Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4
Identifieur interne : 001E57 ( Istex/Corpus ); précédent : 001E56; suivant : 001E58Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4
Auteurs : Michael I. Bruce ; Damien Joly ; Brian W. Skelton ; Allan H. WhiteSource :
- ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2011-05.
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Abstract
The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2. (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).
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DOI: 10.1002/zaac.201000447
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ISTEX:A17A68568A3E2A566BA725AA9D8365715A3979F5Le document en format XML
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Bruce</name><affiliation><mods:affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: michael.bruce@adelaide.edu.au</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia, Fax: + 61‐8‐8303‐4358</mods:affiliation></affiliation></author><author><name sortKey="Joly, Damien" sort="Joly, Damien" uniqKey="Joly D" first="Damien" last="Joly">Damien Joly</name><affiliation><mods:affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</mods:affiliation></affiliation><affiliation><mods:affiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. 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Bruce</name><affiliation><mods:affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: michael.bruce@adelaide.edu.au</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia, Fax: + 61‐8‐8303‐4358</mods:affiliation></affiliation></author><author><name sortKey="Joly, Damien" sort="Joly, Damien" uniqKey="Joly D" first="Damien" last="Joly">Damien Joly</name><affiliation><mods:affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</mods:affiliation></affiliation><affiliation><mods:affiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France</mods:affiliation></affiliation></author><author><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name><affiliation><mods:affiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia</mods:affiliation></affiliation></author><author><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. 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(2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).</div> </front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>cation</json:string><json:string>chem</json:string><json:string>molecular structure</json:string><json:string>structural study</json:string><json:string>zinc chloride</json:string><json:string>structure determination</json:string><json:string>data centre</json:string><json:string>short communication</json:string><json:string>verlag gmbh</json:string><json:string>hydrogen atoms</json:string><json:string>acta crystallogr</json:string><json:string>ligand</json:string></teeft></keywords><author><json:item><name>Prof. Dr. Michael I. 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KGaA, Weinheim</licence></availability><date type="published" when="2011-05"></date></publicationStmt><notesStmt><note type="content-type" subtype="book-reviews" source="bookReview" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-PBH5VBM9-4">book-reviews</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="book-reviews"><analytic><title level="a" type="main" xml:lang="en">Pentamethylcyclopentadienyl(η<hi rend="superscript">6</hi>‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η<hi rend="superscript">6</hi>‐C<hi rend="subscript">8</hi>H<hi rend="subscript">10</hi>)]<hi rend="subscript">2</hi>ZnCl<hi rend="subscript">4</hi></title><title level="a" type="short" xml:lang="en">[RuCp*(η6‐C8H10)]2ZnCl4</title><author xml:id="author-0000" role="corresp"><persName><addName>Prof. Dr.</addName><forename type="first">Michael I.</forename><surname>Bruce</surname></persName><email>michael.bruce@adelaide.edu.au</email><affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia<address><country key="AU"></country></address></affiliation><affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia, Fax: + 61‐8‐8303‐4358</affiliation></author><author xml:id="author-0001"><persName><forename type="first">Damien</forename><surname>Joly</surname></persName><affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia<address><country key="AU"></country></address></affiliation><affiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Brian W.</forename><surname>Skelton</surname></persName><affiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Allan H.</forename><surname>White</surname></persName><affiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia<address><country key="AU"></country></address></affiliation></author><idno type="istex">A17A68568A3E2A566BA725AA9D8365715A3979F5</idno><idno type="ark">ark:/67375/WNG-930Q3CZ9-R</idno><idno type="DOI">10.1002/zaac.201000447</idno><idno type="unit">ZAAC201000447</idno><idno type="toTypesetVersion">file:ZAAC.ZAAC201000447.pdf</idno></analytic><monogr><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="pISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><idno type="book-DOI">10.1002/(ISSN)1521-3749</idno><idno type="book-part-DOI">10.1002/zaac.v637.6</idno><idno type="product">ZAAC</idno><imprint><biblScope unit="vol">637</biblScope><biblScope unit="issue">6</biblScope><biblScope unit="page" from="641">641</biblScope><biblScope unit="page" to="642">642</biblScope><biblScope unit="page-count">2</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2011-05"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η<hi rend="superscript">6</hi>‐C<hi rend="subscript">8</hi>‐ring)]<hi rend="superscript">+</hi>, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl<hi rend="subscript">2</hi>. (2.21 Å) is appreciably longer than in RuCp*<hi rend="subscript">2</hi> (2.18 Å) and similar to the value for the Ru‐η<hi rend="superscript">6</hi> component (2.22 Å).</p> </abstract><abstract xml:lang="en" style="graphical"><p><figure type="box"><media mimeType="image" url="urn:x-wiley:00442313:media:ZAAC201000447:content"></media><media mimeType="image/gif" url="" rendition="webLoRes"></media><media mimeType="image/gif" url="" rendition="webOriginal"></media><media mimeType="image/gif" url="" rendition="webHiRes"></media></figure></p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">Ruthenium</term><term xml:id="kwd2">Cyclopentadienyl</term><term xml:id="kwd3">Cyclooctatrienyl</term><term xml:id="kwd4">Zinc</term></keywords><keywords rend="articleCategory"><term>Short Communication</term></keywords><keywords rend="tocHeading1"><term>Short Communications</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/A17A68568A3E2A566BA725AA9D8365715A3979F5/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3749</doi><issn type="print">0044-2313</issn><issn type="electronic">1521-3749</issn><idGroup><id type="product" value="ZAAC"></id></idGroup><titleGroup><title type="main" xml:lang="en">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="tocForm">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="short">Z. anorg. allg. Chem.</title></titleGroup></publicationMeta><publicationMeta level="part" position="60"><doi origin="wiley" registered="yes">10.1002/zaac.v637.6</doi><numberingGroup><numbering type="journalVolume" number="637">637</numbering><numbering type="journalIssue">6</numbering></numberingGroup><coverDate startDate="2011-05">May 2011</coverDate></publicationMeta><publicationMeta level="unit" type="bookReview" position="4" status="forIssue"><doi origin="wiley" registered="yes">10.1002/zaac.201000447</doi><idGroup><id type="unit" value="ZAAC201000447"></id></idGroup><countGroup><count type="pageTotal" number="2"></count></countGroup><titleGroup><title type="articleCategory">Short Communication</title><title type="tocHeading1">Short Communications</title></titleGroup><copyright ownership="publisher">Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2010-12-21"></event><event type="manuscriptAccepted" date="2011-03-25"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.5.2 mode:FullText" date="2011-06-28"></event><event type="publishedOnlineEarlyUnpaginated" date="2011-03-25"></event><event type="publishedOnlineFinalForm" date="2011-05-19"></event><event type="firstOnline" date="2011-03-25"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-10"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-11-04"></event></eventGroup><numberingGroup><numbering type="pageFirst">641</numbering><numbering type="pageLast">642</numbering></numberingGroup><correspondenceTo>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia, Fax: + 61‐8‐8303‐4358</correspondenceTo><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:ZAAC.ZAAC201000447.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="1"></count><count type="tableTotal" number="0"></count><count type="referenceTotal" number="6"></count></countGroup><titleGroup><title type="main" xml:lang="en">Pentamethylcyclopentadienyl(η<sup>6</sup>‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η<sup>6</sup>‐C<sub>8</sub>H<sub>10</sub>)]<sub>2</sub>ZnCl<sub>4</sub></title><title type="short" xml:lang="en">[RuCp*(η<sup>6</sup>‐C<sub>8</sub>H<sub>10</sub>)]<sub>2</sub>ZnCl<sub>4</sub></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><honorifics>Prof. Dr.</honorifics><givenNames>Michael I.</givenNames><familyName>Bruce</familyName></personName><contactDetails><email>michael.bruce@adelaide.edu.au</email></contactDetails></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1 #af2"><personName><givenNames>Damien</givenNames><familyName>Joly</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Brian W.</givenNames><familyName>Skelton</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Allan H.</givenNames><familyName>White</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="AU" type="organization"><unparsedAffiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France</unparsedAffiliation></affiliation><affiliation xml:id="af3" countryCode="AU" type="organization"><unparsedAffiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Ruthenium</keyword><keyword xml:id="kwd2">Cyclopentadienyl</keyword><keyword xml:id="kwd3">Cyclooctatrienyl</keyword><keyword xml:id="kwd4">Zinc</keyword></keywordGroup><fundingInfo><fundingAgency>Australian Research Council</fundingAgency></fundingInfo><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η<sup>6</sup>‐C<sub>8</sub>‐ring)]<sup>+</sup>, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl<sub>2</sub>. (2.21 Å) is appreciably longer than in RuCp*<sub>2</sub> (2.18 Å) and similar to the value for the Ru‐η<sup>6</sup> component (2.22 Å).</p> </abstract><abstract type="graphical" xml:lang="en"><p><blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:00442313:media:ZAAC201000447:content"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>[RuCp*(η6‐C8H10)]2ZnCl4</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Pentamethylcyclopentadienyl(η6‐cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6‐C8H10)]2ZnCl4</title></titleInfo><name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart><namePart type="given">Michael I.</namePart><namePart type="family">Bruce</namePart><affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</affiliation><affiliation>E-mail: michael.bruce@adelaide.edu.au</affiliation><affiliation>Correspondence address: School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia, Fax: + 61‐8‐8303‐4358</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Damien</namePart><namePart type="family">Joly</namePart><affiliation>School of Chemistry and Physics, University of Adelaide, Adelaide, South Australia 5005, Australia</affiliation><affiliation>UMR 6509 CNRS, Institut de Chimie, Université de Rennes 1, 35042 Rennes Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Brian W.</namePart><namePart type="family">Skelton</namePart><affiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Allan H.</namePart><namePart type="family">White</namePart><affiliation>Chemistry M313, SBBCS, University of Western Australia, Crawley, Western Australia 6009, Australia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="book-reviews" displayLabel="bookReview" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-PBH5VBM9-4">book-reviews</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2011-05</dateIssued><dateCaptured encoding="w3cdtf">2010-12-21</dateCaptured><dateValid encoding="w3cdtf">2011-03-25</dateValid><copyrightDate encoding="w3cdtf">2011</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">1</extent><extent unit="tables">0</extent><extent unit="references">6</extent></physicalDescription><abstract lang="en">The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6‐C8‐ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1‐ferrocenylbuta‐1,3‐diyne in the presence of ZnCl2. (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru‐η6 component (2.22 Å).</abstract> <abstract type="graphical" lang="en"></abstract><note type="funding">Australian Research Council</note><subject lang="en"><genre>keywords</genre><topic>Ruthenium</topic><topic>Cyclopentadienyl</topic><topic>Cyclooctatrienyl</topic><topic>Zinc</topic></subject><relatedItem type="host"><titleInfo><title>ZAAC ‐ Journal of Inorganic and General Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Z. anorg. allg. Chem.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Short Communication</topic></subject><identifier type="ISSN">0044-2313</identifier><identifier type="eISSN">1521-3749</identifier><identifier type="DOI">10.1002/(ISSN)1521-3749</identifier><identifier type="PublisherID">ZAAC</identifier><part><date>2011</date><detail type="volume"><caption>vol.</caption><number>637</number></detail><detail type="issue"><caption>no.</caption><number>6</number></detail><extent unit="pages"><start>641</start><end>642</end><total>2</total></extent></part></relatedItem><identifier type="istex">A17A68568A3E2A566BA725AA9D8365715A3979F5</identifier><identifier type="ark">ark:/67375/WNG-930Q3CZ9-R</identifier><identifier type="DOI">10.1002/zaac.201000447</identifier><identifier type="ArticleID">ZAAC201000447</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. 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