AustralieFrV1, Istex, Curation, bibRecord, 001E57

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Identifieur interne : 001E57 ( Istex/Curation ); précédent : 001E56; suivant : 001E58

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Auteurs : Michael I. Bruce [Australie] ; Damien Joly [Australie, France] ; Brian W. Skelton [Australie] ; Allan H. White [Australie]

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2011-05.

RBID : ISTEX:A17A68568A3E2A566BA725AA9D8365715A3979F5

English descriptors

KwdEn :
- Acta crystallogr, Cation, Chem, Data centre, Hydrogen atoms, Ligand, Molecular structure, Short communication, Structural study, Structure determination, Verlag gmbh, Zinc chloride.
Teeft :
- Acta crystallogr, Cation, Chem, Data centre, Hydrogen atoms, Ligand, Molecular structure, Short communication, Structural study, Structure determination, Verlag gmbh, Zinc chloride.

Abstract

The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2. (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).

Url:

https://api.istex.fr/document/A17A68568A3E2A566BA725AA9D8365715A3979F5/fulltext/pdf

DOI: 10.1002/zaac.201000447

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ISTEX:A17A68568A3E2A566BA725AA9D8365715A3979F5

Le document en format XML

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<affiliation wicri:level="1"><mods:affiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France</mods:affiliation>
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<front><div type="abstract" xml:lang="en">The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2.  (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).</div>
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Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4

Source :

English descriptors

Abstract

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