Stark effect measurements on the NaK molecule
Identifieur interne : 001663 ( PascalFrancis/Checkpoint ); précédent : 001662; suivant : 001664Stark effect measurements on the NaK molecule
Auteurs : A. Gerdes [Allemagne, France] ; O. Dulieu [France] ; H. Knöckel [Allemagne] ; E. Tiemann [Allemagne]Source :
- The European physical journal. D, Atomic, molecular and optical physics : (Print) [ 1434-6060 ] ; 2011.
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- Pascal (Inist)
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Abstract
In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B 1 II and X 1 Σ+ states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B 1 II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].
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<front><div type="abstract" xml:lang="en">In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B <sup>1 </sup>
II<sub> </sub>
and X <sup>1 </sup>
Σ<sup>+</sup>
states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B <sup>1</sup>
II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].</div>
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