Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization
Identifieur interne : 000C34 ( Istex/Corpus ); précédent : 000C33; suivant : 000C35Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization
Auteurs : Antonina Simakova ; Matthew Mackenzie ; Saadyah E. Averick ; Sangwoo Park ; Krzysztof MatyjaszewskiSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2013-11-11.
English descriptors
- KwdEn :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.
- Teeft :
- Angew, Angewandte communications, Aqueous media, Ascorbic, Ascorbic acid, Atom transfer, Atrp, Atrp catalysts, Catalyst, Catalytic systems, Catalyze atrp, Chem, Cyclic voltammogram, Excess bromide salt, Feii species, Hemin, High values, Initiation efficiency, Iron porphyrins, Kinetic plots, Limited control, Linear increase, Macro lett, Macromolecule, Matyjaszewski, Methyl ether methacrylate, Molecular weight, Polym, Polymer, Polymer chain, Poor control, Prosthetic group, Rapid commun, Slow initiation, Verlag gmbh, Weinheim angew.
Abstract
Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.
Url:
DOI: 10.1002/anie.201306337
Links to Exploration step
ISTEX:33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93Le document en format XML
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The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>atrp</json:string><json:string>hemin</json:string><json:string>matyjaszewski</json:string><json:string>polym</json:string><json:string>macromolecule</json:string><json:string>angew</json:string><json:string>ascorbic acid</json:string><json:string>ascorbic</json:string><json:string>aqueous media</json:string><json:string>polymer</json:string><json:string>kinetic plots</json:string><json:string>catalyst</json:string><json:string>verlag gmbh</json:string><json:string>initiation efficiency</json:string><json:string>atom transfer</json:string><json:string>excess bromide salt</json:string><json:string>linear increase</json:string><json:string>molecular weight</json:string><json:string>feii species</json:string><json:string>prosthetic group</json:string><json:string>iron porphyrins</json:string><json:string>weinheim angew</json:string><json:string>atrp catalysts</json:string><json:string>catalyze atrp</json:string><json:string>high values</json:string><json:string>poor control</json:string><json:string>angewandte communications</json:string><json:string>methyl ether methacrylate</json:string><json:string>slow initiation</json:string><json:string>cyclic voltammogram</json:string><json:string>polymer chain</json:string><json:string>catalytic systems</json:string><json:string>limited control</json:string><json:string>rapid commun</json:string><json:string>macro lett</json:string></teeft></keywords><author><json:item><name>Antonina Simakova</name><affiliations><json:string>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string></affiliations></json:item><json:item><name>Matthew Mackenzie</name><affiliations><json:string>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string></affiliations></json:item><json:item><name>Saadyah E. Averick</name><affiliations><json:string>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string></affiliations></json:item><json:item><name>Sangwoo Park</name><affiliations><json:string>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string></affiliations></json:item><json:item><name>Krzysztof Matyjaszewski</name><affiliations><json:string>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string><json:string>E-mail: km3b@andrew.cmu.edu</json:string><json:string>Correspondence address: Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>atom transfer radical polymerization</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>hemin</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>iron</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>polymerization</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>porphyrinoids</value></json:item></subject><articleId><json:string>ANIE201306337</json:string></articleId><arkIstex>ark:/67375/WNG-Q5PSZ0HF-3</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>shortCommunication</json:string></originalGenre><abstract>Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. 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KGaA, Weinheim</licence></availability><date type="published" when="2013-11-11"></date></publicationStmt><notesStmt><note type="content-type" subtype="brief-communication" source="shortCommunication" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="brief-communication"><analytic><title level="a" type="main" xml:lang="en">Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization<ref type="note" target="#nss"></ref></title><author xml:id="author-0000"><persName><forename type="first">Antonina</forename><surname>Simakova</surname></persName><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Matthew</forename><surname>Mackenzie</surname></persName><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Saadyah E.</forename><surname>Averick</surname></persName><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Sangwoo</forename><surname>Park</surname></persName><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0004" role="corresp"><persName><forename type="first">Krzysztof</forename><surname>Matyjaszewski</surname></persName><email>km3b@andrew.cmu.edu</email><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)<address><country key="US"></country></address></affiliation><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation></author><idno type="istex">33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93</idno><idno type="ark">ark:/67375/WNG-Q5PSZ0HF-3</idno><idno type="DOI">10.1002/anie.201306337</idno><idno type="unit">ANIE201306337</idno><idno type="toTypesetVersion">file:ANIE.ANIE201306337.pdf</idno></analytic><monogr><title level="j" type="main">Angewandte Chemie International Edition</title><title level="j" type="alt">ANGEWANDTE CHEMIE INTERNATIONAL EDITION</title><idno type="pISSN">1433-7851</idno><idno type="eISSN">1521-3773</idno><idno type="book-DOI">10.1002/(ISSN)1521-3773</idno><idno type="book-part-DOI">10.1002/anie.v52.46</idno><idno type="product">ANIE</idno><imprint><biblScope unit="vol">52</biblScope><biblScope unit="issue">46</biblScope><biblScope unit="page" from="12148">12148</biblScope><biblScope unit="page" to="12151">12151</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2013-11-11"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="graphical"><p><hi rend="bold">Naturally occurring hemin</hi>, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.<figure type="box"><media mimeType="image" url="urn:x-wiley:14337851:media:ANIE201306337:content"></media></figure></p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">atom transfer radical polymerization</term><term xml:id="kwd2">hemin</term><term xml:id="kwd3">iron</term><term xml:id="kwd4">polymerization</term><term xml:id="kwd5">porphyrinoids</term></keywords><keywords rend="articleCategory"><term>Communication</term></keywords><keywords rend="tocHeading1"><term>Communications</term></keywords><keywords rend="tocHeading2"><term>Polymerization</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/33F4B6FAB24B9B26CDE0FAEF43659D3BE332BA93/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3773</doi><issn type="print">1433-7851</issn><issn type="electronic">1521-3773</issn><idGroup><id type="product" value="ANIE"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="ANGEWANDTE CHEMIE INTERNATIONAL EDITION">Angewandte Chemie International Edition</title><title type="short">Angew. 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KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2013-07-20"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:3.2.9 mode:FullText" date="2014-02-21"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.2.9 mode:FullText" date="2014-02-21"></event><event type="publishedOnlineEarlyUnpaginated" date="2013-09-23"></event><event type="publishedOnlineFinalForm" date="2013-11-08"></event><event type="firstOnline" date="2013-09-23"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.6.4 mode:FullText" date="2015-10-01"></event></eventGroup><numberingGroup><numbering type="pageFirst">12148</numbering><numbering type="pageLast">12151</numbering></numberingGroup><correspondenceTo>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</correspondenceTo><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:ANIE.ANIE201306337.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="5"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="58"></count></countGroup><titleGroup><title type="main" xml:lang="en">Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization<link href="#nss"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Antonina</givenNames><familyName>Simakova</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Matthew</givenNames><familyName>Mackenzie</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Saadyah E.</givenNames><familyName>Averick</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Sangwoo</givenNames><familyName>Park</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#aa" corresponding="yes"><personName><givenNames>Krzysztof</givenNames><familyName>Matyjaszewski</familyName></personName><contactDetails><email>km3b@andrew.cmu.edu</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="US" type="organization"><unparsedAffiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">atom transfer radical polymerization</keyword><keyword xml:id="kwd2">hemin</keyword><keyword xml:id="kwd3">iron</keyword><keyword xml:id="kwd4">polymerization</keyword><keyword xml:id="kwd5">porphyrinoids</keyword></keywordGroup><fundingInfo><fundingAgency>CRP Consortium</fundingAgency></fundingInfo><fundingInfo><fundingAgency>NSF</fundingAgency><fundingNumber>CHE 10‐26060</fundingNumber></fundingInfo><supportingInformation><p>As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
</p><supportingInfoItem><mediaResource alt="supporting information" href="urn-x:wiley:14337851:media:anie201306337:anie_201306337_sm_miscellaneous_information"></mediaResource><caption>miscellaneous_information</caption></supportingInfoItem></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Naturally occurring hemin</b>, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14337851:media:ANIE201306337:content"></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="nss"><p>The financial support from CRP Consortium and NSF (grant number CHE 10‐26060) is appreciated. We acknowledge the sample of catalase received from Ryan Mehl.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization</title></titleInfo><name type="personal"><namePart type="given">Antonina</namePart><namePart type="family">Simakova</namePart><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Matthew</namePart><namePart type="family">Mackenzie</namePart><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Saadyah E.</namePart><namePart type="family">Averick</namePart><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Sangwoo</namePart><namePart type="family">Park</namePart><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Krzysztof</namePart><namePart type="family">Matyjaszewski</namePart><affiliation>Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><affiliation>E-mail: km3b@andrew.cmu.edu</affiliation><affiliation>Correspondence address: Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2013-11-11</dateIssued><dateCaptured encoding="w3cdtf">2013-07-20</dateCaptured><copyrightDate encoding="w3cdtf">2013</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">5</extent><extent unit="tables">1</extent><extent unit="references">58</extent></physicalDescription><abstract>Naturally occurring hemin, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.</abstract><note type="content">*The financial support from CRP Consortium and NSF (grant number CHE 10‐26060) is appreciated. We acknowledge the sample of catalase received from Ryan Mehl.</note><note type="funding">CRP Consortium</note><note type="funding">NSF - No. CHE 10‐26060; </note><subject lang="en"><genre>keywords</genre><topic>atom transfer radical polymerization</topic><topic>hemin</topic><topic>iron</topic><topic>polymerization</topic><topic>porphyrinoids</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title></titleInfo><titleInfo type="abbreviated"><title>Angew. Chem. Int. 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