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Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization

Identifieur interne : 006536 ( Main/Merge ); précédent : 006535; suivant : 006537

Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization

Auteurs : Antonina Simakova [États-Unis] ; Matthew Mackenzie [États-Unis] ; Saadyah E. Averick [États-Unis] ; Sangwoo Park [États-Unis] ; Krzysztof Matyjaszewski [États-Unis]

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2013-11-11.

RBID : ISTEX:33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93

Descripteurs français

Wicri :
- topic : Polymère.

English descriptors

KwdEn :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.
Teeft :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.

Abstract

Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.

Url:

https://api.istex.fr/document/33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93/fulltext/pdf

DOI: 10.1002/anie.201306337

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ISTEX:33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93

Le document en format XML

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<front><div type="abstract">Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.</div>
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Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization

Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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