(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Identifieur interne : 001497 ( Istex/Curation ); précédent : 001496; suivant : 001498(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Auteurs : Joseph A. Corella Ii [États-Unis] ; Robert L. Thompson [États-Unis] ; N. John Cooper [États-Unis]Source :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1992-01.
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Abstract
The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.
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DOI: 10.1002/anie.199200831
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Thompson</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation></author><author><name sortKey="Cooper, N John" sort="Cooper, N John" uniqKey="Cooper N" first="N. John" last="Cooper">N. John Cooper</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation><affiliation wicri:level="1"><mods:affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:5B2A596A43FE94B5156514EA9F4BAA6B73D360BD</idno><date when="1992" year="1992">1992</date><idno type="doi">10.1002/anie.199200831</idno><idno type="url">https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001497</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001497</idno><idno type="wicri:Area/Istex/Curation">001497</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate<ref type="note" target="#fn1"></ref></title><author><name sortKey="Corella Ii, Joseph A" sort="Corella Ii, Joseph A" uniqKey="Corella Ii J" first="Joseph A." last="Corella Ii">Joseph A. Corella Ii</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation></author><author><name sortKey="Thompson, Robert L" sort="Thompson, Robert L" uniqKey="Thompson R" first="Robert L." last="Thompson">Robert L. Thompson</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation></author><author><name sortKey="Cooper, N John" sort="Cooper, N John" uniqKey="Cooper N" first="N. John" last="Cooper">N. John Cooper</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation><affiliation wicri:level="1"><mods:affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh</wicri:regionArea></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie International Edition in English</title><title level="j" type="alt">ANGEWANDTE CHEMIE INTERNATIONAL EDITION IN ENGLISH</title><idno type="ISSN">0570-0833</idno><idno type="eISSN">1521-3773</idno><imprint><biblScope unit="vol">31</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="83">83</biblScope><biblScope unit="page" to="84">84</biblScope><biblScope unit="page-count">2</biblScope><publisher>Hüthig & Wepf Verlag</publisher><pubPlace>Zug</pubPlace><date type="published" when="1992-01">1992-01</date></imprint><idno type="ISSN">0570-0833</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0570-0833</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aryl</term><term>Chem</term><term>Cntbu</term><term>Discrete isocyanide ligands</term><term>Dropwise addition</term><term>Experimental procedure</term><term>Hexane</term><term>Isocyanide</term><term>Ligand</term><term>Mmol</term><term>Oxidative addition</term><term>Reaction mixture</term><term>Reactive intermediates</term><term>Snph</term><term>Trans isomer</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Aryl</term><term>Chem</term><term>Cntbu</term><term>Discrete isocyanide ligands</term><term>Dropwise addition</term><term>Experimental procedure</term><term>Hexane</term><term>Isocyanide</term><term>Ligand</term><term>Mmol</term><term>Oxidative addition</term><term>Reaction mixture</term><term>Reactive intermediates</term><term>Snph</term><term>Trans isomer</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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