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)

Structure, crystal chemistry and magnetism of rare earth calcium-doped cobaltates: Ln2-xCaxCoO4+δ (Ln = Pr, Nd, Sm, Eu and Gd)

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