AustralieFrV1, PascalFrancis, Curation, bibRecord, 004779

Stark effect measurements on the NaK molecule

Identifieur interne : 004779 ( PascalFrancis/Curation ); précédent : 004778; suivant : 004780

Stark effect measurements on the NaK molecule

Auteurs : A. Gerdes [Allemagne, France] ; O. Dulieu [France] ; H. Knöckel [Allemagne] ; E. Tiemann [Allemagne]

Source :

The European physical journal. D, Atomic, molecular and optical physics : (Print) [ 1434-6060 ] ; 2011.

RBID : Pascal:12-0019048

Descripteurs français

Pascal (Inist)
- Effet Stark, Faisceau moléculaire, Transition vibrationnelle, Dispositif expérimental, Etude théorique, Moment dipolaire électrique, Moment dipolaire, Valeur absolue, Etat fondamental, Molécule diatomique, Composé du potassium, Composé du sodium, NaK, K Na, 3355B, 3315K.

English descriptors

KwdEn :
- Absolute value, Diatomic molecules, Dipole moments, Electric dipole moments, Experimental device, Ground states, Molecular beams, Potassium compounds, Sodium compounds, Stark effect, Theoretical study, Vibrational transition.

Abstract

In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B ¹IIand X ¹Σ⁺ states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B ¹ II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].

A01	`01`	`1`		`@0 1434-6060`
A03		`1`		`@0 Eur. phys. j., D At. mol. opt. phys.`
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A08	`01`	`1`	`ENG`	`@1 Stark effect measurements on the NaK molecule`
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A11	`01`	`1`		`@1 GERDES (A.)`
A11	`02`	`1`		`@1 DULIEU (O.)`
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A12	`01`	`1`		`@1 BIRKL (Gerhard) @9 ed.`
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A12	`03`	`1`		`@1 FREEGARDE (Tim) @9 ed.`
A12	`04`	`1`		`@1 GRIMM (Rudolf) @9 ed.`
A12	`05`	`1`		`@1 HUTSON (Jeremy M.) @9 ed.`
A12	`06`	`1`		`@1 WEIDEMÜLLER (Matthias) @9 ed.`
A14	`01`			`@1 Institut für Quantenoptik, Leibniz Universität Hannover, Welfengarten 1 @2 30167 Hannover @3 DEU @Z 1 aut. @Z 3 aut. @Z 4 aut.`
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A15	`01`			`@1 University of Darmstad @3 DEU @Z 1 aut.`
A15	`02`			`@1 University of Oxford @3 GBR @Z 2 aut.`
A15	`03`			`@1 University of Southampton @3 GBR @Z 3 aut.`
A15	`04`			`@1 University of Innsbruck @3 AUS @Z 4 aut.`
A15	`05`			`@1 University of Durham @3 GBR @Z 5 aut.`
A15	`06`			`@1 University of Heidelberg @3 DEU @Z 6 aut.`
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A21				`@1 2011`
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A44				`@0 0000 @1 © 2012 INIST-CNRS. All rights reserved.`
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A47	`01`	`1`		`@0 12-0019048`
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A64	`01`	`1`		`@0 The European physical journal. D, Atomic, molecular and optical physics : (Print)`
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C01	`01`		`ENG`	@0 In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B ¹IIand X ¹Σ⁺ states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B ¹ II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].
C02	`01`	`3`		`@0 001B30C55B`
C02	`02`	`3`		`@0 001B30C15K`
C03	`01`	`3`	`FRE`	`@0 Effet Stark @5 03`
C03	`01`	`3`	`ENG`	`@0 Stark effect @5 03`
C03	`02`	`3`	`FRE`	`@0 Faisceau moléculaire @5 04`
C03	`02`	`3`	`ENG`	`@0 Molecular beams @5 04`
C03	`03`	`X`	`FRE`	`@0 Transition vibrationnelle @5 05`
C03	`03`	`X`	`ENG`	`@0 Vibrational transition @5 05`
C03	`03`	`X`	`SPA`	`@0 Transición vibracional @5 05`
C03	`04`	`X`	`FRE`	`@0 Dispositif expérimental @5 11`
C03	`04`	`X`	`ENG`	`@0 Experimental device @5 11`
C03	`04`	`X`	`SPA`	`@0 Dispositivo experimental @5 11`
C03	`05`	`3`	`FRE`	`@0 Etude théorique @5 21`
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C03	`06`	`3`	`FRE`	`@0 Moment dipolaire électrique @5 41`
C03	`06`	`3`	`ENG`	`@0 Electric dipole moments @5 41`
C03	`07`	`3`	`FRE`	`@0 Moment dipolaire @5 42`
C03	`07`	`3`	`ENG`	`@0 Dipole moments @5 42`
C03	`08`	`X`	`FRE`	`@0 Valeur absolue @5 43`
C03	`08`	`X`	`ENG`	`@0 Absolute value @5 43`
C03	`08`	`X`	`SPA`	`@0 Valor absoluto @5 43`
C03	`09`	`3`	`FRE`	`@0 Etat fondamental @5 44`
C03	`09`	`3`	`ENG`	`@0 Ground states @5 44`
C03	`10`	`3`	`FRE`	`@0 Molécule diatomique @5 50`
C03	`10`	`3`	`ENG`	`@0 Diatomic molecules @5 50`
C03	`11`	`3`	`FRE`	`@0 Composé du potassium @5 51`
C03	`11`	`3`	`ENG`	`@0 Potassium compounds @5 51`
C03	`12`	`3`	`FRE`	`@0 Composé du sodium @5 52`
C03	`12`	`3`	`ENG`	`@0 Sodium compounds @5 52`
C03	`13`	`3`	`FRE`	`@0 NaK @4 INC @5 71`
C03	`14`	`3`	`FRE`	`@0 K Na @4 INC @5 75`
C03	`15`	`3`	`FRE`	`@0 3355B @4 INC @5 83`
C03	`16`	`3`	`FRE`	`@0 3315K @4 INC @5 84`
N21				`@1 002`

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Le document en format XML

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<term>Molecular beams</term>
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<term>Moment dipolaire</term>
<term>Valeur absolue</term>
<term>Etat fondamental</term>
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<term>Composé du potassium</term>
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<front><div type="abstract" xml:lang="en">In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B <sup>1 </sup>
II<sub> </sub>
and X <sup>1 </sup>
Σ<sup>+</sup>
 states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B <sup>1</sup>
 II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].</div>
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<fA08 i1="01" i2="1" l="ENG"><s1>Stark effect measurements on the NaK molecule</s1>
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<sZ>1 aut.</sZ>
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<fA15 i1="01"><s1>University of Darmstad</s1>
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<fA15 i1="02"><s1>University of Oxford</s1>
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<fA15 i1="06"><s1>University of Heidelberg</s1>
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<fA20><s1>105-111</s1>
</fA20>
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</fA64>
<fA66 i1="01"><s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>In a newly built molecular beam apparatus we have measured permanent electric dipole moments of the B <sup>1 </sup>
II<sub> </sub>
and X <sup>1 </sup>
Σ<sup>+</sup>
 states of NaK to test the vibrational dependence of the dipole moment function as predicted by ab initio calculations by Aymar and Dulieu [J. Chem. Phys. 122, 204302 (2005)]. Four vibrational bands were studied, the dipole moment for the B <sup>1</sup>
 II decreases from 2.73(2) D for v = 3 to 1.99(2) D for v = 13. The vibrational dependence shows a fairly good agreement with theory, but the absolute values are lower than those from the calculation by 13%. The ground state dipole moment of 2.72(6) confirms the earlier result by Wormsbecher et al. [J. Chem. Phys. 74, 6983 (1981)].</s0>
</fC01>
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<s5>03</s5>
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<s5>03</s5>
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<fC03 i1="02" i2="3" l="FRE"><s0>Faisceau moléculaire</s0>
<s5>04</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Molecular beams</s0>
<s5>04</s5>
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<s5>05</s5>
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<s5>11</s5>
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<s5>11</s5>
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<s5>21</s5>
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<s5>41</s5>
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<fC03 i1="06" i2="3" l="ENG"><s0>Electric dipole moments</s0>
<s5>41</s5>
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<fC03 i1="07" i2="3" l="FRE"><s0>Moment dipolaire</s0>
<s5>42</s5>
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<fC03 i1="08" i2="X" l="FRE"><s0>Valeur absolue</s0>
<s5>43</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Absolute value</s0>
<s5>43</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Valor absoluto</s0>
<s5>43</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Etat fondamental</s0>
<s5>44</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Ground states</s0>
<s5>44</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Molécule diatomique</s0>
<s5>50</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Diatomic molecules</s0>
<s5>50</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Composé du potassium</s0>
<s5>51</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Potassium compounds</s0>
<s5>51</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Composé du sodium</s0>
<s5>52</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Sodium compounds</s0>
<s5>52</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>NaK</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>K Na</s0>
<s4>INC</s4>
<s5>75</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>3355B</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>3315K</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fN21><s1>002</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Stark effect measurements on the NaK molecule

Stark effect measurements on the NaK molecule

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