(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Identifieur interne : 001497 ( Istex/Corpus ); précédent : 001496; suivant : 001498(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Auteurs : Joseph A. Corella Ii ; Robert L. Thompson ; N. John CooperSource :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1992-01.
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Abstract
The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.
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DOI: 10.1002/anie.199200831
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ISTEX:5B2A596A43FE94B5156514EA9F4BAA6B73D360BDLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title><author><name sortKey="Corella Ii, Joseph A" sort="Corella Ii, Joseph A" uniqKey="Corella Ii J" first="Joseph A." last="Corella Ii">Joseph A. Corella Ii</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author><author><name sortKey="Thompson, Robert L" sort="Thompson, Robert L" uniqKey="Thompson R" first="Robert L." last="Thompson">Robert L. Thompson</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author><author><name sortKey="Cooper, N John" sort="Cooper, N John" uniqKey="Cooper N" first="N. John" last="Cooper">N. John Cooper</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:5B2A596A43FE94B5156514EA9F4BAA6B73D360BD</idno><date when="1992" year="1992">1992</date><idno type="doi">10.1002/anie.199200831</idno><idno type="url">https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001497</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001497</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate<ref type="note" target="#fn1"></ref></title><author><name sortKey="Corella Ii, Joseph A" sort="Corella Ii, Joseph A" uniqKey="Corella Ii J" first="Joseph A." last="Corella Ii">Joseph A. Corella Ii</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author><author><name sortKey="Thompson, Robert L" sort="Thompson, Robert L" uniqKey="Thompson R" first="Robert L." last="Thompson">Robert L. Thompson</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author><author><name sortKey="Cooper, N John" sort="Cooper, N John" uniqKey="Cooper N" first="N. John" last="Cooper">N. John Cooper</name><affiliation><mods:affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Angewandte Chemie International Edition in English</title><title level="j" type="alt">ANGEWANDTE CHEMIE INTERNATIONAL EDITION IN ENGLISH</title><idno type="ISSN">0570-0833</idno><idno type="eISSN">1521-3773</idno><imprint><biblScope unit="vol">31</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="83">83</biblScope><biblScope unit="page" to="84">84</biblScope><biblScope unit="page-count">2</biblScope><publisher>Hüthig & Wepf Verlag</publisher><pubPlace>Zug</pubPlace><date type="published" when="1992-01">1992-01</date></imprint><idno type="ISSN">0570-0833</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0570-0833</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aryl</term><term>Chem</term><term>Cntbu</term><term>Discrete isocyanide ligands</term><term>Dropwise addition</term><term>Experimental procedure</term><term>Hexane</term><term>Isocyanide</term><term>Ligand</term><term>Mmol</term><term>Oxidative addition</term><term>Reaction mixture</term><term>Reactive intermediates</term><term>Snph</term><term>Trans isomer</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Aryl</term><term>Chem</term><term>Cntbu</term><term>Discrete isocyanide ligands</term><term>Dropwise addition</term><term>Experimental procedure</term><term>Hexane</term><term>Isocyanide</term><term>Ligand</term><term>Mmol</term><term>Oxidative addition</term><term>Reaction mixture</term><term>Reactive intermediates</term><term>Snph</term><term>Trans isomer</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>isocyanide</json:string><json:string>cntbu</json:string><json:string>snph</json:string><json:string>ligand</json:string><json:string>hexane</json:string><json:string>mmol</json:string><json:string>discrete isocyanide ligands</json:string><json:string>reactive intermediates</json:string><json:string>trans isomer</json:string><json:string>experimental procedure</json:string><json:string>oxidative addition</json:string><json:string>dropwise addition</json:string><json:string>reaction mixture</json:string><json:string>aryl</json:string></teeft></keywords><author><json:item><name>Joseph A. Corella II</name><affiliations><json:string>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</json:string></affiliations></json:item><json:item><name>Robert L. Thompson</name><affiliations><json:string>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</json:string></affiliations></json:item><json:item><name>Prof. Dr. N. John Cooper</name><affiliations><json:string>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</json:string><json:string>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</json:string></affiliations></json:item></author><articleId><json:string>ANIE199200831</json:string></articleId><arkIstex>ark:/67375/WNG-7R9ZXJ61-B</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>shortCommunication</json:string></originalGenre><abstract>The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</abstract><qualityIndicators><score>4.539</score><pdfWordCount>1915</pdfWordCount><pdfCharCount>10964</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>2</pdfPageCount><pdfPageSize>576 x 792 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>52</abstractWordCount><abstractCharCount>396</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title><genre><json:string>brief-communication</json:string></genre><host><title>Angewandte Chemie International Edition in English</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-3773a</json:string></doi><issn><json:string>0570-0833</json:string></issn><eissn><json:string>1521-3773</json:string></eissn><publisherId><json:string>ANIEBACK</json:string></publisherId><volume>31</volume><issue>1</issue><pages><first>83</first><last>84</last><total>2</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Communication</value></json:item></subject></host><namedEntities><unitex><date><json:string>1992</json:string></date><geogName><json:string>Ill</json:string></geogName><orgName><json:string>National Science Foundation</json:string><json:string>University of Pittsburgh Pittsburgh</json:string></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName><json:string>G. F. Warnock</json:string><json:string>L. Malatesta</json:string><json:string>M. Bassett</json:string><json:string>Dalton Puns</json:string><json:string>J. A. S. Howell</json:string><json:string>G. Jaouen</json:string><json:string>R. G. Finke</json:string><json:string>Dieter Seebach</json:string><json:string>A. LeBeuze</json:string><json:string>D. Seebach</json:string><json:string>A. J. Welch</json:string><json:string>B. Weber</json:string><json:string>C. M. Giandomenico</json:string><json:string>Patricia Leach</json:string><json:string>John Cooper</json:string><json:string>S. J. Geib</json:string><json:string>J. Chem</json:string><json:string>J. P. Collman</json:string><json:string>F. G. A. Stone</json:string><json:string>G. H. D. Royston</json:string><json:string>P. M. Treichel</json:string><json:string>P. A. Leach</json:string><json:string>A. Sonz</json:string><json:string>R. Corfield</json:string><json:string>V. S. Leong</json:string><json:string>G. A. Padoa</json:string><json:string>P. Woodward</json:string><json:string>Y. Yamamoto</json:string><json:string>J. A. Corella</json:string><json:string>A. J. L. Pombeiro</json:string><json:string>M. E. Oosthuizen</json:string><json:string>A. M. R. Galas</json:string><json:string>Beat Weber</json:string><json:string>N. J. Cooper</json:string><json:string>G. K. Barker</json:string><json:string>J. A. K. Howard</json:string><json:string>M. Green</json:string><json:string>J. Chatt</json:string><json:string>C. M. Elson</json:string><json:string>Garry Warnock</json:string><json:string>D. E. Berry</json:string><json:string>F. Bonanti</json:string><json:string>S. J. Lippard</json:string><json:string>R. L. Richards</json:string><json:string>C. T. Lam</json:string><json:string>L. S. Hegedus</json:string><json:string>J. R. Norton</json:string><json:string>H. SiMe</json:string><json:string>J. Organomet</json:string><json:string>S. Warner</json:string><json:string>E. Singleton</json:string><json:string>Dalton Pans</json:string></persName><placeName><json:string>Switzerland</json:string><json:string>Sor</json:string><json:string>Namur</json:string><json:string>Zurich</json:string></placeName><ref_url></ref_url><ref_bibl><json:string>Lippard et al.</json:string><json:string>July 17,1991</json:string></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/WNG-7R9ZXJ61-B</json:string></ark><publicationDate>1992</publicationDate><copyrightDate>1992</copyrightDate><doi><json:string>10.1002/anie.199200831</json:string></doi><id>5B2A596A43FE94B5156514EA9F4BAA6B73D360BD</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate<ref type="note" target="#fn1"></ref></title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>Hüthig & Wepf Verlag</publisher><pubPlace>Zug</pubPlace><availability><licence>Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany</licence></availability><date type="published" when="1992-01"></date></publicationStmt><notesStmt><note type="content-type" subtype="brief-communication" source="shortCommunication" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="brief-communication"><analytic><title level="a" type="main" xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate<ref type="note" target="#fn1"></ref></title><author xml:id="author-0000"><persName><genName>II</genName><forename type="first">Joseph A.</forename><surname>Corella</surname></persName><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Robert L.</forename><surname>Thompson</surname></persName><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)<address><country key="US"></country></address></affiliation></author><author xml:id="author-0002" role="corresp"><persName><addName>Prof. Dr.</addName><forename type="first">N. John</forename><surname>Cooper</surname></persName><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)<address><country key="US"></country></address></affiliation><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation></author><idno type="istex">5B2A596A43FE94B5156514EA9F4BAA6B73D360BD</idno><idno type="ark">ark:/67375/WNG-7R9ZXJ61-B</idno><idno type="DOI">10.1002/anie.199200831</idno><idno type="unit">ANIE199200831</idno><idno type="toTypesetVersion">file:ANIEBACK.ANIE199200831.pdf</idno></analytic><monogr><title level="j" type="main">Angewandte Chemie International Edition in English</title><title level="j" type="alt">ANGEWANDTE CHEMIE INTERNATIONAL EDITION IN ENGLISH</title><idno type="pISSN">0570-0833</idno><idno type="eISSN">1521-3773</idno><idno type="book-DOI">10.1002/(ISSN)1521-3773a</idno><idno type="book-part-DOI">10.1002/anie.v31:1</idno><idno type="product">ANIEBACK</idno><imprint><biblScope unit="vol">31</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="83">83</biblScope><biblScope unit="page" to="84">84</biblScope><biblScope unit="page-count">2</biblScope><publisher>Hüthig & Wepf Verlag</publisher><pubPlace>Zug</pubPlace><date type="published" when="1992-01"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="graphical"><p><hi rend="bold">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1</hi> affords the (tetraisocyanide)ruthenate dianions <hi rend="bold">2</hi>, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus <hi rend="bold">2</hi> reacts with Ph<hi rend="subscript">3</hi>SnCl by oxidative addition to give <hi rend="bold">3</hi> (<hi rend="italic">trans</hi> isomers). But <hi rend="bold">2</hi> also reacts analogous to [Fe(CO)<hi rend="subscript">4</hi>]<hi rend="superscript">2−</hi>, with Si‐ and C‐electrophiles. R = <hi rend="italic">t</hi>Bu, 2,6‐Me<hi rend="subscript">2</hi>C<hi rend="subscript">6</hi>H<hi rend="subscript">3</hi>. <figure type="box"><media mimeType="image" url="urn:x-wiley:05700833:media:ANIE199200831:ust001"></media><media mimeType="image/gif" url="" rendition="webLoRes"></media><media mimeType="image/gif" url="" rendition="webOriginal"></media><media mimeType="image/gif" url="" rendition="webHiRes"></media></figure></p></abstract><textClass><keywords rend="articleCategory"><term>Communication</term></keywords><keywords rend="tocHeading1"><term>Communications</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Hüthig & Wepf Verlag</publisherName><publisherLoc>Zug</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3773a</doi><issn type="print">0570-0833</issn><issn type="electronic">1521-3773</issn><idGroup><id type="product" value="ANIEBACK"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="ANGEWANDTE CHEMIE INTERNATIONAL EDITION IN ENGLISH">Angewandte Chemie International Edition in English</title><title type="tocForm">Angewandte Chemie International Edition</title><title type="short">Angew. Chem. Int. Ed. Engl.</title></titleGroup></publicationMeta><publicationMeta level="part" position="10"><doi origin="wiley" registered="yes">10.1002/anie.v31:1</doi><numberingGroup><numbering type="journalVolume" number="31">31</numbering><numbering type="journalIssue">1</numbering></numberingGroup><coverDate startDate="1992-01">January 1992</coverDate></publicationMeta><publicationMeta level="unit" type="shortCommunication" position="25" status="forIssue"><doi origin="wiley" registered="yes">10.1002/anie.199200831</doi><idGroup><id type="unit" value="ANIE199200831"></id></idGroup><countGroup><count type="pageTotal" number="2"></count></countGroup><titleGroup><title type="articleCategory">Communication</title><title type="tocHeading1">Communications</title></titleGroup><copyright ownership="publisher">Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany</copyright><eventGroup><event type="manuscriptReceived" date="1991-07-30"></event><event type="firstOnline" date="2003-12-22"></event><event type="publishedOnlineFinalForm" date="2003-12-22"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.2 mode:FullText source:HeaderRef result:HeaderRef" date="2010-03-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-24"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">83</numbering><numbering type="pageLast">84</numbering></numberingGroup><correspondenceTo>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:ANIEBACK.ANIE199200831.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="0"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="12"></count></countGroup><titleGroup><title type="main" xml:lang="en">(Isocyanide)ruthenate Analogues of Tetracarbonylferrate<link href="#fn1"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Joseph A.</givenNames><familyName>Corella</familyName><nameSuffix>II</nameSuffix></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Robert L.</givenNames><familyName>Thompson</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><honorifics>Prof. Dr.</honorifics><givenNames>N. John</givenNames><familyName>Cooper</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="US" type="organization"><unparsedAffiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1</b> affords the (tetraisocyanide)ruthenate dianions <b>2</b>, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus <b>2</b> reacts with Ph<sub>3</sub>SnCl by oxidative addition to give <b>3</b> (<i>trans</i> isomers). But <b>2</b> also reacts analogous to [Fe(CO)<sub>4</sub>]<sup>2−</sup>, with Si‐ and C‐electrophiles. R = <i>t</i>Bu, 2,6‐Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>. <blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" copyright="VCH Verlagsgesellschaft mbH" href="urn:x-wiley:05700833:media:ANIE199200831:ust001"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="fn1"><p>We thank the U. S. National Science Foundation for generous financial support through Grant 8722424 and Dr. Garry Warnock and Patricia Leach for stimulating discussions.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title></titleInfo><name type="personal"><namePart type="given">Joseph A.</namePart><namePart type="family">Corella II</namePart><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Robert L.</namePart><namePart type="family">Thompson</namePart><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart><namePart type="given">N. John</namePart><namePart type="family">Cooper</namePart><affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation><affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-S9SX2MFS-0">brief-communication</genre><originInfo><publisher>Hüthig & Wepf Verlag</publisher><place><placeTerm type="text">Zug</placeTerm></place><dateIssued encoding="w3cdtf">1992-01</dateIssued><dateCaptured encoding="w3cdtf">1991-07-30</dateCaptured><copyrightDate encoding="w3cdtf">1992</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">0</extent><extent unit="tables">1</extent><extent unit="references">12</extent></physicalDescription><abstract>The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</abstract><note type="content">*We thank the U. S. National Science Foundation for generous financial support through Grant 8722424 and Dr. Garry Warnock and Patricia Leach for stimulating discussions.</note><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition in English</title></titleInfo><titleInfo type="abbreviated"><title>Angew. Chem. Int. Ed. Engl.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">0570-0833</identifier><identifier type="eISSN">1521-3773</identifier><identifier type="DOI">10.1002/(ISSN)1521-3773a</identifier><identifier type="PublisherID">ANIEBACK</identifier><part><date>1992</date><detail type="volume"><caption>vol.</caption><number>31</number></detail><detail type="issue"><caption>no.</caption><number>1</number></detail><extent unit="pages"><start>83</start><end>84</end><total>2</total></extent></part></relatedItem><identifier type="istex">5B2A596A43FE94B5156514EA9F4BAA6B73D360BD</identifier><identifier type="ark">ark:/67375/WNG-7R9ZXJ61-B</identifier><identifier type="DOI">10.1002/anie.199200831</identifier><identifier type="ArticleID">ANIE199200831</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Hüthig & Wepf Verlag</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/5B2A596A43FE94B5156514EA9F4BAA6B73D360BD/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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