Orange Peel Oxidative Gasification on Ni Catalysts Promoted with CaO, CeO2 or K2O.
Identifieur interne : 000144 ( PubMed/Checkpoint ); précédent : 000143; suivant : 000145Orange Peel Oxidative Gasification on Ni Catalysts Promoted with CaO, CeO2 or K2O.
Auteurs : G. Vargas ; B. Zapata ; M A Valenzuela ; S. AlfaroSource :
- Journal of nanoscience and nanotechnology [ 1533-4880 ] ; 2015.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Gases, Nickel, Oxides.
- chemical : Cerium, Ethylenes, Hydrogen.
- chemistry : Citrus sinensis.
- Biomass, Catalysis, Hot Temperature, Oxidation-Reduction, Thermogravimetry.
Abstract
Orange peel can be considered as an attractive raw material to be gasified for hydrogen or syngas production. In this work, the catalytic evaluation of several silica-supported nickel catalysts in the oxidative degradation of waste orange peel is reported. It was found that the catalytic gasification with the K2O-Ni/silica catalyst produces more hydrogen than the non-catalytic route at 600 degrees C. Surprisingly, a significant amount of ethene was obtained with the CeO2-Ni/silica catalyst, which was explained in terms of an oxidative dehydrogenation reaction of ethane formed during biomass or tar decomposition.
PubMed: 26716225
Affiliations:
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pubmed:26716225Le document en format XML
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<author><name sortKey="Zapata, B" sort="Zapata, B" uniqKey="Zapata B" first="B" last="Zapata">B. Zapata</name>
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<author><name sortKey="Valenzuela, M A" sort="Valenzuela, M A" uniqKey="Valenzuela M" first="M A" last="Valenzuela">M A Valenzuela</name>
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<term>Gases (chemistry)</term>
<term>Hot Temperature</term>
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<term>Nickel (chemistry)</term>
<term>Oxidation-Reduction</term>
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<front><div type="abstract" xml:lang="en">Orange peel can be considered as an attractive raw material to be gasified for hydrogen or syngas production. In this work, the catalytic evaluation of several silica-supported nickel catalysts in the oxidative degradation of waste orange peel is reported. It was found that the catalytic gasification with the K2O-Ni/silica catalyst produces more hydrogen than the non-catalytic route at 600 degrees C. Surprisingly, a significant amount of ethene was obtained with the CeO2-Ni/silica catalyst, which was explained in terms of an oxidative dehydrogenation reaction of ethane formed during biomass or tar decomposition.</div>
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<Title>Journal of nanoscience and nanotechnology</Title>
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<Abstract><AbstractText>Orange peel can be considered as an attractive raw material to be gasified for hydrogen or syngas production. In this work, the catalytic evaluation of several silica-supported nickel catalysts in the oxidative degradation of waste orange peel is reported. It was found that the catalytic gasification with the K2O-Ni/silica catalyst produces more hydrogen than the non-catalytic route at 600 degrees C. Surprisingly, a significant amount of ethene was obtained with the CeO2-Ni/silica catalyst, which was explained in terms of an oxidative dehydrogenation reaction of ethane formed during biomass or tar decomposition.</AbstractText>
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