Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions††Electronic supplementary information (ESI) available: Characterisation of materials. CCDC 1038403–1038407. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03114eClick here for additional data file.Click here for additional data file.
Identifieur interne : 004711 ( Ncbi/Merge ); précédent : 004710; suivant : 004712Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions††Electronic supplementary information (ESI) available: Characterisation of materials. CCDC 1038403–1038407. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03114eClick here for additional data file.Click here for additional data file.
Auteurs : Natasha F. Sciortino ; Katrina A. Zenere ; Maggie E. Corrigan ; Gregory J. Halder [États-Unis] ; Guillaume Chastanet [France] ; Jean-François Létard [France] ; Cameron J. Kepert ; Suzanne M. NevilleSource :
- Chemical Science [ 2041-6520 ] ; 2016.
Abstract
A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.
Url:
DOI: 10.1039/c6sc03114e
PubMed: 28451220
PubMed Central: 5297924
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Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. 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CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:aff id="affb"> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</nlm:aff><country xml:lang="fr">États-Unis</country><wicri:regionArea> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author></analytic><series><title level="j">Chemical Science</title><idno type="ISSN">2041-6520</idno><idno type="eISSN">2041-6539</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p><graphic xlink:href="c6sc03114e-ga.jpg" id="ga" position="float" orientation="portrait"></graphic>A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Kahn, O" uniqKey="Kahn O">O. Kahn</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Gutlich, P" uniqKey="Gutlich P">P. 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Gütlich</name></author></analytic></biblStruct></listBibl></div1></back></TEI><double pmid="28451220"><pmc><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Four-step iron(<sc>ii</sc>) spin state cascade driven by antagonistic solid state interactions<xref ref-type="fn" rid="fn1">†</xref><fn id="fn1"><p>†Electronic supplementary information (ESI) available: Characterisation of materials. CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:aff id="affb"> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</nlm:aff><country xml:lang="fr">États-Unis</country><wicri:regionArea> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">28451220</idno><idno type="pmc">5297924</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5297924</idno><idno type="RBID">PMC:5297924</idno><idno type="doi">10.1039/c6sc03114e</idno><date when="2016">2016</date><idno type="wicri:Area/Pmc/Corpus">002377</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">002377</idno><idno type="wicri:Area/Pmc/Curation">002227</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">002227</idno><idno type="wicri:Area/Pmc/Checkpoint">000929</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000929</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Four-step iron(<sc>ii</sc>) spin state cascade driven by antagonistic solid state interactions<xref ref-type="fn" rid="fn1">†</xref><fn id="fn1"><p>†Electronic supplementary information (ESI) available: Characterisation of materials. CCDC <uri xlink:type="simple" xlink:href="http://dx.doi.org/1038403–1038407">1038403–1038407</uri>. For ESI and crystallographic data in CIF or other electronic format see DOI: <uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1039/c6sc03114e">10.1039/c6sc03114e</uri><supplementary-material content-type="local-data" id="S1"><media xlink:href="SC-008-C6SC03114E-s001.pdf"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material><supplementary-material content-type="local-data" id="S2"><media xlink:href="SC-008-C6SC03114E-s002.cif"><caption><p>Click here for additional data file.</p></caption></media></supplementary-material></p></fn></title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A." last="Zenere">Katrina A. Zenere</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E." last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:aff id="affb"> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA</nlm:aff><country xml:lang="fr">États-Unis</country><wicri:regionArea> X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:aff id="affc"> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France</nlm:aff><country xml:lang="fr">France</country><wicri:regionArea> CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M." last="Neville">Suzanne M. Neville</name><affiliation><nlm:aff id="affa"> School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email:<email>suzanne.neville@sydney.edu.au</email> ; Tel: +61-2-9351-7791</nlm:aff></affiliation></author></analytic><series><title level="j">Chemical Science</title><idno type="ISSN">2041-6520</idno><idno type="eISSN">2041-6539</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p><graphic xlink:href="c6sc03114e-ga.jpg" id="ga" position="float" orientation="portrait"></graphic>A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Kahn, O" uniqKey="Kahn O">O. Kahn</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Gutlich, P" uniqKey="Gutlich P">P. 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Gütlich</name></author></analytic></biblStruct></listBibl></div1></back></TEI></pmc><pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions.</title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F" last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A" last="Zenere">Katrina A. Zenere</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E" last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J" last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:affiliation>X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:affiliation>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:affiliation>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J" last="Kepert">Cameron J. Kepert</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M" last="Neville">Suzanne M. Neville</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2017">2017</date><idno type="RBID">pubmed:28451220</idno><idno type="pmid">28451220</idno><idno type="doi">10.1039/c6sc03114e</idno><idno type="wicri:Area/PubMed/Corpus">001302</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001302</idno><idno type="wicri:Area/PubMed/Curation">001284</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001284</idno><idno type="wicri:Area/PubMed/Checkpoint">001284</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001284</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions.</title><author><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F" last="Sciortino">Natasha F. Sciortino</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Zenere, Katrina A" sort="Zenere, Katrina A" uniqKey="Zenere K" first="Katrina A" last="Zenere">Katrina A. Zenere</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Corrigan, Maggie E" sort="Corrigan, Maggie E" uniqKey="Corrigan M" first="Maggie E" last="Corrigan">Maggie E. Corrigan</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J" last="Halder">Gregory J. Halder</name><affiliation wicri:level="2"><nlm:affiliation>X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 , USA.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>X-ray Science Division , Advanced Photon Source , Argonne National Laboratory , IL 60439 </wicri:regionArea><placeName><region type="state">Illinois</region></placeName></affiliation></author><author><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name><affiliation wicri:level="3"><nlm:affiliation>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Letard, Jean Francois" sort="Letard, Jean Francois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name><affiliation wicri:level="3"><nlm:affiliation>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac , France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>CNRS , Univ. Bordeaux , ICMCB , UPR 9048 , F-33600 , Pessac </wicri:regionArea><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">, Pessac </settlement></placeName></affiliation></author><author><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J" last="Kepert">Cameron J. Kepert</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author><author><name sortKey="Neville, Suzanne M" sort="Neville, Suzanne M" uniqKey="Neville S" first="Suzanne M" last="Neville">Suzanne M. Neville</name><affiliation><nlm:affiliation>School of Chemistry , The University of Sydney , NSW 2006 , Australia . Email: suzanne.neville@sydney.edu.au ; Tel: +61-2-9351-7791.</nlm:affiliation><wicri:noCountry code="subField">Australia </wicri:noCountry></affiliation></author></analytic><series><title level="j">Chemical science</title><idno type="ISSN">2041-6520</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A four-stepped cascade of Fe(ii) high spin (HS) to low spin (LS) states is demonstrated in a family of 2-D Hofmann materials, [Fe3(II)(saltrz)6(M(II)(CN)4)3]·8(H2O) (M(II) = Pd (1(Pd) ), Pt (1(Pt) ); saltrz = (E)-2-(((4H-1,2,4-triazol-4-yl)imino)methyl)phenol). Alongside the fully HS and LS Fe(ii) states, fractional spin state stabilization occurs at HS/LS values of 5/6, 2/3, and 1/6. This unconventional spin state periodicity is driven by the presence of multiple spin crossover (SCO) active Fe(ii) sites which are in subtly distinct environments driven by a network of antagonistic host-host and host-guest interactions. Alternating long- and short-range magnetostructural ordering is achieved over the five distinct spin state ratios HS(1.0)LS(0.0), HS(0.833)LS(0.167), HS(0.667)LS(0.333), HS(0.167)LS(0.833), and HS(0.0)LS(1.0) owing to the flexibility of this 2-D interdigitated lattice topology interconnected by intermolecular interactions. A distinct wave-like spin state patterning is structurally evidenced for each intermediate phase.</div></front></TEI></pubmed></double></record>Pour manipuler ce document sous Unix (Dilib)
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|texte= Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions††Electronic supplementary information (ESI) available: Characterisation of materials. CCDC 1038403–1038407. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03114eClick here for additional data file.Click here for additional data file.
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