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Synthesis and Spectroscopic Characterization of Diphenylargentate, [(C6H5)2Ag](.).

Identifieur interne : 002953 ( Ncbi/Checkpoint ); précédent : 002952; suivant : 002954

Synthesis and Spectroscopic Characterization of Diphenylargentate, [(C6H5)2Ag](.).

Auteurs : M I S. Röhr [Allemagne] ; J. Petersen [Allemagne] ; C. Brunet [France] ; R. Antoine [France] ; M. Broyer [France] ; P. Dugourd [France] ; V. Bona I Kouteck [Allemagne] ; R A J. O'Hair [Australie] ; R. Mitri [Allemagne]

Source :

The journal of physical chemistry letters [ 1948-7185 ] ; 2012.

RBID : pubmed:26288055

Abstract

We present the structural and optical properties of the isolated diphenylargentate anion, which has been synthesized by multistage mass spectrometry in a quadrupole ion trap. The experimental photodetachment spectrum has been obtained by action spectroscopy. Comparison with quantum chemical calculations of the electronic absorption spectrum allows for a precise characterization of the spectroscopic features, showing that in the low-energy regime, the optical properties of diphenylargentate bear a significant resemblance to those of atomic silver.

DOI: 10.1021/jz300280f
PubMed: 26288055

Affiliations:

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<front><div type="abstract" xml:lang="en">We present the structural and optical properties of the isolated diphenylargentate anion, which has been synthesized by multistage mass spectrometry in a quadrupole ion trap. The experimental photodetachment spectrum has been obtained by action spectroscopy. Comparison with quantum chemical calculations of the electronic absorption spectrum allows for a precise characterization of the spectroscopic features, showing that in the low-energy regime, the optical properties of diphenylargentate bear a significant resemblance to those of atomic silver.</div>
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Synthesis and Spectroscopic Characterization of Diphenylargentate, [(C6H5)2Ag](.).

Synthesis and Spectroscopic Characterization of Diphenylargentate, [(C6H5)2Ag](.).

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Abstract

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