Synthesis, Crystal Structures, and Properties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks
Identifieur interne : 002810 ( PascalFrancis/Checkpoint ); précédent : 002809; suivant : 002811Synthesis, Crystal Structures, and Properties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks
Auteurs : Hitoshi Kumagai [Japon] ; Motoko Akita-Tanaka [Japon] ; Satoshi Kawata [Japon] ; Katsuya Inoue [Japon] ; Cameron J. Kepert [Australie] ; Mohamedally Kurmoo [France]Source :
- Crystal growth & design [ 1528-7483 ] ; 2009.
Descripteurs français
- Pascal (Inist)
- Structure cristalline, Synthèse hydrothermale, Croissance cristalline, Propriété thermique, Propriété magnétique, Ligand, Métal transition, Polyèdre coordination, Coordinat bidenté, Liaison hydrogène, Amine, Carboxylate, Pyridine, Structure supramoléculaire, Cuivre, Nickel, Dioxyde de carbone, Matériau paramagnétique, Interaction faible, Interaction échange, Cu2S, 6166, 8110, 6540D, 6166H.
- Wicri :
English descriptors
- KwdEn :
- Amines, Bidentate ligand, Carbon dioxide, Carboxylates, Coordination polyhedron, Copper, Crystal growth, Crystal structure, Exchange interactions, Hydrogen bonds, Hydrothermal synthesis, Ligands, Magnetic properties, Nickel, Paramagnetic materials, Pyridine, Supramolecular structure, Thermal properties, Transition elements, Weak interactions.
Abstract
We report the hydrothermal syntheses, single-crystal structure determinations, and the thermal and magnetic properties of five binuclear complexes obtained from either a mixture of P and M 2,2'-biphenyldicarboxylate, (2,2'-bpdc)2-, or a mixture of cis- and trans-1,4-cyclohexanedicarboxylate, (1,4-chdc)2-, as bridging ligands, di-2-pyridylamine (dpa) as a capping terminal ligand, and a divalent transition metal (Cu, Co, and Ni). All five compounds, [Co2(2,2'-bpdc)2(dpa)2] (1), [Cu2(2,2'-bpdc)2(dpa)2].4H2O (2a), [Cu2(2,2'-bpdc)2(dpa)2] . 2(2,2'-bpdcH2) . H2O (2b), [Co2(cis-chdc)2(dpa)2] (3), and [Ni2(cis-chdc)2(dpa)2] (4), consist of neutral molecular squares of two metal centers bridged by two elbowed dicarboxylate, and each metal is capped by the chelating di-2-pyridylamine, In 1, the Co(II) adopts a tetrahedral coordination from two oxygen atoms of monodentate 2,2'-bpdc2- and two nitrogen atoms from dpa. In 2a and 2b, the Cu(II) adopts distorted octahedral geometry from two bidentate 2,2'-bpdc2- and one bidentate dpa. 1, 2a, and 2b contain both P and M forms of 2,2'-bpdc2-. 3 and 4 contain octahedral metal coordination with only the chair form of cis-chdc2- as bridging ligands in bidentate mode and bidentate peripheral dpa. In each of these complexes, hydrogen bonds between the amine nitrogen and a carboxylate oxygen atom and π-π overlap between the pyridine rings of the dpa define the supramolecular interactions which contribute to the crystals' stability. The magnetic properties are those of paramagnets with weak exchange interactions, as a consequence of the distant exchange pathway between nearest neighbor moment carriers.
Affiliations:
- Australie, France, Japon
- Alsace (région administrative), Grand Est, Nouvelle-Galles du Sud
- Strasbourg, Sydney
- Université de Strasbourg, Université de Sydney
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Kepert</name><affiliation wicri:level="4"><inist:fA14 i1="03"><s1>School of Chemistry, University of Sydney</s1><s2>NSW 2006</s2><s3>AUS</s3><sZ>5 aut.</sZ></inist:fA14><country>Australie</country><placeName><settlement type="city">Sydney</settlement><region type="état">Nouvelle-Galles du Sud</region></placeName><orgName type="university">Université de Sydney</orgName></affiliation></author><author><name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name><affiliation wicri:level="4"><inist:fA14 i1="04"><s1>Laboratoire de Chimie de Coordination Organique, UMR7740-CNRS, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal</s1><s2>67000 Strasbourg</s2><s3>FRA</s3><sZ>6 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">09-0309601</idno><date when="2009">2009</date><idno type="stanalyst">PASCAL 09-0309601 INIST</idno><idno type="RBID">Pascal:09-0309601</idno><idno type="wicri:Area/PascalFrancis/Corpus">002D07</idno><idno type="wicri:Area/PascalFrancis/Curation">003313</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">002810</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">002810</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, Crystal Structures, and Properties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks</title><author><name sortKey="Kumagai, Hitoshi" sort="Kumagai, Hitoshi" uniqKey="Kumagai H" first="Hitoshi" last="Kumagai">Hitoshi Kumagai</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institute for Molecular Science, Nishigounaka 38</s1><s2>Myoudaiji, Okazaki 444-8585</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Japon</country><wicri:noRegion>Myoudaiji, Okazaki 444-8585</wicri:noRegion></affiliation></author><author><name sortKey="Akita Tanaka, Motoko" sort="Akita Tanaka, Motoko" uniqKey="Akita Tanaka M" first="Motoko" last="Akita-Tanaka">Motoko Akita-Tanaka</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institute for Molecular Science, Nishigounaka 38</s1><s2>Myoudaiji, Okazaki 444-8585</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Japon</country><wicri:noRegion>Myoudaiji, Okazaki 444-8585</wicri:noRegion></affiliation></author><author><name sortKey="Kawata, Satoshi" sort="Kawata, Satoshi" uniqKey="Kawata S" first="Satoshi" last="Kawata">Satoshi Kawata</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Graduate School of Science, Osaka University</s1><s2>Toyonaka, Osaka 560-0043</s2><s3>JPN</s3><sZ>3 aut.</sZ></inist:fA14><country>Japon</country><wicri:noRegion>Toyonaka, Osaka 560-0043</wicri:noRegion></affiliation></author><author><name sortKey="Inoue, Katsuya" sort="Inoue, Katsuya" uniqKey="Inoue K" first="Katsuya" last="Inoue">Katsuya Inoue</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Institute for Molecular Science, Nishigounaka 38</s1><s2>Myoudaiji, Okazaki 444-8585</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Japon</country><wicri:noRegion>Myoudaiji, Okazaki 444-8585</wicri:noRegion></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation wicri:level="4"><inist:fA14 i1="03"><s1>School of Chemistry, University of Sydney</s1><s2>NSW 2006</s2><s3>AUS</s3><sZ>5 aut.</sZ></inist:fA14><country>Australie</country><placeName><settlement type="city">Sydney</settlement><region type="état">Nouvelle-Galles du Sud</region></placeName><orgName type="university">Université de Sydney</orgName></affiliation></author><author><name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name><affiliation wicri:level="4"><inist:fA14 i1="04"><s1>Laboratoire de Chimie de Coordination Organique, UMR7740-CNRS, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal</s1><s2>67000 Strasbourg</s2><s3>FRA</s3><sZ>6 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Alsace (région administrative)</region><settlement type="city">Strasbourg</settlement><settlement type="city">Strasbourg</settlement></placeName><orgName type="university">Université de Strasbourg</orgName></affiliation></author></analytic><series><title level="j" type="main">Crystal growth & design</title><title level="j" type="abbreviated">Cryst. growth des.</title><idno type="ISSN">1528-7483</idno><imprint><date when="2009">2009</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Crystal growth & design</title><title level="j" type="abbreviated">Cryst. growth des.</title><idno type="ISSN">1528-7483</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Amines</term><term>Bidentate ligand</term><term>Carbon dioxide</term><term>Carboxylates</term><term>Coordination polyhedron</term><term>Copper</term><term>Crystal growth</term><term>Crystal structure</term><term>Exchange interactions</term><term>Hydrogen bonds</term><term>Hydrothermal synthesis</term><term>Ligands</term><term>Magnetic properties</term><term>Nickel</term><term>Paramagnetic materials</term><term>Pyridine</term><term>Supramolecular structure</term><term>Thermal properties</term><term>Transition elements</term><term>Weak interactions</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term><term>Synthèse hydrothermale</term><term>Croissance cristalline</term><term>Propriété thermique</term><term>Propriété magnétique</term><term>Ligand</term><term>Métal transition</term><term>Polyèdre coordination</term><term>Coordinat bidenté</term><term>Liaison hydrogène</term><term>Amine</term><term>Carboxylate</term><term>Pyridine</term><term>Structure supramoléculaire</term><term>Cuivre</term><term>Nickel</term><term>Dioxyde de carbone</term><term>Matériau paramagnétique</term><term>Interaction faible</term><term>Interaction échange</term><term>Cu2S</term><term>6166</term><term>8110</term><term>6540D</term><term>6166H</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Cuivre</term><term>Nickel</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">We report the hydrothermal syntheses, single-crystal structure determinations, and the thermal and magnetic properties of five binuclear complexes obtained from either a mixture of P and M 2,2'-biphenyldicarboxylate, (2,2'-bpdc)<sup>2-</sup>, or a mixture of cis- and trans-1,4-cyclohexanedicarboxylate, (1,4-chdc)<sup>2-</sup>, as bridging ligands, di-2-pyridylamine (dpa) as a capping terminal ligand, and a divalent transition metal (Cu, Co, and Ni). All five compounds, [Co<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>] (1), [Cu<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>].4H<sub>2</sub>O (2a), [Cu<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>] . 2(2,2'-bpdcH<sub>2</sub>) . H<sub>2</sub>O (2b), [Co<sub>2</sub>(cis-chdc)<sub>2</sub>(dpa)<sub>2</sub>] (3), and [Ni<sub>2</sub>(cis-chdc)<sub>2</sub>(dpa)<sub>2</sub>] (4), consist of neutral molecular squares of two metal centers bridged by two elbowed dicarboxylate, and each metal is capped by the chelating di-2-pyridylamine, In 1, the Co(II) adopts a tetrahedral coordination from two oxygen atoms of monodentate 2,2'-bpdc<sup>2-</sup> and two nitrogen atoms from dpa. In 2a and 2b, the Cu(II) adopts distorted octahedral geometry from two bidentate 2,2'-bpdc<sup>2-</sup> and one bidentate dpa. 1, 2a, and 2b contain both P and M forms of 2,2'-bpdc<sup>2-</sup>. 3 and 4 contain octahedral metal coordination with only the chair form of cis-chdc<sup>2-</sup> as bridging ligands in bidentate mode and bidentate peripheral dpa. In each of these complexes, hydrogen bonds between the amine nitrogen and a carboxylate oxygen atom and π-π overlap between the pyridine rings of the dpa define the supramolecular interactions which contribute to the crystals' stability. The magnetic properties are those of paramagnets with weak exchange interactions, as a consequence of the distant exchange pathway between nearest neighbor moment carriers.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1528-7483</s0></fA01><fA03 i2="1"><s0>Cryst. growth des.</s0></fA03><fA05><s2>9</s2></fA05><fA06><s2>6</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Synthesis, Crystal Structures, and Properties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks</s1></fA08><fA11 i1="01" i2="1"><s1>KUMAGAI (Hitoshi)</s1></fA11><fA11 i1="02" i2="1"><s1>AKITA-TANAKA (Motoko)</s1></fA11><fA11 i1="03" i2="1"><s1>KAWATA (Satoshi)</s1></fA11><fA11 i1="04" i2="1"><s1>INOUE (Katsuya)</s1></fA11><fA11 i1="05" i2="1"><s1>KEPERT (Cameron J.)</s1></fA11><fA11 i1="06" i2="1"><s1>KURMOO (Mohamedally)</s1></fA11><fA14 i1="01"><s1>Institute for Molecular Science, Nishigounaka 38</s1><s2>Myoudaiji, Okazaki 444-8585</s2><s3>JPN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Chemistry, Graduate School of Science, Osaka University</s1><s2>Toyonaka, Osaka 560-0043</s2><s3>JPN</s3><sZ>3 aut.</sZ></fA14><fA14 i1="03"><s1>School of Chemistry, University of Sydney</s1><s2>NSW 2006</s2><s3>AUS</s3><sZ>5 aut.</sZ></fA14><fA14 i1="04"><s1>Laboratoire de Chimie de Coordination Organique, UMR7740-CNRS, Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal</s1><s2>67000 Strasbourg</s2><s3>FRA</s3><sZ>6 aut.</sZ></fA14><fA20><s1>2734-2741</s1></fA20><fA21><s1>2009</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>27261</s2><s5>354000188286090330</s5></fA43><fA44><s0>0000</s0><s1>© 2009 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>15 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>09-0309601</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Crystal growth & design</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>We report the hydrothermal syntheses, single-crystal structure determinations, and the thermal and magnetic properties of five binuclear complexes obtained from either a mixture of P and M 2,2'-biphenyldicarboxylate, (2,2'-bpdc)<sup>2-</sup>, or a mixture of cis- and trans-1,4-cyclohexanedicarboxylate, (1,4-chdc)<sup>2-</sup>, as bridging ligands, di-2-pyridylamine (dpa) as a capping terminal ligand, and a divalent transition metal (Cu, Co, and Ni). All five compounds, [Co<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>] (1), [Cu<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>].4H<sub>2</sub>O (2a), [Cu<sub>2</sub>(2,2'-bpdc)<sub>2</sub>(dpa)<sub>2</sub>] . 2(2,2'-bpdcH<sub>2</sub>) . H<sub>2</sub>O (2b), [Co<sub>2</sub>(cis-chdc)<sub>2</sub>(dpa)<sub>2</sub>] (3), and [Ni<sub>2</sub>(cis-chdc)<sub>2</sub>(dpa)<sub>2</sub>] (4), consist of neutral molecular squares of two metal centers bridged by two elbowed dicarboxylate, and each metal is capped by the chelating di-2-pyridylamine, In 1, the Co(II) adopts a tetrahedral coordination from two oxygen atoms of monodentate 2,2'-bpdc<sup>2-</sup> and two nitrogen atoms from dpa. In 2a and 2b, the Cu(II) adopts distorted octahedral geometry from two bidentate 2,2'-bpdc<sup>2-</sup> and one bidentate dpa. 1, 2a, and 2b contain both P and M forms of 2,2'-bpdc<sup>2-</sup>. 3 and 4 contain octahedral metal coordination with only the chair form of cis-chdc<sup>2-</sup> as bridging ligands in bidentate mode and bidentate peripheral dpa. In each of these complexes, hydrogen bonds between the amine nitrogen and a carboxylate oxygen atom and π-π overlap between the pyridine rings of the dpa define the supramolecular interactions which contribute to the crystals' stability. The magnetic properties are those of paramagnets with weak exchange interactions, as a consequence of the distant exchange pathway between nearest neighbor moment carriers.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66H</s0></fC02><fC02 i1="02" i2="3"><s0>001B80A10</s0></fC02><fC02 i1="03" i2="3"><s0>001B60E40D</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Crystal structure</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Synthèse hydrothermale</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Hydrothermal synthesis</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Croissance cristalline</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Crystal growth</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Propriété thermique</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Thermal properties</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Propriété magnétique</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Magnetic properties</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Ligand</s0><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Ligands</s0><s5>06</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Métal transition</s0><s5>07</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Transition elements</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Polyèdre coordination</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Coordination polyhedron</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Poliedro coordinación</s0><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Coordinat bidenté</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Bidentate ligand</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Ligando bidentado</s0><s5>09</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Liaison hydrogène</s0><s5>10</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Hydrogen bonds</s0><s5>10</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Amine</s0><s5>11</s5></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Amines</s0><s5>11</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Carboxylate</s0><s5>12</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Carboxylates</s0><s5>12</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Pyridine</s0><s2>NK</s2><s5>13</s5></fC03><fC03 i1="13" i2="3" l="ENG"><s0>Pyridine</s0><s2>NK</s2><s5>13</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Structure supramoléculaire</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Supramolecular structure</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Estructura supramolecular</s0><s5>14</s5></fC03><fC03 i1="15" i2="3" l="FRE"><s0>Cuivre</s0><s2>NC</s2><s5>15</s5></fC03><fC03 i1="15" i2="3" l="ENG"><s0>Copper</s0><s2>NC</s2><s5>15</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>Nickel</s0><s2>NC</s2><s5>16</s5></fC03><fC03 i1="16" i2="3" l="ENG"><s0>Nickel</s0><s2>NC</s2><s5>16</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Dioxyde de carbone</s0><s2>NK</s2><s2>FX</s2><s5>17</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Carbon dioxide</s0><s2>NK</s2><s2>FX</s2><s5>17</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Carbono dióxido</s0><s2>NK</s2><s2>FX</s2><s5>17</s5></fC03><fC03 i1="18" i2="3" l="FRE"><s0>Matériau paramagnétique</s0><s5>18</s5></fC03><fC03 i1="18" i2="3" l="ENG"><s0>Paramagnetic materials</s0><s5>18</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>Interaction faible</s0><s5>29</s5></fC03><fC03 i1="19" i2="3" l="ENG"><s0>Weak interactions</s0><s5>29</s5></fC03><fC03 i1="20" i2="3" l="FRE"><s0>Interaction échange</s0><s5>30</s5></fC03><fC03 i1="20" i2="3" l="ENG"><s0>Exchange interactions</s0><s5>30</s5></fC03><fC03 i1="21" i2="3" l="FRE"><s0>Cu2S</s0><s4>INC</s4><s5>46</s5></fC03><fC03 i1="22" i2="3" l="FRE"><s0>6166</s0><s4>INC</s4><s5>71</s5></fC03><fC03 i1="23" i2="3" l="FRE"><s0>8110</s0><s4>INC</s4><s5>72</s5></fC03><fC03 i1="24" i2="3" l="FRE"><s0>6540D</s0><s4>INC</s4><s5>73</s5></fC03><fC03 i1="25" i2="3" l="FRE"><s0>6166H</s0><s4>INC</s4><s5>74</s5></fC03><fN21><s1>222</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist><affiliations><list><country><li>Australie</li><li>France</li><li>Japon</li></country><region><li>Alsace (région administrative)</li><li>Grand Est</li><li>Nouvelle-Galles du Sud</li></region><settlement><li>Strasbourg</li><li>Sydney</li></settlement><orgName><li>Université de Strasbourg</li><li>Université de Sydney</li></orgName></list><tree><country name="Japon"><noRegion><name sortKey="Kumagai, Hitoshi" sort="Kumagai, Hitoshi" uniqKey="Kumagai H" first="Hitoshi" last="Kumagai">Hitoshi Kumagai</name></noRegion><name sortKey="Akita Tanaka, Motoko" sort="Akita Tanaka, Motoko" uniqKey="Akita Tanaka M" first="Motoko" last="Akita-Tanaka">Motoko Akita-Tanaka</name><name sortKey="Inoue, Katsuya" sort="Inoue, Katsuya" uniqKey="Inoue K" first="Katsuya" last="Inoue">Katsuya Inoue</name><name sortKey="Kawata, Satoshi" sort="Kawata, Satoshi" uniqKey="Kawata S" first="Satoshi" last="Kawata">Satoshi Kawata</name></country><country name="Australie"><region name="Nouvelle-Galles du Sud"><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name></region></country><country name="France"><region name="Grand Est"><name sortKey="Kurmoo, Mohamedally" sort="Kurmoo, Mohamedally" uniqKey="Kurmoo M" first="Mohamedally" last="Kurmoo">Mohamedally Kurmoo</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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|texte= Synthesis, Crystal Structures, and Properties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks
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