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Fluorinated‐plasma modification of polyetherimide films

Identifieur interne : 009989 ( Main/Exploration ); précédent : 009988; suivant : 009990

Fluorinated‐plasma modification of polyetherimide films

Auteurs : Meriyam Kaba [Maroc, France] ; Azzouz Essamri [Maroc] ; Andre Mas [France] ; Francois Schue [France] ; G. A. George [Australie] ; F. Cardona [Australie] ; L. Rintoul [Australie] ; B. J. Wood [Australie]

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RBID : ISTEX:E548F11055727CE2B8B2F6828C3B5B051EC5A6F8

Descripteurs français

English descriptors

Abstract

Ultem 1000 polyetherimide films prepared by cast‐evaporating technique were covered with a 1H,1H,2H‐tridecafluoro‐oct‐1‐ene (PFO) plasma‐polymerized layer. The effects of the plasma exposure time on the surface composition were studied by X‐ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and surface energy analysis. The surface topography of the plasma layer was deduced from scanning electron microscopy. The F/C ratio for plasma‐polymerized PFO under the input RF power of 50 W can be as high as 1.30 for 480 s and ∼0.4–2 at % of oxygen was detected, resulting from the reaction of long‐lived radicals in the plasma polymer with atmospheric oxygen. The plasma deposition of fluorocarbon coating from plasma PFO reduces the surface energy from 46 to 18.3 mJ m−2. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3579–3588, 2006

Url:
DOI: 10.1002/app.22930


Affiliations:


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Le document en format XML

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<div type="abstract" xml:lang="en">Ultem 1000 polyetherimide films prepared by cast‐evaporating technique were covered with a 1H,1H,2H‐tridecafluoro‐oct‐1‐ene (PFO) plasma‐polymerized layer. The effects of the plasma exposure time on the surface composition were studied by X‐ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and surface energy analysis. The surface topography of the plasma layer was deduced from scanning electron microscopy. The F/C ratio for plasma‐polymerized PFO under the input RF power of 50 W can be as high as 1.30 for 480 s and ∼0.4–2 at % of oxygen was detected, resulting from the reaction of long‐lived radicals in the plasma polymer with atmospheric oxygen. The plasma deposition of fluorocarbon coating from plasma PFO reduces the surface energy from 46 to 18.3 mJ m−2. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3579–3588, 2006</div>
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