Supra‐Aggregation: Microphase Formation in Complex Fluids
Identifieur interne : 002817 ( Istex/Corpus ); précédent : 002816; suivant : 002818Supra‐Aggregation: Microphase Formation in Complex Fluids
Auteurs : P. André ; A. Filankembo ; I. Lisiecki ; C. Petit ; T. Gulik-Krzywicki ; B. W. Ninham ; M. PileniSource :
- Advanced Materials [ 0935-9648 ] ; 2000-01.
English descriptors
- KwdEn :
- Appl, Aqueous solution, Birefringent, Birefringent phase, Bragg peak, Chemical synthesis, Complex fluids, Cylinder phase, Experimental section, Ffem, Ffem pattern, Ffem patterns, Final version, Full curve, Hgte, Hgte nanocrystals, Isotropic, Isotropic phase, Lamellar, Lamellar phase, Lamellar spacing, Lett, Lower phase, Mater, Nanocrystals, Overall water content, Phase diagram, Phys, Spherulites, Surfactant, Surfactant head group area, Surfactant molecules, Surfactant volume fractions, Upper phase, Various water contents, Verlag gmbh, Volume fraction, Volume fractions, Water concentrations, Water content, Water volume fraction, Whole system.
- Teeft :
- Appl, Aqueous solution, Birefringent, Birefringent phase, Bragg peak, Chemical synthesis, Complex fluids, Cylinder phase, Experimental section, Ffem, Ffem pattern, Ffem patterns, Final version, Full curve, Hgte, Hgte nanocrystals, Isotropic, Isotropic phase, Lamellar, Lamellar phase, Lamellar spacing, Lett, Lower phase, Mater, Nanocrystals, Overall water content, Phase diagram, Phys, Spherulites, Surfactant, Surfactant head group area, Surfactant molecules, Surfactant volume fractions, Upper phase, Various water contents, Verlag gmbh, Volume fraction, Volume fractions, Water concentrations, Water content, Water volume fraction, Whole system.
Abstract
Emulsions are not necessarily thermodynamically unstable. Here it is shown that thermodynamically stable states of self‐assembled supra‐aggregates exist, and that the component ratios and microstructures that form can be predicted quantitatively from elementary arguments. The Figure is a freeze fracture image of one of the phases that forms when copper(II) bis(2‐ethylhexyl)sulfosuccinate is mixed with isooctane and water.
Url:
DOI: 10.1002/(SICI)1521-4095(200001)12:2<119::AID-ADMA119>3.0.CO;2-Y
Links to Exploration step
ISTEX:D718625A4CE884EBA47CBF1BAA0651FDC91BF3EELe document en format XML
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Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</mods:affiliation></affiliation><affiliation><mods:affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</mods:affiliation></affiliation></author><author><name sortKey="Filankembo, A" sort="Filankembo, A" uniqKey="Filankembo A" first="A." last="Filankembo">A. Filankembo</name><affiliation><mods:affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</mods:affiliation></affiliation></author><author><name sortKey="Lisiecki, I" sort="Lisiecki, I" uniqKey="Lisiecki I" first="I." last="Lisiecki">I. Lisiecki</name><affiliation><mods:affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</mods:affiliation></affiliation><affiliation><mods:affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</mods:affiliation></affiliation></author><author><name sortKey="Petit, C" sort="Petit, C" uniqKey="Petit C" first="C." last="Petit">C. Petit</name><affiliation><mods:affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</mods:affiliation></affiliation><affiliation><mods:affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</mods:affiliation></affiliation></author><author><name sortKey="Gulik Rzywicki, T" sort="Gulik Rzywicki, T" uniqKey="Gulik Rzywicki T" first="T." last="Gulik-Krzywicki">T. Gulik-Krzywicki</name><affiliation><mods:affiliation>Centre de Génétique Moléculaire‐C.N.R.S., F‐91190 Gif‐sur‐Yvette, Cedex (France)</mods:affiliation></affiliation></author><author><name sortKey="Ninham, B W" sort="Ninham, B W" uniqKey="Ninham B" first="B. W." last="Ninham">B. W. Ninham</name><affiliation><mods:affiliation>Department of Applied Mathematics, P.O. Box 4, Canberra, ACT 0200 (Australia)</mods:affiliation></affiliation><affiliation><mods:affiliation>Physical Chemistry I, P.O. Box 124, University of Lund, Lund, SE 22100 (Sweden)</mods:affiliation></affiliation></author><author><name sortKey="Pileni, M" sort="Pileni, M" uniqKey="Pileni M" first="M." last="Pileni">M. Pileni</name><affiliation><mods:affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</mods:affiliation></affiliation><affiliation><mods:affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Advanced Materials</title><title level="j" type="alt">ADVANCED MATERIALS</title><idno type="ISSN">0935-9648</idno><idno type="eISSN">1521-4095</idno><imprint><biblScope unit="vol">12</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="119">119</biblScope><biblScope unit="page" to="123">123</biblScope><biblScope unit="page-count">5</biblScope><publisher>WILEY‐VCH Verlag GmbH</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2000-01">2000-01</date></imprint><idno type="ISSN">0935-9648</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0935-9648</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Appl</term><term>Aqueous solution</term><term>Birefringent</term><term>Birefringent phase</term><term>Bragg peak</term><term>Chemical synthesis</term><term>Complex fluids</term><term>Cylinder phase</term><term>Experimental section</term><term>Ffem</term><term>Ffem pattern</term><term>Ffem patterns</term><term>Final version</term><term>Full curve</term><term>Hgte</term><term>Hgte nanocrystals</term><term>Isotropic</term><term>Isotropic phase</term><term>Lamellar</term><term>Lamellar phase</term><term>Lamellar spacing</term><term>Lett</term><term>Lower phase</term><term>Mater</term><term>Nanocrystals</term><term>Overall water content</term><term>Phase diagram</term><term>Phys</term><term>Spherulites</term><term>Surfactant</term><term>Surfactant head group area</term><term>Surfactant molecules</term><term>Surfactant volume fractions</term><term>Upper phase</term><term>Various water contents</term><term>Verlag gmbh</term><term>Volume fraction</term><term>Volume fractions</term><term>Water concentrations</term><term>Water content</term><term>Water volume fraction</term><term>Whole system</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Appl</term><term>Aqueous solution</term><term>Birefringent</term><term>Birefringent phase</term><term>Bragg peak</term><term>Chemical synthesis</term><term>Complex fluids</term><term>Cylinder phase</term><term>Experimental section</term><term>Ffem</term><term>Ffem pattern</term><term>Ffem patterns</term><term>Final version</term><term>Full curve</term><term>Hgte</term><term>Hgte nanocrystals</term><term>Isotropic</term><term>Isotropic phase</term><term>Lamellar</term><term>Lamellar phase</term><term>Lamellar spacing</term><term>Lett</term><term>Lower phase</term><term>Mater</term><term>Nanocrystals</term><term>Overall water content</term><term>Phase diagram</term><term>Phys</term><term>Spherulites</term><term>Surfactant</term><term>Surfactant head group area</term><term>Surfactant molecules</term><term>Surfactant volume fractions</term><term>Upper phase</term><term>Various water contents</term><term>Verlag gmbh</term><term>Volume fraction</term><term>Volume fractions</term><term>Water concentrations</term><term>Water content</term><term>Water volume fraction</term><term>Whole system</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">Emulsions are not necessarily thermodynamically unstable. Here it is shown that thermodynamically stable states of self‐assembled supra‐aggregates exist, and that the component ratios and microstructures that form can be predicted quantitatively from elementary arguments. The Figure is a freeze fracture image of one of the phases that forms when copper(II) bis(2‐ethylhexyl)sulfosuccinate is mixed with isooctane and water.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>phys</json:string><json:string>spherulites</json:string><json:string>isotropic phase</json:string><json:string>water content</json:string><json:string>nanocrystals</json:string><json:string>surfactant</json:string><json:string>birefringent</json:string><json:string>appl</json:string><json:string>lett</json:string><json:string>hgte</json:string><json:string>volume fraction</json:string><json:string>lamellar</json:string><json:string>ffem</json:string><json:string>water volume fraction</json:string><json:string>ffem pattern</json:string><json:string>surfactant molecules</json:string><json:string>experimental section</json:string><json:string>volume fractions</json:string><json:string>verlag gmbh</json:string><json:string>whole system</json:string><json:string>upper phase</json:string><json:string>hgte nanocrystals</json:string><json:string>various water contents</json:string><json:string>overall water content</json:string><json:string>aqueous solution</json:string><json:string>birefringent phase</json:string><json:string>lamellar phase</json:string><json:string>cylinder phase</json:string><json:string>isotropic</json:string><json:string>surfactant volume fractions</json:string><json:string>full curve</json:string><json:string>bragg peak</json:string><json:string>water concentrations</json:string><json:string>lamellar spacing</json:string><json:string>ffem patterns</json:string><json:string>surfactant head group area</json:string><json:string>lower phase</json:string><json:string>chemical synthesis</json:string><json:string>phase diagram</json:string><json:string>complex fluids</json:string><json:string>final version</json:string><json:string>mater</json:string></teeft></keywords><author><json:item><name>P. André</name><affiliations><json:string>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</json:string><json:string>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</json:string></affiliations></json:item><json:item><name>A. Filankembo</name><affiliations><json:string>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</json:string></affiliations></json:item><json:item><name>I. Lisiecki</name><affiliations><json:string>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</json:string><json:string>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</json:string></affiliations></json:item><json:item><name>C. Petit</name><affiliations><json:string>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</json:string><json:string>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</json:string></affiliations></json:item><json:item><name>T. Gulik‐Krzywicki</name><affiliations><json:string>Centre de Génétique Moléculaire‐C.N.R.S., F‐91190 Gif‐sur‐Yvette, Cedex (France)</json:string></affiliations></json:item><json:item><name>B. W. Ninham</name><affiliations><json:string>Department of Applied Mathematics, P.O. Box 4, Canberra, ACT 0200 (Australia)</json:string><json:string>Physical Chemistry I, P.O. Box 124, University of Lund, Lund, SE 22100 (Sweden)</json:string></affiliations></json:item><json:item><name>M.‐P. Pileni</name><affiliations><json:string>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</json:string><json:string>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Complex fluids</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Emulsions</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Microphases</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Supra‐aggregates, self‐assembled</value></json:item></subject><articleId><json:string>ADMA119</json:string></articleId><arkIstex>ark:/67375/WNG-SQZ2DL9G-2</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>Emulsions are not necessarily thermodynamically unstable. Here it is shown that thermodynamically stable states of self‐assembled supra‐aggregates exist, and that the component ratios and microstructures that form can be predicted quantitatively from elementary arguments. The Figure is a freeze fracture image of one of the phases that forms when copper(II) bis(2‐ethylhexyl)sulfosuccinate is mixed with isooctane and water.</abstract><qualityIndicators><score>6.84</score><pdfWordCount>4156</pdfWordCount><pdfCharCount>23986</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>5</pdfPageCount><pdfPageSize>595 x 794 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>57</abstractWordCount><abstractCharCount>425</abstractCharCount><keywordCount>4</keywordCount></qualityIndicators><title>Supra‐Aggregation: Microphase Formation in Complex Fluids</title><genre><json:string>article</json:string></genre><host><title>Advanced Materials</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-4095</json:string></doi><issn><json:string>0935-9648</json:string></issn><eissn><json:string>1521-4095</json:string></eissn><publisherId><json:string>ADMA</json:string></publisherId><volume>12</volume><issue>2</issue><pages><first>119</first><last>123</last><total>5</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Communication</value></json:item></subject></host><namedEntities><unitex><date><json:string>2000</json:string></date><geogName><json:string>Bragg</json:string></geogName><orgName><json:string>Volkswagen Foundation, Hanover, and the Foundation of the Chemical Industry</json:string><json:string>Wet Chemical Synthesis</json:string><json:string>Physikalische Chemie Universität Hamburg Bundesstrasse</json:string><json:string>Physico-Chemical Research Institute, Belarussian State University</json:string><json:string>Universität Hamburg</json:string><json:string>University of Lund Lund</json:string></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName><json:string>J. Appl</json:string><json:string>S. M. Garrison</json:string><json:string>V. M. Orera</json:string><json:string>P. Chaudari</json:string><json:string>R. F. W. Pease</json:string><json:string>Mike T. Harrison</json:string><json:string>T. N. Zemb</json:string><json:string>P. Chaudhari</json:string><json:string>R. C. Bradt</json:string><json:string>J. M. Phillips</json:string><json:string>P. AndrØ</json:string><json:string>K. Char</json:string><json:string>M. P. Pileni</json:string><json:string>R. Hu</json:string><json:string>Pascal AndrØ</json:string><json:string>A. L. Rogach</json:string><json:string>A. Eychmüller</json:string><json:string>H. Weller</json:string><json:string>J. Mater</json:string><json:string>Steve V. Kershaw</json:string><json:string>Paris Cedex</json:string><json:string>J. A. VallØs</json:string><json:string>H. L. Kao</json:string><json:string>M. D. Thouless</json:string><json:string>D. R. Clarke</json:string><json:string>S. V. Kershaw</json:string><json:string>A. Kornowski</json:string><json:string>J. Gellings</json:string><json:string>R. I. Merino</json:string><json:string>Barry W. Ninham</json:string><json:string>T. H. Geballe</json:string><json:string>P.O. Box</json:string><json:string>J. Phys</json:string><json:string>M. Curie</json:string><json:string>J. B. Bulman</json:string><json:string>M. Darula</json:string><json:string>E. Olsson</json:string><json:string>A. Guinier</json:string><json:string>J. I. Pena</json:string><json:string>P. Lindner</json:string><json:string>A. Figueras</json:string><json:string>I. Lisiecki</json:string><json:string>G. Dhalenne</json:string><json:string>J. Tanori</json:string><json:string>D. J. Mitchell</json:string><json:string>J. Chem</json:string><json:string>D. Dhalenne</json:string><json:string>W. J. Minford</json:string><json:string>B. W. Ninham</json:string><json:string>F. K. Le Gones</json:string><json:string>J. P. Cotton</json:string><json:string>B. Boyer</json:string><json:string>A. 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Werder</json:string><json:string>D. F. Evans</json:string><json:string>V. S. Stubican</json:string><json:string>Marie-Paule Pileni</json:string><json:string>C. B. Eom</json:string><json:string>C. H. Chen</json:string><json:string>H. J. A. Koopmans</json:string><json:string>R. W. Barton</json:string><json:string>T. Gulik-Krzywicki</json:string><json:string>W. D. Dozier</json:string><json:string>S. Beuven</json:string><json:string>Y. Suzuki</json:string><json:string>S. Andersson</json:string><json:string>N. Newman</json:string><json:string>Alex Eychmüller</json:string><json:string>Z. Blum</json:string><json:string>M. S. Coclough</json:string><json:string>M. A. Rebolledo</json:string><json:string>P. Pileni</json:string><json:string>J. Ludwig</json:string><json:string>K. P. Daly</json:string><json:string>A. E. Lee</json:string><json:string>Andreas Kornowski</json:string><json:string>R. 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Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">A.</forename><surname>Filankembo</surname></persName><affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. Curie (Paris VI), B.P. 52, 4 Place Jussieu, F‐752 31 Paris Cedex 05 (France)<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">I.</forename><surname>Lisiecki</surname></persName><affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)<address><country key="FR"></country></address></affiliation><affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. 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W.</forename><surname>Ninham</surname></persName><affiliation>Department of Applied Mathematics, P.O. Box 4, Canberra, ACT 0200 (Australia)<address><country key="AU"></country></address></affiliation><affiliation>Physical Chemistry I, P.O. Box 124, University of Lund, Lund, SE 22100 (Sweden)<address><country key="SE"></country></address></affiliation></author><author xml:id="author-0006"><persName><forename type="first">M.‐P.</forename><surname>Pileni</surname></persName><affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)<address><country key="FR"></country></address></affiliation><affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. 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W.</namePart><namePart type="family">Ninham</namePart><affiliation>Department of Applied Mathematics, P.O. Box 4, Canberra, ACT 0200 (Australia)</affiliation><affiliation>Physical Chemistry I, P.O. Box 124, University of Lund, Lund, SE 22100 (Sweden)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.‐P.</namePart><namePart type="family">Pileni</namePart><affiliation>C.E.A.‐C.E.N. Saclay, DRECAM‐S.C.M., F‐91191 Gif‐sur‐Yvette, Cedex (France)</affiliation><affiliation>Laboratoire S.R.S.I., U.R.A. C.N.R.S. 1662, Université P. et M. 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Here it is shown that thermodynamically stable states of self‐assembled supra‐aggregates exist, and that the component ratios and microstructures that form can be predicted quantitatively from elementary arguments. The Figure is a freeze fracture image of one of the phases that forms when copper(II) bis(2‐ethylhexyl)sulfosuccinate is mixed with isooctane and water.</abstract><subject lang="en"><genre>keywords</genre><topic>Complex fluids</topic><topic>Emulsions</topic><topic>Microphases</topic><topic>Supra‐aggregates, self‐assembled</topic></subject><relatedItem type="host"><titleInfo><title>Advanced Materials</title></titleInfo><titleInfo type="abbreviated"><title>Adv. 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