(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Identifieur interne : 001497 ( Istex/Corpus ); précédent : 001496; suivant : 001498(Isocyanide)ruthenate Analogues of Tetracarbonylferrate
Auteurs : Joseph A. Corella Ii ; Robert L. Thompson ; N. John CooperSource :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1992-01.
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Abstract
The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.
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DOI: 10.1002/anie.199200831
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<front><div type="abstract">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</div>
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<profileDesc><abstract xml:lang="en" style="graphical"><p><hi rend="bold">The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1</hi>
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<abstractGroup><abstract type="graphical" xml:lang="en"><p><b>The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1</b>
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isomers). But <b>2</b>
also reacts analogous to [Fe(CO)<sub>4</sub>
]<sup>2−</sup>
, with Si‐ and C‐electrophiles. R = <i>t</i>
Bu, 2,6‐Me<sub>2</sub>
C<sub>6</sub>
H<sub>3</sub>
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<noteGroup><note xml:id="fn1"><p>We thank the U. S. National Science Foundation for generous financial support through Grant 8722424 and Dr. Garry Warnock and Patricia Leach for stimulating discussions.</p>
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<mods version="3.6"><titleInfo lang="en"><title>(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title>
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<titleInfo type="alternative" contentType="CDATA" lang="en"><title>(Isocyanide)ruthenate Analogues of Tetracarbonylferrate</title>
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<name type="personal"><namePart type="given">Joseph A.</namePart>
<namePart type="family">Corella II</namePart>
<affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation>
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<name type="personal"><namePart type="given">Robert L.</namePart>
<namePart type="family">Thompson</namePart>
<affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation>
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<name type="personal"><namePart type="termsOfAddress">Prof. Dr.</namePart>
<namePart type="given">N. John</namePart>
<namePart type="family">Cooper</namePart>
<affiliation>Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation>
<affiliation>Correspondence address: Department of Chemistry, University of Pittsburgh Pittsburgh, PA 15260 (USA)</affiliation>
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<abstract>The potassium–naphthalene reduction of dichloro(tetraisocyanide)ruthenium complexes 1 affords the (tetraisocyanide)ruthenate dianions 2, which can be trapped with electrophiles and partially characterized by IR spectroscopy. Thus 2 reacts with Ph3SnCl by oxidative addition to give 3 (trans isomers). But 2 also reacts analogous to [Fe(CO)4]2−, with Si‐ and C‐electrophiles. R = tBu, 2,6‐Me2C6H3.</abstract>
<note type="content">*We thank the U. S. National Science Foundation for generous financial support through Grant 8722424 and Dr. Garry Warnock and Patricia Leach for stimulating discussions.</note>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition in English</title>
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<identifier type="ISSN">0570-0833</identifier>
<identifier type="eISSN">1521-3773</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3773a</identifier>
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<part><date>1992</date>
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<number>31</number>
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