Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions
Identifieur interne : 001047 ( Istex/Corpus ); précédent : 001046; suivant : 001048Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions
Auteurs : Peter Boyd ; Alison Edwards ; Michael Gardiner ; Curtis Ho ; Marie-Hélène Lemée-Cailleau ; David Mcguinness ; Anung Riapanitra ; Jonathan Steed ; Damien Stringer ; Brian YatesSource :
- Angewandte Chemie [ 0044-8249 ] ; 2010-08-23.
English descriptors
- KwdEn :
- Angew, Chem, Current address, Dalton trans, Fluxional behavior, Hydride, Ligand, Mass spectrometry, Meoh, Neutron, Organometallics, Palladium, Prismatic crystals, Qmax rint prisms, Radiation crystal dimensions, Solid state, Space group, Space group aba2, Synchrotron radiation crystal dimensions, Terminal hydride, Terminal hydride ligand, Verlag gmbh, Weinheim angew.
- Teeft :
- Angew, Chem, Current address, Dalton trans, Fluxional behavior, Hydride, Ligand, Mass spectrometry, Meoh, Neutron, Organometallics, Palladium, Prismatic crystals, Qmax rint prisms, Radiation crystal dimensions, Solid state, Space group, Space group aba2, Synchrotron radiation crystal dimensions, Terminal hydride, Terminal hydride ligand, Verlag gmbh, Weinheim angew.
Abstract
Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.
Url:
DOI: 10.1002/ange.201003177
Links to Exploration step
ISTEX:579BB6EAD207C7EF9FE09573152F5A43DD83C20ALe document en format XML
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Dr. Soeparno 61, Purwokerto 53123 (Indonesia)</mods:affiliation></affiliation></author><author><name sortKey="Steed, Jonathan" sort="Steed, Jonathan" uniqKey="Steed J" first="Jonathan" last="Steed">Jonathan Steed</name><affiliation><mods:affiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</mods:affiliation></affiliation></author><author><name sortKey="Stringer, Damien" sort="Stringer, Damien" uniqKey="Stringer D" first="Damien" last="Stringer">Damien Stringer</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation></affiliation></author><author><name sortKey="Yates, Brian" sort="Yates, Brian" uniqKey="Yates B" first="Brian" last="Yates">Brian Yates</name><affiliation><mods:affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie</title><title level="j" type="alt">ANGEWANDTE CHEMIE</title><idno type="ISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><imprint><biblScope unit="vol">122</biblScope><biblScope unit="issue">36</biblScope><biblScope unit="page" from="6459">6459</biblScope><biblScope unit="page" to="6462">6462</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2010-08-23">2010-08-23</date></imprint><idno type="ISSN">0044-8249</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-8249</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Angew</term><term>Chem</term><term>Current address</term><term>Dalton trans</term><term>Fluxional behavior</term><term>Hydride</term><term>Ligand</term><term>Mass spectrometry</term><term>Meoh</term><term>Neutron</term><term>Organometallics</term><term>Palladium</term><term>Prismatic crystals</term><term>Qmax rint prisms</term><term>Radiation crystal dimensions</term><term>Solid state</term><term>Space group</term><term>Space group aba2</term><term>Synchrotron radiation crystal dimensions</term><term>Terminal hydride</term><term>Terminal hydride ligand</term><term>Verlag gmbh</term><term>Weinheim angew</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Angew</term><term>Chem</term><term>Current address</term><term>Dalton trans</term><term>Fluxional behavior</term><term>Hydride</term><term>Ligand</term><term>Mass spectrometry</term><term>Meoh</term><term>Neutron</term><term>Organometallics</term><term>Palladium</term><term>Prismatic crystals</term><term>Qmax rint prisms</term><term>Radiation crystal dimensions</term><term>Solid state</term><term>Space group</term><term>Space group aba2</term><term>Synchrotron radiation crystal dimensions</term><term>Terminal hydride</term><term>Terminal hydride ligand</term><term>Verlag gmbh</term><term>Weinheim angew</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>angew</json:string><json:string>organometallics</json:string><json:string>meoh</json:string><json:string>ligand</json:string><json:string>qmax rint prisms</json:string><json:string>verlag gmbh</json:string><json:string>neutron</json:string><json:string>palladium</json:string><json:string>space group</json:string><json:string>prismatic crystals</json:string><json:string>solid state</json:string><json:string>hydride</json:string><json:string>mass spectrometry</json:string><json:string>weinheim angew</json:string><json:string>terminal hydride</json:string><json:string>current address</json:string><json:string>synchrotron radiation crystal dimensions</json:string><json:string>terminal hydride ligand</json:string><json:string>fluxional behavior</json:string><json:string>space group aba2</json:string><json:string>radiation crystal dimensions</json:string><json:string>dalton trans</json:string></teeft></keywords><author><json:item><name>Peter D. W. Boyd Prof.</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string><json:string>Current address: Department of Chemistry, The University of Auckland, Auckland 1142 (New Zealand)</json:string></affiliations></json:item><json:item><name>Alison J. Edwards Dr.</name><affiliations><json:string>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai NSW 2234 (Australia)</json:string></affiliations></json:item><json:item><name>Michael G. Gardiner Dr.</name><affiliations><json:string>E-mail: michael.gardiner@utas.edu.au</json:string><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string><json:string>E-mail: michael.gardiner@utas.edu.au</json:string></affiliations></json:item><json:item><name>Curtis C. Ho</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string></affiliations></json:item><json:item><name>Marie‐Hélène Lemée‐Cailleau Dr.</name><affiliations><json:string>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)</json:string></affiliations></json:item><json:item><name>David S. McGuinness Dr.</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string></affiliations></json:item><json:item><name>Anung Riapanitra</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string><json:string>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. Dr. Soeparno 61, Purwokerto 53123 (Indonesia)</json:string></affiliations></json:item><json:item><name>Jonathan W. Steed Prof.</name><affiliations><json:string>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</json:string></affiliations></json:item><json:item><name>Damien N. Stringer Dr.</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string></affiliations></json:item><json:item><name>Brian F. Yates Prof.</name><affiliations><json:string>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Homogene Katalyse</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Kupplungsreaktionen</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>N‐heterocyclische Carbene</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Palladium</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Reduktionen</value></json:item></subject><articleId><json:string>ANGE201003177</json:string></articleId><arkIstex>ark:/67375/WNG-VBQRWHQP-T</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>shortCommunication</json:string></originalGenre><abstract>Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.</abstract><qualityIndicators><score>5.793</score><pdfWordCount>3265</pdfWordCount><pdfCharCount>18791</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>4</pdfPageCount><pdfPageSize>595.276 x 841.89 pts (A4)</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>44</abstractWordCount><abstractCharCount>403</abstractCharCount><keywordCount>5</keywordCount></qualityIndicators><title>Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions</title><genre><json:string>brief-communication</json:string></genre><host><title>Angewandte Chemie</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-3757</json:string></doi><issn><json:string>0044-8249</json:string></issn><eissn><json:string>1521-3757</json:string></eissn><publisherId><json:string>ANGE</json:string></publisherId><volume>122</volume><issue>36</issue><pages><first>6459</first><last>6462</last><total>4</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Zuschrift</value></json:item></subject></host><namedEntities><unitex><date><json:string>2010</json:string></date><geogName></geogName><orgName><json:string>Australia Indonesia Partnership for Reconstruction and Development</json:string><json:string>Bragg Institute Australian Nuclear Science and Technology</json:string><json:string>Department of Chemistry, South Road, University of Durham Durham DH</json:string><json:string>Department of Chemistry Universitas Jenderal Soedirman Jl</json:string><json:string>University of Auckland</json:string><json:string>AIPRD</json:string><json:string>Department of Chemistry The University of Auckland Auckland</json:string></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName><json:string>L. 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Mol</json:string><json:string>F. D. Toste</json:string><json:string>M. Basato</json:string><json:string>R. Kempe</json:string><json:string>A. Neels</json:string><json:string>J. Benet-Buchholz</json:string><json:string>D. A. Pantazis</json:string><json:string>T. Scherg</json:string><json:string>S. S. Stahl</json:string><json:string>M. Tromp</json:string><json:string>X. Y. Mak</json:string><json:string>H. Gornitzka</json:string><json:string>R. Vilar</json:string><json:string>E. Herdtweck</json:string><json:string>K. Kulicke</json:string><json:string>E. Peris</json:string><json:string>M. A. L. Geibel</json:string><json:string>G. P. F. van Strijdonck</json:string><json:string>M. Sana</json:string><json:string>S. E. Himmel</json:string><json:string>O. Repic</json:string><json:string>B. K. Shaw</json:string><json:string>D. Q. Wang</json:string><json:string>R. C. Jones</json:string><json:string>G. P. A. Yap</json:string><json:string>J. R. A. Sietsma</json:string><json:string>H. J. Chiu</json:string><json:string>R. J. van Haaren</json:string><json:string>Alison J. Edwards</json:string><json:string>Jonathan W. Steed</json:string><json:string>M. Heckenroth</json:string><json:string>M. A. Taige</json:string><json:string>G. D. Frey</json:string><json:string>H. Kurosawa</json:string><json:string>M. S. Sanford</json:string><json:string>P. W. N. M. van Leeuwen</json:string><json:string>W. J. Youngs</json:string><json:string>Jules Horowitz</json:string><json:string>R. Scopelliti</json:string><json:string>S. J. Young</json:string><json:string>D. Pieraccini</json:string><json:string>S. S. Subramanium</json:string><json:string>M. Poyatos</json:string><json:string>Dalton Trans</json:string><json:string>A. Moreno</json:string><json:string>C. J. Elsevier</json:string><json:string>N. K. Sauter</json:string><json:string>A. J. Edwards</json:string><json:string>G. Bertrand</json:string><json:string>M. Portnoy</json:string><json:string>T. M. McPhillips</json:string><json:string>N. Marion</json:string><json:string>S. P. Nolan</json:string><json:string>A. Pfaltz</json:string><json:string>R. Kuwano</json:string><json:string>A. J. Canty</json:string><json:string>S. M. Soltis</json:string><json:string>M. A. Khan</json:string><json:string>M. Sharma</json:string><json:string>D. J. Williams</json:string><json:string>B. O. Patrick</json:string><json:string>C. Markert</json:string><json:string>S. E. McPhillips</json:string><json:string>T. Steinke</json:string><json:string>B. Kellenberger</json:string><json:string>M. K. Whittlesey</json:string><json:string>M. Spiegler</json:string><json:string>J. Organomet</json:string><json:string>P. Reisinger</json:string><json:string>Y. Liu</json:string><json:string>A. Gonzalez</json:string><json:string>Y. A. Wanniarachchi</json:string><json:string>A. E. Cohen</json:string><json:string>T. Otani</json:string><json:string>A. M. Deacon</json:string><json:string>V. Farina</json:string></persName><placeName><json:string>Australia</json:string><json:string>Grenoble</json:string><json:string>UK</json:string><json:string>Victoria</json:string><json:string>Indonesia</json:string><json:string>Denmark</json:string><json:string>New Zealand</json:string><json:string>France</json:string><json:string>Cambridge</json:string></placeName><ref_url><json:string>http://dx.doi.org/</json:string></ref_url><ref_bibl><json:string>[12]</json:string><json:string>[8]</json:string><json:string>[1]</json:string><json:string>[27]</json:string><json:string>[3]</json:string><json:string>[24]</json:string></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/WNG-VBQRWHQP-T</json:string></ark><categories><wos></wos><scienceMetrix></scienceMetrix><scopus><json:string>1 - Health Sciences</json:string><json:string>2 - Medicine</json:string><json:string>3 - General Medicine</json:string></scopus></categories><publicationDate>2010</publicationDate><copyrightDate>2010</copyrightDate><doi><json:string>10.1002/ange.201003177</json:string></doi><id>579BB6EAD207C7EF9FE09573152F5A43DD83C20A</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/579BB6EAD207C7EF9FE09573152F5A43DD83C20A/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/579BB6EAD207C7EF9FE09573152F5A43DD83C20A/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/579BB6EAD207C7EF9FE09573152F5A43DD83C20A/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}<hi rend="subscript">2</hi>Pd<hi rend="subscript">2</hi>H]<hi rend="superscript">+</hi>: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions<ref type="note" target="#nss"></ref></title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><licence>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</licence></availability><date type="published" when="2010-08-23"></date></publicationStmt><notesStmt><note type="content-type" subtype="brief-communication" source="shortCommunication" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="brief-communication"><analytic><title level="a" type="main" xml:lang="en">Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}<hi rend="subscript">2</hi>Pd<hi rend="subscript">2</hi>H]<hi rend="superscript">+</hi>: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions<ref type="note" target="#nss"></ref></title><author xml:id="author-0000"><persName><forename type="first">Peter D. W.</forename><surname>Boyd</surname><roleName type="degree">Prof.</roleName></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation><affiliation>Current address: Department of Chemistry, The University of Auckland, Auckland 1142 (New Zealand)<address><country key="NZ"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Alison J.</forename><surname>Edwards</surname><roleName type="degree">Dr.</roleName></persName><affiliation>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai NSW 2234 (Australia)<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Michael G.</forename><surname>Gardiner</surname><roleName type="degree">Dr.</roleName></persName><email>michael.gardiner@utas.edu.au</email><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Curtis C.</forename><surname>Ho</surname></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0004"><persName><forename type="first">Marie‐Hélène</forename><surname>Lemée‐Cailleau</surname><roleName type="degree">Dr.</roleName></persName><affiliation>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)<address><country key="FR"></country></address></affiliation></author><author xml:id="author-0005"><persName><forename type="first">David S.</forename><surname>McGuinness</surname><roleName type="degree">Dr.</roleName></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0006"><persName><forename type="first">Anung</forename><surname>Riapanitra</surname></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation><affiliation>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. Dr. Soeparno 61, Purwokerto 53123 (Indonesia)<address><country key="ID"></country></address></affiliation></author><author xml:id="author-0007"><persName><forename type="first">Jonathan W.</forename><surname>Steed</surname><roleName type="degree">Prof.</roleName></persName><affiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)<address><country key="GB"></country></address></affiliation></author><author xml:id="author-0008"><persName><forename type="first">Damien N.</forename><surname>Stringer</surname><roleName type="degree">Dr.</roleName></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation></author><author xml:id="author-0009"><persName><forename type="first">Brian F.</forename><surname>Yates</surname><roleName type="degree">Prof.</roleName></persName><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858<address><country key="AU"></country></address></affiliation></author><idno type="istex">579BB6EAD207C7EF9FE09573152F5A43DD83C20A</idno><idno type="ark">ark:/67375/WNG-VBQRWHQP-T</idno><idno type="DOI">10.1002/ange.201003177</idno><idno type="unit">ANGE201003177</idno><idno type="toTypesetVersion">file:ANGE.ANGE201003177.pdf</idno></analytic><monogr><title level="j" type="main">Angewandte Chemie</title><title level="j" type="alt">ANGEWANDTE CHEMIE</title><idno type="pISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><idno type="book-DOI">10.1002/(ISSN)1521-3757</idno><idno type="book-part-DOI">10.1002/ange.v122:36</idno><idno type="product">ANGE</idno><imprint><biblScope unit="vol">122</biblScope><biblScope unit="issue">36</biblScope><biblScope unit="page" from="6459">6459</biblScope><biblScope unit="page" to="6462">6462</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2010-08-23"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="de" style="graphical"><p><hi rend="bold">Durch basenunterstützte Reduktion</hi> einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; Pd<hi rend="superscript">I</hi> cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.<figure type="box"><media mimeType="image" url="urn:x-wiley:00448249:media:ANGE201003177:content"></media><media mimeType="image/gif" url="" rendition="webLoRes"></media><media mimeType="image/gif" url="" rendition="webOriginal"></media><media mimeType="image/gif" url="" rendition="webHiRes"></media></figure></p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">Homogene Katalyse</term><term xml:id="kwd2">Kupplungsreaktionen</term><term xml:id="kwd3">N‐heterocyclische Carbene</term><term xml:id="kwd4">Palladium</term><term xml:id="kwd5">Reduktionen</term></keywords><keywords rend="articleCategory"><term>Zuschrift</term></keywords><keywords rend="tocHeading1"><term>Zuschriften</term></keywords><keywords rend="tocHeading2"><term>N‐heterocyclische Carbenkomplexe</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/579BB6EAD207C7EF9FE09573152F5A43DD83C20A/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3757</doi><issn type="print">0044-8249</issn><issn type="electronic">1521-3757</issn><idGroup><id type="product" value="ANGE"></id></idGroup><titleGroup><title type="main" xml:lang="de" sort="ANGEWANDTE CHEMIE">Angewandte Chemie</title><title type="short">Angewandte Chemie</title></titleGroup></publicationMeta><publicationMeta level="part" position="360"><doi origin="wiley" registered="yes">10.1002/ange.v122:36</doi><numberingGroup><numbering type="journalVolume" number="122">122</numbering><numbering type="journalIssue">36</numbering></numberingGroup><coverDate startDate="2010-08-23">August 23, 2010</coverDate></publicationMeta><publicationMeta level="unit" type="shortCommunication" position="15" status="forIssue"><doi origin="wiley" registered="yes">10.1002/ange.201003177</doi><idGroup><id type="unit" value="ANGE201003177"></id></idGroup><countGroup><count type="pageTotal" number="4"></count></countGroup><titleGroup><title type="articleCategory">Zuschrift</title><title type="tocHeading1">Zuschriften</title><title type="tocHeading2">N‐heterocyclische Carbenkomplexe</title></titleGroup><copyright ownership="publisher">Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2010-05-26"></event><event type="firstOnline" date="2010-08-19"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.16 mode:FullText" date="2010-08-19"></event><event type="publishedOnlineFinalForm" date="2010-08-19"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-03"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">6459</numbering><numbering type="pageLast">6462</numbering></numberingGroup><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:ANGE.ANGE201003177.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="3"></count><count type="tableTotal" number="0"></count><count type="referenceTotal" number="64"></count></countGroup><titleGroup><title type="main" xml:lang="en">Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}<sub>2</sub>Pd<sub>2</sub>H]<sup>+</sup>: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions<link href="#nss"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa #ap"><personName><givenNames>Peter D. W.</givenNames><familyName>Boyd</familyName><degrees>Prof.</degrees></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#ab"><personName><givenNames>Alison J.</givenNames><familyName>Edwards</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Michael G.</givenNames><familyName>Gardiner</familyName><degrees>Dr.</degrees></personName><contactDetails><email>michael.gardiner@utas.edu.au</email></contactDetails></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Curtis C.</givenNames><familyName>Ho</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#ac"><personName><givenNames>Marie‐Hélène</givenNames><familyName>Lemée‐Cailleau</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#aa"><personName><givenNames>David S.</givenNames><familyName>McGuinness</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#aa #app"><personName><givenNames>Anung</givenNames><familyName>Riapanitra</familyName></personName></creator><creator xml:id="au8" creatorRole="author" affiliationRef="#ad"><personName><givenNames>Jonathan W.</givenNames><familyName>Steed</familyName><degrees>Prof.</degrees></personName></creator><creator xml:id="au9" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Damien N.</givenNames><familyName>Stringer</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au10" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Brian F.</givenNames><familyName>Yates</familyName><degrees>Prof.</degrees></personName></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="AU" type="organization"><unparsedAffiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</unparsedAffiliation></affiliation><affiliation xml:id="ab" countryCode="AU" type="organization"><unparsedAffiliation>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai NSW 2234 (Australia)</unparsedAffiliation></affiliation><affiliation xml:id="ac" countryCode="FR" type="organization"><unparsedAffiliation>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)</unparsedAffiliation></affiliation><affiliation xml:id="ad" countryCode="GB" type="organization"><unparsedAffiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</unparsedAffiliation></affiliation><affiliation xml:id="ap" countryCode="NZ" type="organization"><unparsedAffiliation>Current address: Department of Chemistry, The University of Auckland, Auckland 1142 (New Zealand)</unparsedAffiliation></affiliation><affiliation xml:id="app" countryCode="ID" type="organization"><unparsedAffiliation>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. 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</p><supportingInfoItem><mediaResource alt="supporting information" href="urn-x:wiley:00448249:media:ange201003177:ange_201003177_sm_miscellaneous_information"></mediaResource><caption>miscellaneous_information</caption></supportingInfoItem></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="de"><p><b>Durch basenunterstützte Reduktion</b> einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; Pd<sup>I</sup> cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:00448249:media:ANGE201003177:content"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="nss"><p>X‐ray data were obtained on MX1 at the Australian Synchrotron, Victoria, Australia.<link href="#bib29">29</link> We thank the Australian Government for an Australian Partnership Scholarship (APS) under the Australia Indonesia Partnership for Reconstruction and Development (AIPRD), The University of Auckland for research and study leave support, and Dr. Ross O. Piltz for assistance with neutron data reduction. NHC=N‐heterocyclic carbene ligand.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ‐bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions</title></titleInfo><name type="personal"><namePart type="given">Peter D. W.</namePart><namePart type="family">Boyd</namePart><namePart type="termsOfAddress">Prof.</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><affiliation>Current address: Department of Chemistry, The University of Auckland, Auckland 1142 (New Zealand)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Alison J.</namePart><namePart type="family">Edwards</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai NSW 2234 (Australia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Michael G.</namePart><namePart type="family">Gardiner</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>E-mail: michael.gardiner@utas.edu.au</affiliation><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><affiliation>E-mail: michael.gardiner@utas.edu.au</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Curtis C.</namePart><namePart type="family">Ho</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Marie‐Hélène</namePart><namePart type="family">Lemée‐Cailleau</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Institut Laue‐Langevin, B.P.156, 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">David S.</namePart><namePart type="family">McGuinness</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Anung</namePart><namePart type="family">Riapanitra</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><affiliation>Current address: Department of Chemistry, Universitas Jenderal Soedirman, Jl. Dr. Soeparno 61, Purwokerto 53123 (Indonesia)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jonathan W.</namePart><namePart type="family">Steed</namePart><namePart type="termsOfAddress">Prof.</namePart><affiliation>Department of Chemistry, South Road, University of Durham, Durham DH1 3LE (UK)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Damien N.</namePart><namePart type="family">Stringer</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Brian F.</namePart><namePart type="family">Yates</namePart><namePart type="termsOfAddress">Prof.</namePart><affiliation>School of Chemistry, University of Tasmania, Private Bag 75, Hobart TAS 7001 (Australia), Fax: (+61) 3‐6229‐2858</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2010-08-23</dateIssued><dateCaptured encoding="w3cdtf">2010-05-26</dateCaptured><copyrightDate encoding="w3cdtf">2010</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">3</extent><extent unit="tables">0</extent><extent unit="references">64</extent></physicalDescription><abstract>Durch basenunterstützte Reduktion einer Palladium(II)‐Vorstufe wurde der erste Palladium(I)‐NHC‐Komplex (NHC=N‐heterocyclisches Carben) in hoher Ausbeute hergestellt und isoliert. Die Position des einzigartigen terminalen Hydridliganden (siehe Bild; PdI cyan, H weiß, N blau) wurde durch Neutronenbeugung am Einkristall bestimmt, und das fluktuierende Verhalten des Komplexes in Lösung wurde untersucht.</abstract><note type="content">*X‐ray data were obtained on MX1 at the Australian Synchrotron, Victoria, Australia.29 We thank the Australian Government for an Australian Partnership Scholarship (APS) under the Australia Indonesia Partnership for Reconstruction and Development (AIPRD), The University of Auckland for research and study leave support, and Dr. Ross O. Piltz for assistance with neutron data reduction. NHC=N‐heterocyclic carbene ligand.</note><note type="funding">Australian Government</note><note type="funding">Australia Indonesia Partnership for Reconstruction and Development</note><subject lang="en"><genre>keywords</genre><topic>Homogene Katalyse</topic><topic>Kupplungsreaktionen</topic><topic>N‐heterocyclische Carbene</topic><topic>Palladium</topic><topic>Reduktionen</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie</title></titleInfo><titleInfo type="abbreviated"><title>Angewandte Chemie</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><note type="content"> Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer‐reviewed, but not copy‐edited or typeset. They are made available as submitted by the authors.Supporting Info Item: miscellaneous_information - </note><subject><genre>article-category</genre><topic>Zuschrift</topic></subject><identifier type="ISSN">0044-8249</identifier><identifier type="eISSN">1521-3757</identifier><identifier type="DOI">10.1002/(ISSN)1521-3757</identifier><identifier type="PublisherID">ANGE</identifier><part><date>2010</date><detail type="volume"><caption>vol.</caption><number>122</number></detail><detail type="issue"><caption>no.</caption><number>36</number></detail><extent unit="pages"><start>6459</start><end>6462</end><total>4</total></extent></part></relatedItem><identifier type="istex">579BB6EAD207C7EF9FE09573152F5A43DD83C20A</identifier><identifier type="ark">ark:/67375/WNG-VBQRWHQP-T</identifier><identifier type="DOI">10.1002/ange.201003177</identifier><identifier type="ArticleID">ANGE201003177</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. 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