Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization
Identifieur interne : 000C34 ( Istex/Corpus ); précédent : 000C33; suivant : 000C35Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization
Auteurs : Antonina Simakova ; Matthew Mackenzie ; Saadyah E. Averick ; Sangwoo Park ; Krzysztof MatyjaszewskiSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2013-11-11.
English descriptors
- KwdEn :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.
- Teeft :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.
Abstract
Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.
Url:
DOI: 10.1002/anie.201306337
Links to Exploration step
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<front><div type="abstract">Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.</div>
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