(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Identifieur interne : 001497 ( Istex/Curation ); précédent : 001496; suivant : 001498(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Auteurs : Joseph A. Corella Ii [États-Unis] ; Robert L. Thompson [États-Unis] ; N. John Cooper [États-Unis]Source :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1992-01.
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Abstract
The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.
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DOI: 10.1002/anie.199200831
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<term>Dropwise addition</term>
<term>Experimental procedure</term>
<term>Hexane</term>
<term>Isocyanide</term>
<term>Ligand</term>
<term>Mmol</term>
<term>Oxidative addition</term>
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<front><div type="abstract">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</div>
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